Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 12, Problem 49E
Which orbitals of each atom overlap in forming a bond between bromine and oxygen?
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4.
a) Give a suitable rationale for the following cyclization, stating the type of process involved
(e.g. 9-endo-dig), clearly showing the mechanistic details at each step.
H
CO₂Me
1) NaOMe
2) H3O®
CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for
unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be
catalyzed the propylene molecules must first adsorb onto the surface. In order to completely
cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total
of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that
have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
Chapter 12 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 12 - Write the electronic configuration for the ions of...Ch. 12 - A monoatomic ion with a charge of 1 has an...Ch. 12 - Identify by symbol two positively charged...Ch. 12 - Considering only ions with charges of 1+,2+,1, and...Ch. 12 - Write the symbols of two ions that are...Ch. 12 - Considering only ions with charges of 1+,2+,1, and...Ch. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - When potassium and chlorine react and form an...Ch. 12 - Fill in the blanks with the smallest integers...
Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Consider the following bonds: GeSe, BrSe, BrGe....Ch. 12 - Prob. 23ECh. 12 - Consider the following bonds: TeSe, OTe, OSe....Ch. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - What is the maximum number of atoms to which a...Ch. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Which orbitals of each atom overlap in forming a...Ch. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - A monatomic ion with a 2 charge has the electron...Ch. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Which ions among the following are isoelectronic...Ch. 12 - Prob. 12.2TCCh. 12 - Prob. 12.3TCCh. 12 - Prob. 12.4TCCh. 12 - Prob. 12.5TCCh. 12 - Prob. 1CLECh. 12 - Prob. 2CLECh. 12 - Prob. 3CLECh. 12 - Prob. 4CLECh. 12 - Prob. 5CLECh. 12 - Prob. 6CLECh. 12 - Write the electron configurations for the oxide...Ch. 12 - Arrange the following bonds in order of decreasing...
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