(a) Interpretation: The strongest type of intermolecular attraction that exists in C 5 H 12 is to be stated. Concept introduction: Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

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Answer 1

Question

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

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2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Answer 2

Question

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

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Answer 3

Question

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

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Answer 4

Question

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

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Answer 5

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 6

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 7

Chapter 11, Problem 81E

Interpretation Introduction

(a)

Interpretation:

The strongest type of intermolecular attraction that exists in C5H12 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3CH2CH2−Cl is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−OH is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The strongest type of intermolecular attraction that exists in CH3−O−CH3 is to be stated.

Concept introduction:

Intermolecular and intramolecular are the two types of forces present in a molecule. As the intermolecular forces of attraction in a molecule increase, the molecules interact with each other more strongly. So, the temperature at which the liquid boils also increases.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 11 - Prob. 1CE Ch. 11 - Prob. 2CE Ch. 11 - Prob. 3CE Ch. 11 - Prob. 4CE Ch. 11 - Prob. 5CE Ch. 11 - Prob. 6CE Ch. 11 - Prob. 7CE Ch. 11 - Prob. 8CE Ch. 11 - Prob. 1KT Ch. 11 - Prob. 2KT

Solution Summary: The author explains that dispersion force is the strongest type of intermolecular attraction in C_Text5.

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