General, Organic, and Biological Chemistry Seventh Edition
General, Organic, and Biological Chemistry Seventh Edition
7th Edition
ISBN: 9781305767867
Author: H. Stephan Stoker
Publisher: Cengage Learning
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Chapter 14, Problem 14.44EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group.  Alcohols contain both nonpolar and polar groups in it.  Hydroxyl group is the polar group and the alkyl group is the nonpolar group.  Physical properties of alcohol depend on which of the two groups dominate.  Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms.  When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product.  The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule.  The general scheme for hydration of alkene can be given as,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 14, Problem 14.44EP , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group.  Alcohols contain both nonpolar and polar groups in it.  Hydroxyl group is the polar group and the alkyl group is the nonpolar group.  Physical properties of alcohol depend on which of the two groups dominate.  Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound.  Addition of hydrogen to this carbonyl group leads to the formation of alcohol.  When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group.  A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 14, Problem 14.44EP , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group.  Alcohols contain both nonpolar and polar groups in it.  Hydroxyl group is the polar group and the alkyl group is the nonpolar group.  Physical properties of alcohol depend on which of the two groups dominate.  Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Double bond between a carbon atom and oxygen atom means that the compound is a carbonyl compound.  Addition of hydrogen to this carbonyl group leads to the formation of alcohol.  When hydrogen is added to the carbonyl, the oxygen of the carbonyl is converted into hydroxyl group.  A scheme for the addition of hydrogen to the carbonyl group can be given as shown below,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 14, Problem 14.44EP , additional homework tip  3

(d)

Interpretation Introduction

Interpretation:

The predominant organic product that is formed in the given reaction has to be written.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group.  Alcohols contain both nonpolar and polar groups in it.  Hydroxyl group is the polar group and the alkyl group is the nonpolar group.  Physical properties of alcohol depend on which of the two groups dominate.  Alcohols can be prepared in laboratory by hydration of alkenes and reduction of carbonyl compounds.

Alkenes are compounds that contain a double bond between carbon atoms.  When alkenes undergo hydration in presence of sulfuric acid as catalyst, an alcohol is formed as product.  The major product formed in case of unsymmetrical alkene is found by using Markovnikov’s rule.  The general scheme for hydration of alkene can be given as,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 14, Problem 14.44EP , additional homework tip  4

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Chapter 14 Solutions

General, Organic, and Biological Chemistry Seventh Edition

Ch. 14.4 - Prob. 2QQCh. 14.4 - Prob. 3QQCh. 14.5 - Prob. 1QQCh. 14.5 - Prob. 2QQCh. 14.5 - Prob. 3QQCh. 14.5 - Prob. 4QQCh. 14.6 - Prob. 1QQCh. 14.6 - Prob. 2QQCh. 14.6 - Prob. 3QQCh. 14.7 - Prob. 1QQCh. 14.7 - Prob. 2QQCh. 14.8 - Prob. 1QQCh. 14.8 - Prob. 2QQCh. 14.9 - Prob. 1QQCh. 14.9 - Prob. 2QQCh. 14.9 - Prob. 3QQCh. 14.9 - Prob. 4QQCh. 14.9 - Prob. 5QQCh. 14.9 - Prob. 6QQCh. 14.10 - Prob. 1QQCh. 14.10 - Prob. 2QQCh. 14.11 - Prob. 1QQCh. 14.11 - Prob. 2QQCh. 14.11 - Prob. 3QQCh. 14.12 - Prob. 1QQCh. 14.12 - Prob. 2QQCh. 14.13 - Prob. 1QQCh. 14.13 - Prob. 2QQCh. 14.13 - Prob. 3QQCh. 14.14 - Prob. 1QQCh. 14.14 - Prob. 2QQCh. 14.14 - Prob. 3QQCh. 14.15 - Prob. 1QQCh. 14.15 - Prob. 2QQCh. 14.15 - Prob. 3QQCh. 14.15 - Prob. 4QQCh. 14.16 - Prob. 1QQCh. 14.16 - Prob. 2QQCh. 14.17 - Prob. 1QQCh. 14.17 - Prob. 2QQCh. 14.17 - Prob. 3QQCh. 14.18 - Prob. 1QQCh. 14.18 - Prob. 2QQCh. 14.18 - Prob. 3QQCh. 14.19 - Prob. 1QQCh. 14.19 - Prob. 2QQCh. 14.20 - Prob. 1QQCh. 14.20 - Prob. 2QQCh. 14.20 - Prob. 3QQCh. 14.20 - Prob. 4QQCh. 14.20 - Prob. 5QQCh. 14.21 - Prob. 1QQCh. 14.21 - Prob. 2QQCh. 14.21 - Prob. 3QQCh. 14.21 - Prob. 4QQCh. 14.21 - Prob. 5QQCh. 14 - Prob. 14.1EPCh. 14 - Prob. 14.2EPCh. 14 - Prob. 14.3EPCh. 14 - Prob. 14.4EPCh. 14 - Prob. 14.5EPCh. 14 - Prob. 14.6EPCh. 14 - Prob. 14.7EPCh. 14 - Prob. 14.8EPCh. 14 - Prob. 14.9EPCh. 14 - Prob. 14.10EPCh. 14 - Write a condensed structural formula for each of...Ch. 14 - Write a condensed structural formula for each of...Ch. 14 - Prob. 14.13EPCh. 14 - Prob. 14.14EPCh. 14 - Prob. 14.15EPCh. 14 - Prob. 14.16EPCh. 14 - Prob. 14.17EPCh. 14 - Prob. 14.18EPCh. 14 - Each of the following alcohols is named...Ch. 14 - Prob. 14.20EPCh. 14 - Prob. 14.21EPCh. 14 - Prob. 14.22EPCh. 14 - Prob. 14.23EPCh. 14 - Prob. 14.24EPCh. 14 - Prob. 14.25EPCh. 14 - Prob. 14.26EPCh. 14 - Prob. 14.27EPCh. 14 - Prob. 14.28EPCh. 14 - Prob. 14.29EPCh. 14 - Prob. 14.30EPCh. 14 - Prob. 14.31EPCh. 14 - Prob. 14.32EPCh. 14 - Prob. 14.33EPCh. 14 - Prob. 14.34EPCh. 14 - Explain why the boiling points of alcohols are...Ch. 14 - Explain why the water solubilities of alcohols are...Ch. 14 - Prob. 14.37EPCh. 14 - Prob. 14.38EPCh. 14 - Prob. 14.39EPCh. 14 - Which member of each of the following pairs of...Ch. 14 - Determine the maximum number of hydrogen bonds...Ch. 14 - Determine the maximum number of hydrogen bonds...Ch. 14 - Prob. 14.43EPCh. 14 - Prob. 14.44EPCh. 14 - Prob. 14.45EPCh. 14 - Prob. 14.46EPCh. 14 - Classify each of the following alcohols as a...Ch. 14 - Classify each of the following alcohols as a...Ch. 14 - Classify each of the following alcohols as a...Ch. 14 - Classify each of the following alcohols as a...Ch. 14 - Prob. 14.51EPCh. 14 - Prob. 14.52EPCh. 14 - Prob. 14.53EPCh. 14 - Prob. 14.54EPCh. 14 - Prob. 14.55EPCh. 14 - Prob. 14.56EPCh. 14 - Prob. 14.57EPCh. 14 - Prob. 14.58EPCh. 14 - Prob. 14.59EPCh. 14 - Prob. 14.60EPCh. 14 - The alcohol 2,2-dimethyl-1-butanol cannot be...Ch. 14 - Prob. 14.62EPCh. 14 - Prob. 14.63EPCh. 14 - Prob. 14.64EPCh. 14 - Draw the structure of the aldehyde or ketone...Ch. 14 - Draw the structure of the aldehyde or ketone...Ch. 14 - Prob. 14.67EPCh. 14 - Prob. 14.68EPCh. 14 - Prob. 14.69EPCh. 14 - Prob. 14.70EPCh. 14 - Three isomeric pentanols with unbranched carbon...Ch. 14 - Prob. 14.72EPCh. 14 - Prob. 14.73EPCh. 14 - Prob. 14.74EPCh. 14 - Prob. 14.75EPCh. 14 - Prob. 14.76EPCh. 14 - Prob. 14.77EPCh. 14 - Prob. 14.78EPCh. 14 - Prob. 14.79EPCh. 14 - Prob. 14.80EPCh. 14 - Prob. 14.81EPCh. 14 - Prob. 14.82EPCh. 14 - Prob. 14.83EPCh. 14 - Prob. 14.84EPCh. 14 - Prob. 14.85EPCh. 14 - Prob. 14.86EPCh. 14 - Prob. 14.87EPCh. 14 - Prob. 14.88EPCh. 14 - Prob. 14.89EPCh. 14 - Prob. 14.90EPCh. 14 - Prob. 14.91EPCh. 14 - Classify each of the following compounds as an...Ch. 14 - Draw or write the following for the simplest ether...Ch. 14 - Draw or write the following for the simplest ether...Ch. 14 - Prob. 14.95EPCh. 14 - Prob. 14.96EPCh. 14 - Prob. 14.97EPCh. 14 - Prob. 14.98EPCh. 14 - Prob. 14.99EPCh. 14 - Prob. 14.100EPCh. 14 - Prob. 14.101EPCh. 14 - Prob. 14.102EPCh. 14 - Prob. 14.103EPCh. 14 - Prob. 14.104EPCh. 14 - Prob. 14.105EPCh. 14 - Prob. 14.106EPCh. 14 - Prob. 14.107EPCh. 14 - Prob. 14.108EPCh. 14 - Prob. 14.109EPCh. 14 - Prob. 14.110EPCh. 14 - Prob. 14.111EPCh. 14 - Prob. 14.112EPCh. 14 - Prob. 14.113EPCh. 14 - Give common names for all ethers that are...Ch. 14 - How many isomeric ethers exist when the R groups...Ch. 14 - Prob. 14.116EPCh. 14 - Prob. 14.117EPCh. 14 - Draw condensed structural formulas for the...Ch. 14 - Prob. 14.119EPCh. 14 - Prob. 14.120EPCh. 14 - Prob. 14.121EPCh. 14 - Prob. 14.122EPCh. 14 - Prob. 14.123EPCh. 14 - How do the chemical reactivities of ethers compare...Ch. 14 - Explain why ether molecules cannot hydrogen-bond...Ch. 14 - How many hydrogen bonds can form between a single...Ch. 14 - Classify each of the following molecular...Ch. 14 - Classify each of the following molecular...Ch. 14 - Prob. 14.129EPCh. 14 - Prob. 14.130EPCh. 14 - Prob. 14.131EPCh. 14 - Draw a condensed structural formula for each of...Ch. 14 - Prob. 14.133EPCh. 14 - Prob. 14.134EPCh. 14 - Prob. 14.135EPCh. 14 - Prob. 14.136EPCh. 14 - Prob. 14.137EPCh. 14 - For each of the following pairs of compounds,...Ch. 14 - Assign an IUPAC name to each of the following...Ch. 14 - Prob. 14.140EPCh. 14 - Prob. 14.141EPCh. 14 - Prob. 14.142EPCh. 14 - Prob. 14.143EPCh. 14 - Prob. 14.144EPCh. 14 - Prob. 14.145EPCh. 14 - Prob. 14.146EP
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