Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 97CWP
A reaction of the form
gives a plot of ln[A] versus time (in seconds), which is a straight line with a slope of −7.35 X 10−3. Assuming [A]0 = 0.0100 M, calculate the time (in seconds) required for the reaction to reach 22.9% completion.
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Chapter 11 Solutions
Chemistry: An Atoms First Approach
Ch. 11 - Define reaction rate. Distinguish between the...Ch. 11 - Distinguish between the differential rate law and...Ch. 11 - One experimental procedure that can be used to...Ch. 11 - The initial rate for a reaction is equal to the...Ch. 11 - Prob. 5RQCh. 11 - Derive expressions for the half-life of zero-,...Ch. 11 - Prob. 7RQCh. 11 - Prob. 8RQCh. 11 - Prob. 9RQCh. 11 - Give the Arrhenius equation. Take the natural log...
Ch. 11 - Why does a catalyst increase the rate of a...Ch. 11 - Prob. 1ALQCh. 11 - Describe at least two experiments you could...Ch. 11 - Prob. 3ALQCh. 11 - Prob. 4ALQCh. 11 - Consider the following statements: In general, the...Ch. 11 - For the reaction A + B C, explain at least two...Ch. 11 - Prob. 7ALQCh. 11 - Prob. 8ALQCh. 11 - Prob. 9ALQCh. 11 - Prob. 10QCh. 11 - Prob. 11QCh. 11 - The plot below shows the number of collisions with...Ch. 11 - For the reaction O2(g)+2NO(g)2NO2(g) the observed...Ch. 11 - Prob. 14QCh. 11 - Prob. 15QCh. 11 - Prob. 16QCh. 11 - Prob. 17QCh. 11 - Prob. 18QCh. 11 - Prob. 19QCh. 11 - Consider the following energy plots for a chemical...Ch. 11 - Prob. 21QCh. 11 - Would the slope of a ln(k) versus 1/T plot (with...Ch. 11 - Prob. 23ECh. 11 - In the Haber process for the production of...Ch. 11 - At 40C, H2O2 (aq) will decompose according to the...Ch. 11 - Consider the general reaction aA+bBcC and the...Ch. 11 - What are the units for each of the following if...Ch. 11 - The rate law for the reaction...Ch. 11 - The reaction 2NO(g)+Cl2(g)2NOCl(g) was studied at...Ch. 11 - The reaction 2I-(aq)+S2O82-(aq)I2(aq)+2SO42-(aq)...Ch. 11 - The decomposition of nitrosyl chloride was...Ch. 11 - The following data were obtained for the gas-phase...Ch. 11 - The reaction I(aq)+OCl(aq)IO(aq)+Cl(aq) was...Ch. 11 - The reaction 2NO(g)+O2(g)2NO2(g) was studied. and...Ch. 11 - The rote of the reaction between hemoglobin (Hb)...Ch. 11 - The following data were obtained for the reaction...Ch. 11 - The decomposition of hydrogen peroxide was...Ch. 11 - Prob. 38ECh. 11 - The rate of the reaction NO2(g)+CO(g)NO(g)+CO2(g)...Ch. 11 - A certain reaction has the following general form:...Ch. 11 - The decomposition of ethanol (C2H5OH) on an...Ch. 11 - Prob. 42ECh. 11 - The dimerization of butadiene 2C4H6(g)C8H12(g) was...Ch. 11 - The rate of the reaction O(g)+NO2(g)NO(g)+O2(g)...Ch. 11 - Experimental data for the reaction A2B+C have been...Ch. 11 - Prob. 46ECh. 11 - The reaction AB+C is known to be zero order in A...Ch. 11 - The decomposition of hydrogen iodide on finely...Ch. 11 - Prob. 49ECh. 11 - A first-order reaction is 75.0% complete in 320....Ch. 11 - The rate law for the decomposition of phosphine...Ch. 11 - DDT (molar mass = 354.49 g/mol) was a widely used...Ch. 11 - Consider the following initial rate data for the...Ch. 11 - Prob. 54ECh. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - You and a coworker have developed a molecule...Ch. 11 - Consider the hypothetical reaction A+B+2C2D+3E...Ch. 11 - Prob. 59ECh. 11 - A possible mechanism for the decomposition of...Ch. 11 - A proposed mechanism for a reaction is...Ch. 11 - The mechanism for the gas-phase reaction of...Ch. 11 - For the following reaction profile, indicate a....Ch. 11 - Draw a rough sketch of the energy profile for each...Ch. 11 - Prob. 65ECh. 11 - The activation energy for some reaction...Ch. 11 - The rate constant for the gas-phase decomposition...Ch. 11 - The reaction (CH3)3CBr+OH(CH3)3COH+Br in a certain...Ch. 11 - Prob. 69ECh. 11 - A first-order reaction has rate constants of 4.6 ...Ch. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Which of the following reactions would you expect...Ch. 11 - Prob. 74ECh. 11 - One mechanism for the destruction of ozone in the...Ch. 11 - One of the concerns about the use of Freons is...Ch. 11 - Prob. 77ECh. 11 - The decomposition of NH3 to N2 and H2 was studied...Ch. 11 - The decomposition of many substances on the...Ch. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Consider the following representation of the...Ch. 11 - The reaction H2SeO3(aq) + 6I-(aq) + 4H+(aq) Se(s)...Ch. 11 - Prob. 85AECh. 11 - Sulfuryl chloride (SO2Cl2) decomposes to sulfur...Ch. 11 - For the reaction 2N2O5(g)4NO2(g)+O2(g) the...Ch. 11 - Prob. 88AECh. 11 - Cobra venom helps the snake secure food by binding...Ch. 11 - Iodomethane (CH3I) is a commonly used reagent in...Ch. 11 - Experiments during a recent summer on a number of...Ch. 11 - The activation energy of a certain uncatalyzed...Ch. 11 - Consider the reaction 3A+B+CD+E where the rate law...Ch. 11 - The thiosulfate ion (S2O32) is oxidized by iodine...Ch. 11 - The reaction A(aq)+B(aq)products(aq) was studied,...Ch. 11 - A certain substance, initially present at 0.0800...Ch. 11 - A reaction of the form aAProducts gives a plot of...Ch. 11 - A certain reaction has the form aAProducts At a...Ch. 11 - Which of the following statement(s) is( are) true?...Ch. 11 - Consider the hypothetical reaction A2(g) + B2(g) ...Ch. 11 - Experiments have shown that the average frequency...Ch. 11 - Consider a reaction of the type aA products, in...Ch. 11 - A study was made of the effect of the hydroxide...Ch. 11 - Two isomers (A and B) of a given compound dimerize...Ch. 11 - Prob. 105CPCh. 11 - Most reactions occur by a series of steps. The...Ch. 11 - Prob. 107CPCh. 11 - The decomposition of NO2(g) occurs by the...Ch. 11 - The following data were collected in two studies...Ch. 11 - Prob. 110CPCh. 11 - Prob. 111CPCh. 11 - Prob. 112CPCh. 11 - Sulfuryl chloride undergoes first-order...Ch. 11 - Upon dissolving InCl(s) in HCl, In+(aq) undergoes...Ch. 11 - The decomposition of iodoethane in the gas phase...Ch. 11 - Consider the following reaction: CH3X+YCH3Y+X At...
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- 2) Draw the correct chemical structure (using line-angle drawings / "line structures") from their given IUPAC name: a. (E)-1-chloro-3,4,5-trimethylhex-2-ene b. (Z)-4,5,7-trimethyloct-4-en-2-ol C. (2E,6Z)-4-methylocta-2,6-dienearrow_forwardපිපිම Draw curved arrows to represent the flow of electrons in the reaction on the left Label the reactants on the left as either "Acid" or "Base" (iii) Decide which direction the equilibrium arrows will point in each reaction, based on the given pk, values (a) + H-O H 3-H + (c) H" H + H****H 000 44-00 NH₂ (e) i Дон OH Ө NHarrow_forward3) Label the configuration in each of the following alkenes as E, Z, or N/A (for non-stereogenic centers). 00 E 000 N/A E Br N/A N/A (g) E N/A OH E (b) Oz N/A Br (d) 00 E Z N/A E (f) Oz N/A E (h) Z N/Aarrow_forward
- 6) Fill in the missing Acid, pKa value, or conjugate base in the table below: Acid HCI Approximate pK, -7 Conjugate Base H-C: Hydronium (H₂O') -1.75 H-O-H Carboxylic Acids (RCOOH) Ammonium (NH4) 9.24 Water (H₂O) H-O-H Alcohols (ROH) RO-H Alkynes R--H Amines 25 25 38 HOarrow_forward5) Rank the following sets of compounds in order of decreasing acidity (most acidic to least acidic), and choose the justification(s) for each ranking. (a) OH V SH я вон CH most acidic (lowst pKa) least acidic (highest pKa) Effect(s) Effect(s) Effect(s) inductive effect O inductive effect O inductive effect electronegativity electronegativity O electronegativity resonance polarizability resonance polarizability O resonance O polarizability hybridization Ohybridization O hybridization оarrow_forwardHow negatively charged organic bases are formed.arrow_forward
- Nonearrow_forward1) For the following molecules: (i) Label the indicated alkenes as either cis (Z), trans (E), or N/A (for non-stereogenic centers) by bubbling in the appropriate label on the molecule. (ii) Complete the IUPAC name located below the structure (HINT: Put the letter of the configuration in parentheses at the beginning of the name!) E z N/A ()-3,4,6-trimethylhept-2-ene E Oz O N/A ()-3-ethyl-1-fluoro-4-methylhex-3-ene E -+- N/A Me )-2,3-dimethylpent-2-ene (d) (b) E O N/A Br ()-5-bromo-1-chloro-3-ethyloct-4-ene ОЕ Z N/A Et (___)-3-ethyl-4-methylhex-3-ene E (f) Oz N/A z N/A HO (4.7)-4-(2-hydroxyethyl)-7-methylnona-4,7-dien-2-onearrow_forwardO 9:21AM Tue Mar 4 ## 64% Problem 51 of 15 Submit Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H :0: CI. AI :CI: :CI: Cl AI Select to Add Arrows Select to Add Arrows O: Cl :CI: :0: H CI: CI CO Select to Add Arrows Select to Add Arrows :O: CI :0: Cl. 10: AIarrow_forward
- (i) Draw in the missing lone pair(s) of electrons of the reactants on the left (ii) Draw (curved) arrows to show the flow of electrons in the acid/base reaction on the left (iii) Draw the products of the acid/base on the right (iv) Select the correct label for each product as either "conjugate acid" or "conjugate base" (a) JOH OH NH₂ acid base (b) De "H conjugate acid conjugate acid conjugate base conjugate base acid base conjugate acid conjugate base conjugate acid conjugate base acid basearrow_forwardCould someone answer this NMR and explain please Comment on the general features of the 1H-NMR spectrum of isoamyl ester provided below.arrow_forwardMacmillan Learning Draw the acyl chloride that would give the ketone shown using the Friedel-Crafts acylation reaction. Select Draw Templates More с H о Cl 2Q Erase AICI₂arrow_forward
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