Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
3rd Edition
ISBN: 9780137533268
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 11.2, Problem 4P
Interpretation Introduction

Interpretation: To choose the correct option of the given statements.

Concept introduction:

Delocalization energy is nothing else it is the energy released when deloclization π electrons takes place. This energy is also called as resonance energy. More the resonating srtuctures more will be the stability. The delocalization of electrons depend upon the electronegativity of elements. As the electronegativity increases poor will be the delocalization and lesser will be delocalization energy.

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2. Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction energies in order to identify the lower energy conformer for each stereoisomer. Based on your calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable. [1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3 CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol) all-cis-1,2,3- 1 all-cis-1,2,4- 2
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What is the mechanism by which the 1,4 product is created?  Please draw it by hand with arrows and stuff.

Chapter 11 Solutions

Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)

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