Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Question
Chapter 12.3, Problem 12.8YT
Interpretation Introduction
Interpretation:
Five organic and inorganic compounds have to be listed with its context.
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Students have asked these similar questions
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly
where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial
credit will be given. Note: You may need to draw in lone pairs before drawing the arrows.
A.
B.
H-Br
人
C
Θ
CI
H
Cl
Θ
+
Br
O
Chapter 12 Solutions
Chemistry In Context
Ch. 12.1 - Skill Building Finding Equilibrium Glucose and...Ch. 12.1 - Prob. 12.3YTCh. 12.1 - Prob. 12.4YTCh. 12.2 - Prob. 12.5YTCh. 12.2 - Prob. 12.6YTCh. 12.2 - A practicing scientist must Judge a potential...Ch. 12.3 - Prob. 12.8YTCh. 12.3 - Skill Building Checking on Carbon a. Examine the...Ch. 12.3 - Prob. 12.10YTCh. 12.3 - Prob. 12.11YT
Ch. 12.3 - Prob. 12.12YTCh. 12.4 - Prob. 12.13YTCh. 12.4 - Skill Building Functional Groups in Dopamine Draw...Ch. 12.4 - Prob. 12.15YTCh. 12.5 - Prob. 12.16YTCh. 12.5 - Prob. 12.17YTCh. 12.6 - Prob. 12.18YTCh. 12.6 - Prob. 12.19YTCh. 12.6 - The structures of proteins, such as the ones shown...Ch. 12.7 - Reconsider your work in past chapters. List three...Ch. 12.7 - Prob. 12.22YTCh. 12.7 - Prob. 12.23YTCh. 12.8 - Prob. 12.24YTCh. 12.8 - Prob. 12.25YTCh. 12.9 - Skill Building Ester Formation Draw structural...Ch. 12.9 - Prob. 12.27YTCh. 12.9 - You Decide Supersize My Aspirin A friend who...Ch. 12.9 - Modern methods of drug discovery involve...Ch. 12.10 - Make two lists of drugs for each of the two...Ch. 12.10 - See for yourself the shapes of drug molecules by...Ch. 12.10 - Prob. 12.33YTCh. 12.10 - Prob. 12.34YTCh. 12 - Scientific Practices Follow the Hormone Using the...Ch. 12 - The field of chemistry has many sub-disciplines....Ch. 12 - Prob. 2QCh. 12 - Prob. 4QCh. 12 - Nitrous acid (HNO2) has a Ka value of 4.0 10 4,...Ch. 12 - Use the Henderson-Hasselbalch equation and Table...Ch. 12 - Write the structural formula and line-angle...Ch. 12 - Prob. 8QCh. 12 - Prob. 9QCh. 12 - Prob. 10QCh. 12 - Prob. 11QCh. 12 - Prob. 12QCh. 12 - Estradiol is relatively insoluble in water but...Ch. 12 - Prob. 14QCh. 12 - Prob. 15QCh. 12 - Prob. 16QCh. 12 - Define and relate the two terms: hormone and...Ch. 12 - Refer to Figure 11.17. Select two examples of...Ch. 12 - Prob. 19QCh. 12 - Molecules as diverse as cholesterol, sex hormones,...Ch. 12 - Prob. 21QCh. 12 - Prob. 22QCh. 12 - Prob. 23QCh. 12 - Sulfanilamide is the simplest sulfa drug, a type...Ch. 12 - Explain why an equilibrium constant cannot tell...Ch. 12 - Use the information in Table 12.1 to redraw Figure...Ch. 12 - Draw structural formulas for each of these...Ch. 12 - In Your Turn 12.12, you were asked to draw...Ch. 12 - Prob. 29QCh. 12 - Prob. 30QCh. 12 - Prob. 31QCh. 12 - Prob. 32QCh. 12 - Prob. 34QCh. 12 - Prob. 35QCh. 12 - Prob. 36QCh. 12 - Prob. 37QCh. 12 - Prob. 38QCh. 12 - The text states that some racemic mixtures contain...Ch. 12 - Prob. 40QCh. 12 - Prob. 41QCh. 12 - Prob. 44QCh. 12 - Prob. 47QCh. 12 - Prob. 49QCh. 12 - Dorothy Crowfoot Hodgkin first determined the...Ch. 12 - Prob. 52Q
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- 4. For the reactions below, draw the expected product. Be sure to indicate relevant stereochemistry or formal charges in the product structure. a) CI, H e b) H lux ligh Br 'Harrow_forwardArrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidityarrow_forward1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)arrow_forward
- Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…arrow_forwardPropose a synthesis pathway for the following transformations. b) c) d)arrow_forwardThe rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.arrow_forward
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- In the drawing area below, draw the major products of this organic reaction: 1. NaOH ? 2. CH3Br If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. No reaction. Click and drag to start drawing a structure. ☐ : A คarrow_forwardPredict the major products of the following organic reaction: NC Δ ? Some important Notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to draw bonds carefully to show important geometric relationships between substituents. Note: if your answer contains a complicated ring structure, you must use one of the molecular fragment stamps (available in the menu at right) to enter the ring structure. You can add any substituents using the pencil tool in the usual way. Click and drag to start drawing a structure. Х аarrow_forwardPredict the major products of this organic reaction. Be sure you use dash and wedge bonds to show stereochemistry where it's important. + ☑ OH 1. TsCl, py .... 文 P 2. t-BuO K Click and drag to start drawing a structure.arrow_forward
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