Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
Question
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Chapter 12, Problem 12.19P
Interpretation Introduction

(a)

Interpretation:

To predict bond angles about each highlighted carbon.

Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.19P , additional homework tip  1

Concept Introduction:

VSEPR predicts the geometry and the bond angles for the molecules according to the theory, the structure is predicted by the lone pairs and bond pairs present in the bond formation.

Electron pair = Lone pair + Bond pair.

Electron pair Hybridization Geometry Bond angles
2 sp Linear 180°
3 sp2 Trigonal planar 120°
4 sp3 Tetrahedra or square planar 109.5° or 90°
5 sp3 d Trigonal bipyramidal 120° and 90°
6 sp3 d2 Octahedral 90°

Interpretation Introduction

(b)

Interpretation:

To predict bond angles about each highlighted carbon.

Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.19P , additional homework tip  2

Concept Introduction:

VSEPR predicts the geometry and the bond angles for the molecules according to the theory, the structure is predicted by the lone pairs and bond pairs present in the bond formation.

Electron pair = Lone pair + Bond pair.

Electron pair Hybridization Geometry Bond angles
2 sp Linear 180°
3 sp2 Trigonal planar 120°
4 sp3 Tetrahedra or square planar 109.5° or 90°
5 sp3 d Trigonal bipyramidal 120° and 90°
6 sp3 d2 Octahedral 90°

Interpretation Introduction

(c)

Interpretation:

To predict bond angles about each highlighted carbon.

Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.19P , additional homework tip  3

Concept Introduction:

VSEPR predicts the geometry and the bond angles for the molecules according to the theory, the structure is predicted by the lone pairs and bond pairs present in the bond formation.

Electron pair = Lone pair + Bond pair.

Electron pair Hybridization Geometry Bond angles.
2 sp Linear 180°
3 sp2 Trigonal planar 120°
4 sp3 Tetrahedra or square planar 109.5° or 90°
5 sp3 d Trigonal bipyramidal 120° and 90°
6 sp3 d2 Octahedral 90°

Interpretation Introduction

(d)

Interpretation:

To predict bond angles about each highlighted carbon.

Introduction to General, Organic and Biochemistry, Chapter 12, Problem 12.19P , additional homework tip  4

Concept Introduction:

VSEPR predicts the geometry and the bond angles for the molecules according to the theory, the structure is predicted by the lone pairs and bond pairs present in the bond formation.

Electron pair = Lone pair + Bond pair.

Electron pair Hybridization Geometry Bond angles.
2 sp Linear 180°
3 sp2 Trigonal planar 120°
4 sp3 Tetrahedra or square planar 109.5° or 90°
5 sp3 d Trigonal bipyramidal 120° and 90°
6 sp3 d2 Octahedral 90°

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Chapter 12 Solutions

Introduction to General, Organic and Biochemistry

Ch. 12 - Prob. 12.11PCh. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Prob. 12.16PCh. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 12.19PCh. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 12.24PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - Prob. 12.28PCh. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Prob. 12.33PCh. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Prob. 12.39PCh. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 12.41PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - Prob. 12.44PCh. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - Prob. 12.49PCh. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Prob. 12.51PCh. 12 - Prob. 12.52PCh. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 12.56PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Prob. 12.60PCh. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - Prob. 12.62PCh. 12 - Prob. 12.63PCh. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - Prob. 12.66PCh. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - Prob. 12.68PCh. 12 - Prob. 12.69PCh. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - Prob. 12.75PCh. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - Prob. 12.78PCh. 12 - Prob. 12.79PCh. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 12.81P
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