(a) Interpretation: The structure and the correct name of the given compound are to be stated. Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature . The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name. Rules for writing IUPAC name from structural formula are: • First identify the longest carbon chain. • The next step is to identify the groups attached to the longest chain. • Identify the position, location, and number of the substituents bonded to the carbon chain. • Use prefix di, tri, tetra if same type of substituents are present. • Name the substituents in alphabetical order.

Question

An open vessel containing water stands in a laboratory measuring 5.0 m x 5.0 m x 3.0 m at 25 °C ; the vapor pressure (vp) of water at this temperature is 3.2 kPa. When the system has come to equilibrium, what mass of water will be found in the air if there is no ventilation? Repeat the calculation for open vessels containing benzene (vp = 13.1 kPa) and mercury (vp = 0.23 Pa)

Answer 1

Question

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

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An open vessel containing water stands in a laboratory measuring 5.0 m x 5.0 m x 3.0 m at 25 °C ; the vapor pressure (vp) of water at this temperature is 3.2 kPa. When the system has come to equilibrium, what mass of water will be found in the air if there is no ventilation? Repeat the calculation for open vessels containing benzene (vp = 13.1 kPa) and mercury (vp = 0.23 Pa)

Every chemist knows to ‘add acid to water with constant stirring’ when diluting a concentrated acid in order to keep the solution from spewing boiling acid all over the place. Explain how this one fact is enough to prove that strong acids and water do not form ideal solutions.

The predominant components of our atmosphere are N₂, O₂, and Ar in the following mole fractions: χN2 = 0.780, χO2 = 0.21, χAr = 0.01. Assuming that these molecules act as ideal gases, calculate ΔGmix, ΔSmix, and ΔHmix when the total pressure is 1 bar and the temperature is 300 K.

Answer 2

Question

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

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Answer 3

Question

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

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Answer 4

Question

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

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Answer 5

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 6

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 7

Chapter 12, Problem 12.12E

Interpretation Introduction

(a)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure and the correct name of the given compound are to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 12

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Answer 23

Ch. 12 - Prob. 12.1E Ch. 12 - Define the terms alkene, alkyne, and aromatic...Ch. 12 - Select those compounds that can be correctly...Ch. 12 - Prob. 12.4E Ch. 12 - Give the IUPAC name for the following compounds:...Ch. 12 - Prob. 12.6E Ch. 12 - Prob. 12.7E Ch. 12 - Prob. 12.8E Ch. 12 - Prob. 12.9E Ch. 12 - Prob. 12.10E

Solution Summary: The author explains the systematic naming of organic compound by IUPAC nomenclature.

Chapter 12 Solutions