(a) Interpretation: The chemical formula of sodium acetate tri-hydrate is to be stated. Concept introduction: A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature , the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

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Answer 1

Question

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)

2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Answer 2

Question

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

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Answer 3

Question

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

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Answer 4

Question

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

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Answer 5

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 6

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 7

Chapter 11, Problem 73E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of sodium acetate tri-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The chemical formula of calcium sulfate di-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The chemical formula of potassium chromate tetra-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The chemical formula of zinc sulphate hepta-hydrate is to be stated.

Concept introduction:

A crystalline compound with fixed number of water molecules are known as hydrates. The water molecules are known as water of crystallization. According to IUPAC nomenclature, the naming of hydrates is done by first naming the anhydrous compound followed by the number of water molecules and hydrate.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 11 - Prob. 1CE Ch. 11 - Prob. 2CE Ch. 11 - Prob. 3CE Ch. 11 - Prob. 4CE Ch. 11 - Prob. 5CE Ch. 11 - Prob. 6CE Ch. 11 - Prob. 7CE Ch. 11 - Prob. 8CE Ch. 11 - Prob. 1KT Ch. 11 - Prob. 2KT

Solution Summary: The author explains the chemical formula of sodium acetate tri-hydrate, which is the anhydrous part of the hydrate formula.

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