Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 11, Problem 83E
Interpretation Introduction

Interpretation:

The boiling point of water at an elevation where the atmospheric pressure is 0.500atm is to be stated.

Concept introduction:

Boiling is defined as a process in which a substance starts converting from liquid state to gaseous state. The temperature at which a substance starts boiling is known as its boiling point temperature. A liquid starts to boil at the temperature when the vapor pressure of the liquid becomes equal to the standard atmospheric pressure.

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fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 11 Solutions

Introductory Chemistry: Concepts and Critical Thinking (8th Edition)

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