The product formed in the given reaction has to be shown with the stereochemistry. Concept Introduction: Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents. The chemical formula of the Grignard reagent is RMgX . Where R- Alkyl or aryl or vinyl X - Halogens such as Br,Cl or I Grignard reaction with ketone : Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol. General scheme: Stereocenter: In the product of a chemical reaction , if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

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Answer 1

Question

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

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Problem 7 of 10 Draw the major product of this reaction. Ignore inorganic byproducts. S' S 1. BuLi 2. ethylene oxide (C2H4O) Select to Draw a Submit

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Answer 2

Question

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

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Answer 3

Question

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

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See solution

Answer 4

Question

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

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Answer 5

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 6

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 7

Chapter 12, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Grignard reagent: Alkyl, vinyl, or aryl-magnesium halides are called as Grignard reagents.

The chemical formula of the Grignard reagent is RMgX.

WhereR- Alkyl or aryl or vinylX - Halogens such as Br,Cl or I

Grignard reaction with ketone:

Grignard regent reacts with ketone followed by acidic work up to form secondary or tertiary alcohol.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

General scheme:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The product formed in the given reaction has to be shown with the stereochemistry.

Concept Introduction:

LiAlH4 - Lithium aluminium hydride is a reducing agent.

It reduces aldehydes, ketones and esters into alcohol.

Conversion of ester into alcohol:

Stereocenter: In the product of a chemical reaction, if a carbon atom has been attached with four different carbon atoms, then it is known as chiral carbon atom or stereocenter in the product. The bond of the functional group because of which a new chiral carbon is supposed to form has to be represented in solid wedge bond.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - Prob. 1P Ch. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3P Ch. 12.1 - Prob. 4P Ch. 12.2 - Prob. 5P Ch. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7P Ch. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Solution Summary: The author explains the chemical formula of Grignard reagents. The product formed in the reaction has to be shown with the stereochemistry.

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Chapter 12 Solutions