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Bundle: General, Organic, and Biological Chemistry, 7th + OWLv2 Quick Prep for General Chemistry, 4 terms (24 months) Printed Access Card
7th Edition
ISBN: 9781305717534
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Question
Chapter 13.4, Problem 1QQ
Interpretation Introduction
Interpretation:
The correct IUPAC name for the given compound has to be chosen from the given options.
Concept Introduction:
- The suffix –ane has to be replaced with the suffix –ene. This is used to indicate the presence of double bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond. In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
- Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
- In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
- In case if substituents are present in cycloalkene, then the double‑bonded carbon
atoms are numbered 1 and 2 in a direction where the substituent gets the lower number. - If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula. To indicate a double bond between carbon atom, double line is used.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 13 Solutions
Bundle: General, Organic, and Biological Chemistry, 7th + OWLv2 Quick Prep for General Chemistry, 4 terms (24 months) Printed Access Card
Ch. 13.1 - Prob. 1QQCh. 13.1 - Prob. 2QQCh. 13.1 - Prob. 3QQCh. 13.2 - Prob. 1QQCh. 13.2 - Prob. 2QQCh. 13.2 - Prob. 3QQCh. 13.2 - Prob. 4QQCh. 13.3 - Prob. 1QQCh. 13.3 - Prob. 2QQCh. 13.3 - Prob. 3QQ
Ch. 13.3 - Prob. 4QQCh. 13.4 - Prob. 1QQCh. 13.4 - Prob. 2QQCh. 13.5 - Prob. 1QQCh. 13.5 - Prob. 2QQCh. 13.5 - Prob. 3QQCh. 13.6 - Prob. 1QQCh. 13.6 - Prob. 2QQCh. 13.6 - Prob. 3QQCh. 13.7 - Prob. 1QQCh. 13.7 - Prob. 2QQCh. 13.7 - Prob. 3QQCh. 13.8 - Prob. 1QQCh. 13.8 - Prob. 2QQCh. 13.9 - Prob. 1QQCh. 13.9 - Prob. 2QQCh. 13.10 - Prob. 1QQCh. 13.10 - Prob. 2QQCh. 13.10 - Prob. 3QQCh. 13.10 - Prob. 4QQCh. 13.10 - Prob. 5QQCh. 13.11 - Prob. 1QQCh. 13.11 - Prob. 2QQCh. 13.11 - Prob. 3QQCh. 13.11 - Prob. 4QQCh. 13.11 - Prob. 5QQCh. 13.12 - Prob. 1QQCh. 13.12 - Prob. 2QQCh. 13.12 - Prob. 3QQCh. 13.12 - Prob. 4QQCh. 13.12 - Prob. 5QQCh. 13.13 - Prob. 1QQCh. 13.13 - Prob. 2QQCh. 13.13 - Prob. 3QQCh. 13.14 - Prob. 1QQCh. 13.14 - Prob. 2QQCh. 13.14 - Prob. 3QQCh. 13.14 - Prob. 4QQCh. 13.15 - Prob. 1QQCh. 13.15 - Prob. 2QQCh. 13.15 - Prob. 3QQCh. 13.15 - Prob. 4QQCh. 13.16 - Prob. 1QQCh. 13.16 - Prob. 2QQCh. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Prob. 13.3EPCh. 13 - Prob. 13.4EPCh. 13 - Prob. 13.5EPCh. 13 - Prob. 13.6EPCh. 13 - Prob. 13.7EPCh. 13 - Prob. 13.8EPCh. 13 - Prob. 13.9EPCh. 13 - What is the molecular formula for each of the...Ch. 13 - Prob. 13.11EPCh. 13 - Prob. 13.12EPCh. 13 - What is wrong, if anything, with the following...Ch. 13 - Prob. 13.14EPCh. 13 - Prob. 13.15EPCh. 13 - Prob. 13.16EPCh. 13 - Prob. 13.17EPCh. 13 - Prob. 13.18EPCh. 13 - Draw a condensed structural formula for each of...Ch. 13 - Draw a condensed structural formula for each of...Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - Prob. 13.23EPCh. 13 - Prob. 13.24EPCh. 13 - Prob. 13.25EPCh. 13 - Classify each of the following compounds as...Ch. 13 - Prob. 13.27EPCh. 13 - How many hydrogen atoms are present in a molecule...Ch. 13 - Prob. 13.29EPCh. 13 - Draw a line-angle structural formula for each of...Ch. 13 - Prob. 13.31EPCh. 13 - Prob. 13.32EPCh. 13 - Prob. 13.33EPCh. 13 - Prob. 13.34EPCh. 13 - Prob. 13.35EPCh. 13 - Prob. 13.36EPCh. 13 - Prob. 13.37EPCh. 13 - Prob. 13.38EPCh. 13 - For each of the following pairs of alkenes,...Ch. 13 - Prob. 13.40EPCh. 13 - Prob. 13.41EPCh. 13 - Prob. 13.42EPCh. 13 - Prob. 13.43EPCh. 13 - Prob. 13.44EPCh. 13 - Prob. 13.45EPCh. 13 - Prob. 13.46EPCh. 13 - For each molecule, indicate whether cistrans...Ch. 13 - For each molecule, indicate whether cistrans...Ch. 13 - Prob. 13.49EPCh. 13 - Prob. 13.50EPCh. 13 - Prob. 13.51EPCh. 13 - Draw a structural formula for each of the...Ch. 13 - Prob. 13.53EPCh. 13 - Prob. 13.54EPCh. 13 - Prob. 13.55EPCh. 13 - Prob. 13.56EPCh. 13 - Prob. 13.57EPCh. 13 - Prob. 13.58EPCh. 13 - Why is the number of carbon atoms in a terpene...Ch. 13 - How many isoprene units are present in a....Ch. 13 - Prob. 13.61EPCh. 13 - Indicate whether each of the following statements...Ch. 13 - Prob. 13.63EPCh. 13 - With the help of Figure 13-7, indicate whether...Ch. 13 - Prob. 13.65EPCh. 13 - Prob. 13.66EPCh. 13 - Prob. 13.67EPCh. 13 - Prob. 13.68EPCh. 13 - Prob. 13.69EPCh. 13 - Prob. 13.70EPCh. 13 - Prob. 13.71EPCh. 13 - Prob. 13.72EPCh. 13 - Prob. 13.73EPCh. 13 - Prob. 13.74EPCh. 13 - Prob. 13.75EPCh. 13 - Write a chemical equation showing reactants,...Ch. 13 - Supply the structural formula of the product in...Ch. 13 - Prob. 13.78EPCh. 13 - What reactant would you use to prepare each of the...Ch. 13 - Prob. 13.80EPCh. 13 - Prob. 13.81EPCh. 13 - Prob. 13.82EPCh. 13 - Prob. 13.83EPCh. 13 - Prob. 13.84EPCh. 13 - Prob. 13.85EPCh. 13 - Prob. 13.86EPCh. 13 - Prob. 13.87EPCh. 13 - Prob. 13.88EPCh. 13 - Prob. 13.89EPCh. 13 - Prob. 13.90EPCh. 13 - Prob. 13.91EPCh. 13 - Prob. 13.92EPCh. 13 - Prob. 13.93EPCh. 13 - What are the bond angles about the triple bond in...Ch. 13 - Prob. 13.95EPCh. 13 - Prob. 13.96EPCh. 13 - Prob. 13.97EPCh. 13 - Prob. 13.98EPCh. 13 - Prob. 13.99EPCh. 13 - Prob. 13.100EPCh. 13 - Prob. 13.101EPCh. 13 - Prob. 13.102EPCh. 13 - Prob. 13.103EPCh. 13 - Prob. 13.104EPCh. 13 - Prob. 13.105EPCh. 13 - Prob. 13.106EPCh. 13 - Prob. 13.107EPCh. 13 - Prob. 13.108EPCh. 13 - Assign each of the compounds in Problem 13-107 an...Ch. 13 - Assign each of the compounds in Problem 13-108 an...Ch. 13 - Prob. 13.111EPCh. 13 - Prob. 13.112EPCh. 13 - Prob. 13.113EPCh. 13 - Prob. 13.114EPCh. 13 - Prob. 13.115EPCh. 13 - Write a structural formula for each of the...Ch. 13 - Eight isomeric substituted benzenes have the...Ch. 13 - Prob. 13.118EPCh. 13 - Prob. 13.119EPCh. 13 - Prob. 13.120EPCh. 13 - Prob. 13.121EPCh. 13 - Prob. 13.122EPCh. 13 - Prob. 13.123EPCh. 13 - Prob. 13.124EPCh. 13 - Prob. 13.125EPCh. 13 - For each of the following classes of compounds,...Ch. 13 - Prob. 13.127EPCh. 13 - Prob. 13.128EPCh. 13 - Prob. 13.129EPCh. 13 - Prob. 13.130EP
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