EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Chapter 12, Problem 43P

(a)

Interpretation Introduction

Interpretation:

The conversion of N-methylbenzylamine to given compound has to be explained.

Concept introduction:

The molecular formula of N-methylbutanamide is C5H11NO.

The structure of N- methylbutanamide is as follows.

EP ESSENTIAL ORG.CHEM.-MOD.MASTERING   , Chapter 12, Problem 43P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

The conversion of N-methylbenzylamine to given compound has to be explained.

Concept introduction:

The molecular formula of N-methylbutanamide is C5H11NO.

The structure of N- methylbutanamide is as follows.

EP ESSENTIAL ORG.CHEM.-MOD.MASTERING   , Chapter 12, Problem 43P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

The conversion of N-methylbenzylamine to given compound has to be explained.

Concept introduction:

The molecular formula of N-methylbutanamide is C5H11NO.

The structure of N- methylbutanamide is as follows.

EP ESSENTIAL ORG.CHEM.-MOD.MASTERING   , Chapter 12, Problem 43P , additional homework tip  3

(d)

Interpretation Introduction

Interpretation:

The conversion of N-methylbenzylamine to given compound has to be explained.

Concept introduction:

The molecular formula of N-methylbutanamide is C5H11NO.

The structure of N- methylbutanamide is as follows.

EP ESSENTIAL ORG.CHEM.-MOD.MASTERING   , Chapter 12, Problem 43P , additional homework tip  4

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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1
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