
Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Question
Chapter 12, Problem 29Q
Interpretation Introduction
Interpretation:
Like benzene, the structural formulas of styrene resonance structures have to be shown.
Concept Introduction:
- Polymer: A polymer is a long molecule formed by joining together of thousands of small molecular units by
chemical bonds. - Monomers: Small molecules which combine together to form polymer molecules are known as Monomers.
Polymers are large molecules made of chains of monomers, small molecules that link together.Polymerization is the formation of polymers from these small units (or) macromolecules formed by the covalent attachment of a set of small molecules termed as monomers.- Polymer can occur naturally (proteins, carbohydrates) and can be synthesized nylon, Teflon, Polyethylene, etc.,
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 12 Solutions
Chemistry In Context
Ch. 12.1 - Skill Building Finding Equilibrium Glucose and...Ch. 12.1 - Prob. 12.3YTCh. 12.1 - Prob. 12.4YTCh. 12.2 - Prob. 12.5YTCh. 12.2 - Prob. 12.6YTCh. 12.2 - A practicing scientist must Judge a potential...Ch. 12.3 - Prob. 12.8YTCh. 12.3 - Skill Building Checking on Carbon a. Examine the...Ch. 12.3 - Prob. 12.10YTCh. 12.3 - Prob. 12.11YT
Ch. 12.3 - Prob. 12.12YTCh. 12.4 - Prob. 12.13YTCh. 12.4 - Skill Building Functional Groups in Dopamine Draw...Ch. 12.4 - Prob. 12.15YTCh. 12.5 - Prob. 12.16YTCh. 12.5 - Prob. 12.17YTCh. 12.6 - Prob. 12.18YTCh. 12.6 - Prob. 12.19YTCh. 12.6 - The structures of proteins, such as the ones shown...Ch. 12.7 - Reconsider your work in past chapters. List three...Ch. 12.7 - Prob. 12.22YTCh. 12.7 - Prob. 12.23YTCh. 12.8 - Prob. 12.24YTCh. 12.8 - Prob. 12.25YTCh. 12.9 - Skill Building Ester Formation Draw structural...Ch. 12.9 - Prob. 12.27YTCh. 12.9 - You Decide Supersize My Aspirin A friend who...Ch. 12.9 - Modern methods of drug discovery involve...Ch. 12.10 - Make two lists of drugs for each of the two...Ch. 12.10 - See for yourself the shapes of drug molecules by...Ch. 12.10 - Prob. 12.33YTCh. 12.10 - Prob. 12.34YTCh. 12 - Scientific Practices Follow the Hormone Using the...Ch. 12 - The field of chemistry has many sub-disciplines....Ch. 12 - Prob. 2QCh. 12 - Prob. 4QCh. 12 - Nitrous acid (HNO2) has a Ka value of 4.0 10 4,...Ch. 12 - Use the Henderson-Hasselbalch equation and Table...Ch. 12 - Write the structural formula and line-angle...Ch. 12 - Prob. 8QCh. 12 - Prob. 9QCh. 12 - Prob. 10QCh. 12 - Prob. 11QCh. 12 - Prob. 12QCh. 12 - Estradiol is relatively insoluble in water but...Ch. 12 - Prob. 14QCh. 12 - Prob. 15QCh. 12 - Prob. 16QCh. 12 - Define and relate the two terms: hormone and...Ch. 12 - Refer to Figure 11.17. Select two examples of...Ch. 12 - Prob. 19QCh. 12 - Molecules as diverse as cholesterol, sex hormones,...Ch. 12 - Prob. 21QCh. 12 - Prob. 22QCh. 12 - Prob. 23QCh. 12 - Sulfanilamide is the simplest sulfa drug, a type...Ch. 12 - Explain why an equilibrium constant cannot tell...Ch. 12 - Use the information in Table 12.1 to redraw Figure...Ch. 12 - Draw structural formulas for each of these...Ch. 12 - In Your Turn 12.12, you were asked to draw...Ch. 12 - Prob. 29QCh. 12 - Prob. 30QCh. 12 - Prob. 31QCh. 12 - Prob. 32QCh. 12 - Prob. 34QCh. 12 - Prob. 35QCh. 12 - Prob. 36QCh. 12 - Prob. 37QCh. 12 - Prob. 38QCh. 12 - The text states that some racemic mixtures contain...Ch. 12 - Prob. 40QCh. 12 - Prob. 41QCh. 12 - Prob. 44QCh. 12 - Prob. 47QCh. 12 - Prob. 49QCh. 12 - Dorothy Crowfoot Hodgkin first determined the...Ch. 12 - Prob. 52Q
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