Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 12, Problem 12.55AP

(a)

Interpretation Introduction

Interpretation:

The name of the cycloalkane has to be identified.

Concept Introduction:

Naming of Cycloalkane using IUPAC nomenclature:

Cycloalkanes are named by adding cyclo- as a prefix to the name of the alkane corresponding to the number of carbons in the ring. Cycloalkanes-containing groups attached to the main ring are named the same way as branches in an alkane are. The positions of the substituent groups on the ring are identified by numbering the carbons in the chain so that the substituents have the lowest possible set of position numbers.

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes.  There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(b)

Interpretation Introduction

Interpretation:

The name of the cycloalkane has to be identified.

Concept introduction:

Naming of Cycloalkane using IUPAC nomenclature:

Cycloalkanes are named by adding cyclo- as a prefix to the name of the alkane corresponding to the number of carbons in the ring.  Cycloalkanes-containing groups attached to the main ring are named the same way as branches in an alkane are.  The positions of the substituent groups on the ring are identified by numbering the carbons in the chain so that the substituents have the lowest possible set of position numbers.

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes.  There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(c)

Interpretation Introduction

Interpretation:

The name of the cycloalkane has to be identified.

Concept introduction:

Naming of Cycloalkane using IUPAC nomenclature:

Cycloalkanes are named by adding cyclo- as a prefix to the name of the alkane corresponding to the number of carbons in the ring. Cycloalkanes-containing groups attached to the main ring are named the same way as branches in an alkane are. The positions of the substituent groups on the ring are identified by numbering the carbons in the chain so that the substituents have the lowest possible set of position numbers.

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

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Chapter 12 Solutions

Fundamentals of General, Organic, and Biological Chemistry (8th Edition)

Ch. 12.6 - Identify each carbon in the molecule shown in...Ch. 12.6 - Prob. 12.12PCh. 12.6 - Prob. 12.13PCh. 12.6 - Draw and name alkanes that meet the following...Ch. 12.6 - Prob. 12.15KCPCh. 12.6 - Prob. 12.1CIAPCh. 12.6 - Prob. 12.2CIAPCh. 12.6 - Prob. 12.3CIAPCh. 12.8 - Prob. 12.1MRPCh. 12.8 - Prob. 12.2MRPCh. 12.8 - Prob. 12.16PCh. 12.8 - Write the structures of all singly chlorinated...Ch. 12.10 - Prob. 12.18PCh. 12.10 - Prob. 12.19PCh. 12.10 - What is wrong with the following names? It will be...Ch. 12.10 - Prob. 12.21KCPCh. 12.10 - Prob. 12.4CIAPCh. 12.10 - (a) What common produce items might you see...Ch. 12 - Convert the following models into line drawings...Ch. 12 - Prob. 12.23UKCCh. 12 - Prob. 12.24UKCCh. 12 - Give the IUPAC names for the following...Ch. 12 - Prob. 12.26UKCCh. 12 - What characteristics of carbon make possible the...Ch. 12 - Prob. 12.28APCh. 12 - Prob. 12.29APCh. 12 - Prob. 12.30APCh. 12 - For each of the following, give an example of a...Ch. 12 - Identify the highlighted functional groups in the...Ch. 12 - Identify the functional groups in the following...Ch. 12 - Propose structures for molecules that fit the...Ch. 12 - Prob. 12.35APCh. 12 - What requirement must be met for two compounds to...Ch. 12 - Prob. 12.37APCh. 12 - Prob. 12.38APCh. 12 - Prob. 12.39APCh. 12 - Prob. 12.40APCh. 12 - Give an example of a compound that meets the...Ch. 12 - (a)There are two isomers with the formula C4H10....Ch. 12 - Write condensed structures for the following...Ch. 12 - Prob. 12.44APCh. 12 - Prob. 12.45APCh. 12 - Which of the following pairs of structures are...Ch. 12 - Prob. 12.47APCh. 12 - Prob. 12.48APCh. 12 - Prob. 12.49APCh. 12 - What are the IUPAC names of the following alkanes?Ch. 12 - Prob. 12.51APCh. 12 - Write condensed structures for the following...Ch. 12 - Draw line structures for the following...Ch. 12 - Name the following cycloalkanes:Ch. 12 - Prob. 12.55APCh. 12 - Prob. 12.56APCh. 12 - Prob. 12.57APCh. 12 - Prob. 12.58APCh. 12 - Prob. 12.59APCh. 12 - Prob. 12.60APCh. 12 - Prob. 12.61APCh. 12 - Write the formulas of the four singly chlorinated...Ch. 12 - Write the formulas of the three doubly brominated...Ch. 12 - Identify the indicated functional groups in the...Ch. 12 - The line structure for pregabalin (Lyrica) is...Ch. 12 - Prob. 12.66CPCh. 12 - Prob. 12.67CPCh. 12 - Most lipsticks are about 70% castor oil and wax....Ch. 12 - Prob. 12.69CPCh. 12 - Prob. 12.70CPCh. 12 - Prob. 12.71CPCh. 12 - Which of the following structures represent the...
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