Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Question
Chapter 12, Problem 59E
Interpretation Introduction
Interpretation:
Lewis diagram for both the iodides
Concept introduction:
Lewis diagram is the electron dot model of the diagram showing each pair of electrons between the two atoms leading to the formation of one covalent bond.
Lewis diagrams follow the octet rule when drawn. That is, the total number of electrons around each can be maximum eight.
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Draw all of the Lewis structures of O22- which obey the octet rule and use this Lewis structure or these resonance structures to predict how many covalent bonds connect each oxygen atom in the real structure to the central O atom. Assume that the octet rule is followed for the O atom when you draw your structure(s). Pick the correct statement from the choices below.
a) Each oxygen atom is connected to the central O atom with 1 covalent bonds.
b) Each oxygen atom is connected to the central O atom with 1.33 covalent bonds.
c) Each oxygen atom is connected to the central O atom with 2 covalent bonds.
d) Each oxygen atom is connected to the central O atom with 1.67 covalent bonds.
e) Each oxygen atom is connected to the central O atom with 1.25 covalent bonds.
Draw possible dot structures of PO4³- and
NO4³- that fulfill the octet rule. One structure
is stable the other is not. Explain why one is
stable and the other does not exist. Use the
fact that nitrogen atom is smaller than
phosphorous atom, and possible repulsion of
the lone electron pairs on the oxygen atoms
due to their closeness to explain why one
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Answer the questions in the table below about the shape of the phosphorus trifluoride (PF3) molecule.
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Note: one "electron group" means one lone pair, one single bond,
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Chapter 12 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 12 - Write the electronic configuration for the ions of...Ch. 12 - A monoatomic ion with a charge of 1 has an...Ch. 12 - Identify by symbol two positively charged...Ch. 12 - Considering only ions with charges of 1+,2+,1, and...Ch. 12 - Write the symbols of two ions that are...Ch. 12 - Considering only ions with charges of 1+,2+,1, and...Ch. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - When potassium and chlorine react and form an...Ch. 12 - Fill in the blanks with the smallest integers...
Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Consider the following bonds: GeSe, BrSe, BrGe....Ch. 12 - Prob. 23ECh. 12 - Consider the following bonds: TeSe, OTe, OSe....Ch. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - What is the maximum number of atoms to which a...Ch. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Which orbitals of each atom overlap in forming a...Ch. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - A monatomic ion with a 2 charge has the electron...Ch. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Which ions among the following are isoelectronic...Ch. 12 - Prob. 12.2TCCh. 12 - Prob. 12.3TCCh. 12 - Prob. 12.4TCCh. 12 - Prob. 12.5TCCh. 12 - Prob. 1CLECh. 12 - Prob. 2CLECh. 12 - Prob. 3CLECh. 12 - Prob. 4CLECh. 12 - Prob. 5CLECh. 12 - Prob. 6CLECh. 12 - Write the electron configurations for the oxide...Ch. 12 - Arrange the following bonds in order of decreasing...
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- Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardIn which of the following molecules does the sulfur have an expanded octet? For those that do, write the Lewis structure. (a) SO2 (b) SF4 (c) SO2Cl2 (d) SF6arrow_forwardDraw Lewis structures for the following molecules or polyatomic ions. a. SO3 b. SO32arrow_forward
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