A study of the rate of dimerization of C 4 H 6 gave the data shown in the table: 2 C 4 H 6 → C 8 H 12 (a) Determine the average rate of dimerization between 0 s and 1600 s, and between 1600 s and 3200 s. (b) Estimate the instantaneous rate of dimerization at 3200 s from a graph of time versus [C 4 H 6 ]. What are the units of this rate? (c) Determine the average rate of formation of C 8 H 1 2 at 1600 s and the instantaneous rate of formation at 3200 s from the rates found in parts (a) and (b).
A study of the rate of dimerization of C 4 H 6 gave the data shown in the table: 2 C 4 H 6 → C 8 H 12 (a) Determine the average rate of dimerization between 0 s and 1600 s, and between 1600 s and 3200 s. (b) Estimate the instantaneous rate of dimerization at 3200 s from a graph of time versus [C 4 H 6 ]. What are the units of this rate? (c) Determine the average rate of formation of C 8 H 1 2 at 1600 s and the instantaneous rate of formation at 3200 s from the rates found in parts (a) and (b).
A study of the rate of dimerization of C4H6 gave the data shown in the table:
2
C
4
H
6
→
C
8
H
12
(a) Determine the average rate of dimerization between 0 s and 1600 s, and between 1600 s and 3200 s. (b) Estimate the instantaneous rate of dimerization at 3200 s from a graph of time versus [C4H6]. What are the units of this rate? (c) Determine the average rate of formation of C8H12 at 1600 s and the instantaneous rate of formation at 3200 s from the rates found in parts (a) and (b).
Topic: Photochemistry and Photophysics of Supramolecules
Two cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 C
With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.
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