The member that is expected to be more soluble among the given pair has to be identified. Concept Introduction: Alcohol is an organic compound that has hydroxyl as its functional group . Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate. Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 1

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 3

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 4

Question

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

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Answer 5

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 6

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 7

Chapter 14, Problem 14.39EP

(a)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The member that is expected to be more soluble among the given pair has to be identified.

Concept Introduction:

Alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it. Hydroxyl group is the polar group and the alkyl group is the nonpolar group. Physical properties of alcohol depend on which of the two groups dominate.

Alcohols are soluble in water because of the polar hydroxyl group that is present in alcohol. If the length of the carbon chain is too large, then the solubility of alcohol in water will decrease. Generally alcohols have more solubility than alkanes of same molecular mass due to its ability to form hydrogen bonding with water molecules.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

Solution Summary: The author explains that alcohol is an organic compound that has hydroxyl as its functional group. Alcohols contain both nonpolar and polar groups in it.

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Chapter 14 Solutions