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- The complete answerChemistry 9) Write Newman projections for the gauche and anti-conformations of 1,2- dibromoethane (BrCH2CH2Br). Which conformation is more stable than the other and explain why?4.) For each of the following pairs, give the relationship between the two compounds. You many ignore conformational isomerism here, and any conformers may be considered to be identical compounds. H H. a. H H H. H F F CH, b. он CH3 он c. CH, он он CH3 d. CHs CH3 CH, CH3 CH, .CH2 Br H. H. Br CH3 CH3 Br Br f. CH, H. CH3 он H. H Br Br H. OH 2
- 2.(a) Different conformations are found in 2-methylpentane. (i) Using Newman Projection, draw all the possible staggered and eclipsed conformations of pentane by referring to the bond rotation at C3-C4.(ii) Compare their stability and explain your answer.Rank the conformations of 1,2-dichloroethane in terms of stability. Draw a plot of potential energy versus rotation for the C-C bond in 1,2-dichloroethane. Do your calculations for conformations of 1,2-dichloroethane agree with the plot you predict?(b) Consider the following tetra-substituted cyclohexane: OH Draw the alternative chair conformations of the cyclohexane compound, shown above. List the unfavourable steric interactions for each chair conformation and determine the more stable conformation of the compound. i.
- The most stable conformation of cis-1,3-dimethylcyclohexane has how many hydrogen atoms in axial positions?4.(a). Draw the structures of (i) cis-1,4-Dibromocyclohexane and (ii) trans-1,4- Dibromocyclohexane. 4(b). Draw the most stable conformers of (i) cis-1,4-Dibromocyclohexane and (ii) trans-1,4-Dibromocyclohexane. 4(c)Which is more stable? (i) cis-1,4-Dibromocyclohexane or (ii) trans-1,4- Dibromolcyclohexane. Explain the reason for your choice.Two VSEPR diagrams for Molecule 1 are given below. They are conformational isomers or molecules that place atoms differently in space because of the rotation of a single bond. H H H:O H:O Conformer 1 H H H Ö: Conformer 2 3. (a) Can you “see” either of the two conformational isomers (Conformer 1 or Conformer 2) in the line drawing that you drew for Molecule 1? Explain your answer.

