(a) Interpretation: Structural formula for the alcohol formed by acid-catalyzed hydration of 2-methyl-2-butene should be determined. Concept Introduction: According to Markovnikov’s rule, in acid-catalyzed hydration of alkenes , H of H 2 O adds to the carbon of the double bond with greater number of hydrogen atoms and OH of H 2 O adds to the carbon with smaller number of hydrogen atoms.

Question

b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

Answer 1

Question

Chapter 12.5, Problem 12.8QC

Interpretation Introduction

(a)

Interpretation:

Structural formula for the alcohol formed by acid-catalyzed hydration of 2-methyl-2-butene should be determined.

Concept Introduction:

According to Markovnikov’s rule, in acid-catalyzed hydration of alkenes, H of H₂ O adds to the carbon of the double bond with greater number of hydrogen atoms and OH of H₂ O adds to the carbon with smaller number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

Structural formula for the alcohol formed by acid-catalyzed hydration of the given alkene should be determined.

Concept Introduction:

According to Markovnikov’s rule, in acid-catalyzed hydration of alkenes, H of H₂ O adds to the carbon of the double bond with greater number of hydrogen atoms and OH of H₂ O adds to the carbon with smaller number of hydrogen atoms.

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