Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 12, Problem 51E
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 12 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 12 - What is the difference between average rate,...Ch. 12 - Ozone decomposes to oxygen according to the...Ch. 12 - In the nuclear industry, chlorine trifluoride is...Ch. 12 - A study of the rate of dimerization of C4H6 gave...Ch. 12 - A study of the rate of the reaction represented as...Ch. 12 - Consider the following reaction in aqueous...Ch. 12 - Describe the effect of each of the following on...Ch. 12 - Explain why an egg cooks move slowly in boiling...Ch. 12 - Go to the PhET Reactions and change to Angled...Ch. 12 - In the PhET Reactions tab to observe how multiple...
Ch. 12 - In the PhET Reactions under Options. (a) Leave...Ch. 12 - How do the rate of a reaction and its rate...Ch. 12 - Doubling the concentration of a reactant increases...Ch. 12 - Tripling the concentration of a reactant increases...Ch. 12 - How much and in what direction will each of the...Ch. 12 - How will each of the following affect the rate of...Ch. 12 - Regular ?ights of supersonic aircraft in the...Ch. 12 - Radioactive phosphorus is used in the study of...Ch. 12 - The rate constant for the radioactive decay of 14C...Ch. 12 - The decomposition of acetaldehyde is a second...Ch. 12 - Alcohol is removed from the bloodstream by a...Ch. 12 - Under certain conditions the decomposition of...Ch. 12 - Nitrosyl chloride, NOCI, decomposes to NO and CI2....Ch. 12 - From the following data, determine the rate...Ch. 12 - Nitrogen monoxide reacts with chlorine according...Ch. 12 - Hydrogen reacts with nitrogen monoxide to form...Ch. 12 - For the reaction AB+C, the following data were...Ch. 12 - For the reaction QW+X, the following data were...Ch. 12 - The rate constant for the ?rst-order decomposition...Ch. 12 - The annual production of HNO3 in 2013 was 60...Ch. 12 - The following data have been determined for the...Ch. 12 - Describe how graphical methods can be used to...Ch. 12 - Use the data provided to graphically determine the...Ch. 12 - Use the data provided in a graphical method to...Ch. 12 - Pure ozone decomposes slowly to oxygen, 2O33O2(g)....Ch. 12 - From the given data, use a graphical method to...Ch. 12 - What is the half-life for the first-order decay of...Ch. 12 - What is the half-life for the first-order decay of...Ch. 12 - What is the half-life for the decomposition of...Ch. 12 - What is the half-life for the decomposition of O3...Ch. 12 - The reaction of compound A to give compounds C and...Ch. 12 - The half-life of a reaction of compound A to give...Ch. 12 - Some bacteria are resistant to the antibiotic...Ch. 12 - Both technetium-99 and thallium-201 are used to...Ch. 12 - There are two molecules with the formula C3H6...Ch. 12 - Fluorine-18 is a radioactive isotope that decays...Ch. 12 - Suppose that the half-life of steroids taken by an...Ch. 12 - Recently, the skeleton of King Richard III was...Ch. 12 - Nitroglycerine is an extremely sensitive...Ch. 12 - For the past 10 years, the unsaturated hydrocarbon...Ch. 12 - Chemical reactions occur when reactants collide....Ch. 12 - When every collision between reactants leads to a...Ch. 12 - What is the activation energy of a reaction, and...Ch. 12 - Account for the relationship between the rate of a...Ch. 12 - Describe how graphical methods can be used to...Ch. 12 - How does an increase in temperature affect rate of...Ch. 12 - The rate of a certain reaction doubles for every...Ch. 12 - In an experiment, a sample of NaClO3 was 90%...Ch. 12 - The rate constant at 325 C for the decomposition...Ch. 12 - The rate constant for the decomposition of...Ch. 12 - An elevated level of the enzyme alkaline...Ch. 12 - In terms of collision theory, to which of the...Ch. 12 - Hydrogen iodide, HI, decomposes in the gas phase...Ch. 12 - The element Co exists in two oxidation states,...Ch. 12 - The hydrolysis of the sugar sucrose to the sugars...Ch. 12 - Use the PhET Reactions Single collision" tab of...Ch. 12 - Use the PhET Reactions Single collision tab of the...Ch. 12 - Why awe elementary reactions involving three or...Ch. 12 - In general, can we predict the effect of doubling...Ch. 12 - Define these terms: (a) unimolecular reaction (b)...Ch. 12 - What is the rate equation for the elementary...Ch. 12 - Given the following reactions and the...Ch. 12 - Write the rate equation for each of the following...Ch. 12 - Nitrogen (Il) oxide, NO, reacts with hydrogen, H2,...Ch. 12 - Experiments were conducted to study the rate of...Ch. 12 - The reaction of CO with CI2 gives phosgene...Ch. 12 - . Account for the increase in reaction rate...Ch. 12 - Compare the functions of homogeneous and...Ch. 12 - Consider this scenario and answer the following...Ch. 12 - For each of the following pairs of reaction...Ch. 12 - For each of the following pairs of reaction...Ch. 12 - For each of the following reaction diagrams,...Ch. 12 - For each of the following reaction diagrams,...Ch. 12 - Based on the diagrams in Exercise 12.83, which of...Ch. 12 - Based on the diagram in Exercise 12.83, which of...
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- Zeroth Order Reaction In a certain experiment the decomposition of hydrogen iodide on finely divided gold is zeroth order with respect to HI. 2HI(g) Au H2(g) + 12(9) Rate = -d[HI]/dt k = 2.00x104 mol L-1 s-1 If the experiment has an initial HI concentration of 0.460 mol/L, what is the concentration of HI after 28.0 minutes? 1 pts Submit Answer Tries 0/5 How long will it take for all of the HI to decompose? 1 pts Submit Answer Tries 0/5 What is the rate of formation of H2 16.0 minutes after the reaction is initiated? 1 pts Submit Answer Tries 0/5arrow_forwardangelarodriguezmunoz149@gmail.com Hi i need help with this question i am not sure what the right answers are.arrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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