Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 12, Problem 76E

The reaction of CO with CI2 gives phosgene (COCI2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:

CI 2 ( g ) 2 CI ( g ) (fast, k1 represents the forward rate constant, k-1 the reverse rate constant)

CO ( g ) + CI ( g ) COCI ( g ) (slow, k2 the rate constant)

COCI ( g ) + CI ( g ) COCI 2 ( g ) (fast, k3 the rate constant)

(a) Write the overall reaction.

(b) Identify all intermediates.

(c) Write the rate law for each elementary reaction.

(d) Write the overall rate law expression.

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Chapter 12 Solutions

Chemistry by OpenStax (2015-05-04)

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