Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 12, Problem 12.69E
Interpretation Introduction
Interpretation:
The structure and IUPAC name of the product formed by reaction of propene with a diatomic molecule is to be predicted.
Concept Introduction:
There are set of rules framed by International Union for Pure and Applied Chemistry (IUPAC) to be followed while naming chemical compounds.
The addition of one or more than one chlorine atoms in an unsaturated compound is known as chlorination reaction. Chlorination reaction is a type of halogenation reaction.
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
dm
Re
Explanation
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b) Use curved arrows to show the reaction of the radical with hydrogen bromide.
Br:
Br H
..
Answer Bank
Indicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+
Chapter 12 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 12 - Prob. 12.1ECh. 12 - Define the terms alkene, alkyne, and aromatic...Ch. 12 - Select those compounds that can be correctly...Ch. 12 - Prob. 12.4ECh. 12 - Give the IUPAC name for the following compounds:...Ch. 12 - Prob. 12.6ECh. 12 - Prob. 12.7ECh. 12 - Prob. 12.8ECh. 12 - Prob. 12.9ECh. 12 - Prob. 12.10E
Ch. 12 - Prob. 12.11ECh. 12 - Prob. 12.12ECh. 12 - What type of hybridized orbital is present on...Ch. 12 - What type of orbital overlaps to form a pi bond in...Ch. 12 - Prob. 12.15ECh. 12 - Explain the difference between geometric and...Ch. 12 - Draw structural formulas and give IUPAC names for...Ch. 12 - Prob. 12.18ECh. 12 - Which of the following alkenes can exist as...Ch. 12 - Draw structural formulas for the following:...Ch. 12 - Prob. 12.21ECh. 12 - In what ways are the physical properties of...Ch. 12 - Prob. 12.23ECh. 12 - Prob. 12.24ECh. 12 - Complete the following reactions. Where more than...Ch. 12 - Prob. 12.26ECh. 12 - Prob. 12.27ECh. 12 - What reagents would you use to prepare each of the...Ch. 12 - What is an important commercial application of...Ch. 12 - Prob. 12.30ECh. 12 - Terpin hydrate is used medicinally as an...Ch. 12 - Prob. 12.32ECh. 12 - Prob. 12.33ECh. 12 - Prob. 12.34ECh. 12 - Prob. 12.35ECh. 12 - Much of todays plumbing in newly built homes is...Ch. 12 - Prob. 12.37ECh. 12 - What type of hybridized orbital is present on...Ch. 12 - How many sigma bonds and how many pi bonds make up...Ch. 12 - Prob. 12.40ECh. 12 - Explain why geometric isomerism is not possible in...Ch. 12 - Give the common name and major uses of the...Ch. 12 - Describe the physical and chemical properties of...Ch. 12 - Prob. 12.44ECh. 12 - Prob. 12.45ECh. 12 - Prob. 12.46ECh. 12 - Prob. 12.47ECh. 12 - Prob. 12.48ECh. 12 - Limonene, which is present in citrus peelings, has...Ch. 12 - A disubstituted cycloalkane such as a exhibits...Ch. 12 - Prob. 12.51ECh. 12 - Prob. 12.52ECh. 12 - Give an IUPAC name for the following as...Ch. 12 - Give an IUPAC name for the following as...Ch. 12 - Name the following compounds, using the prefixed...Ch. 12 - Name the following compounds, using the prefixed...Ch. 12 - Name the following by numbering the benzene ring....Ch. 12 - Name the following by numbering the benzene ring....Ch. 12 - Prob. 12.59ECh. 12 - Write structural formulas for the following:...Ch. 12 - Prob. 12.61ECh. 12 - Prob. 12.62ECh. 12 - Prob. 12.63ECh. 12 - Prob. 12.64ECh. 12 - Prob. 12.65ECh. 12 - Prob. 12.66ECh. 12 - Prob. 12.67ECh. 12 - Prob. 12.68ECh. 12 - Prob. 12.69ECh. 12 - Prob. 12.70ECh. 12 - Prob. 12.71ECh. 12 - Prob. 12.72ECh. 12 - Prob. 12.73ECh. 12 - Prob. 12.74ECh. 12 - Prob. 12.75ECh. 12 - Prob. 12.76ECh. 12 - Prob. 12.77ECh. 12 - Prob. 12.78ECh. 12 - Prob. 12.79ECh. 12 - Prob. 12.80ECh. 12 - Prob. 12.81ECh. 12 - Prob. 12.82ECh. 12 - Prob. 12.83ECh. 12 - The compound CH2=CHCH2CH2CH3 is an example of: a....Ch. 12 - The correct structural for ethyne is: a. HC=CH b....Ch. 12 - Prob. 12.86E
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