Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 11, Problem 45E
Interpretation Introduction
Interpretation:
Whether the viscosity of water is unusually high or low is to be stated.
Concept introduction:
Viscosity is the property of fluid which has higher resistance to flow. Water is less viscous as compared to liquids like honey or motor oil. Liquids with stronger intermolecular interactions are usually more viscous than liquids with weak intermolecular interactions.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
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-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
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a) Tris(acetylacetonato)iron(III)
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Chapter 11 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 11 - Prob. 1CECh. 11 - Prob. 2CECh. 11 - Prob. 3CECh. 11 - Prob. 4CECh. 11 - Prob. 5CECh. 11 - Prob. 6CECh. 11 - Prob. 7CECh. 11 - Prob. 8CECh. 11 - Prob. 1KTCh. 11 - Prob. 2KT
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