Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 11, Problem 78RQ
Determining the Structure of Solids
The diagrams that follow illustrate two typical arrangements of paving bricks in a patio or driveway. Sketch the unit cell that corresponds to each pattern of bricks.
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Chapter 11 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 11 - Prob. 1PECh. 11 - List the following in order of their boiling...Ch. 11 - Propylamine and trimethylamine have the same...Ch. 11 - People living in arid, dry, regions can cool their...Ch. 11 - Use the kinetic molecular theory to explain why...Ch. 11 - Considering Figure 11.24, in which direction...Ch. 11 - Suppose a liquid is in equilibrium with its vapor...Ch. 11 - The Dead Sea is approximately 1300 ft below sea...Ch. 11 - The atmospheric pressure at the summit of Mt....Ch. 11 - Benzene has a boiling point of 80.1C, and a...
Ch. 11 - Steam can cause more severe bums than water, even...Ch. 11 - The equilibrium line from point B to D in Figure...Ch. 11 - What phase changes will occur if water at 20C and...Ch. 11 - Prob. 14PECh. 11 - Use Le Chtelier's principle to predict how a...Ch. 11 - Prob. 16PECh. 11 - At 0.00C, hexane, C6H14, has a vapor pressure of...Ch. 11 - Prob. 18PECh. 11 - Chromium crystallizes in a body-centered cubic...Ch. 11 - What is the ratio of the ions in the unit cell of...Ch. 11 - Polonium is the only metal known to crystallize in...Ch. 11 - Use the data in the previous Practice Exercise to...Ch. 11 - Stearic acid is an organic acid that has a chain...Ch. 11 - Boron nitride, which has the empirical formula BN,...Ch. 11 - Crystals of elemental sulfur are easily crushed...Ch. 11 - 11.1 Why are the intermolecular attractive forces...Ch. 11 - Compare the behavior of gases, liquids, and solids...Ch. 11 - Prob. 3RQCh. 11 - Why do intermolecular attractions weaken as the...Ch. 11 - Prob. 5RQCh. 11 - Define polarizability. How does this property...Ch. 11 - Prob. 7RQCh. 11 - 11.8 Which nonmetals, besides hydrogen, are...Ch. 11 - Prob. 9RQCh. 11 - Which would give a stronger iondipole interaction...Ch. 11 - Prob. 11RQCh. 11 - Prob. 12RQCh. 11 - Intermolecular Forces and Physical...Ch. 11 - Prob. 14RQCh. 11 - Intermolecular Forces and Physical Properties Name...Ch. 11 - Prob. 16RQCh. 11 - Prob. 17RQCh. 11 - Prob. 18RQCh. 11 - Prob. 19RQCh. 11 - Prob. 20RQCh. 11 - Intermolecular Forces and Physical...Ch. 11 - Prob. 22RQCh. 11 - Prob. 23RQCh. 11 - Prob. 24RQCh. 11 - Prob. 25RQCh. 11 - Prob. 26RQCh. 11 - Prob. 27RQCh. 11 - Prob. 28RQCh. 11 - Prob. 29RQCh. 11 - Changes of State and Dynamic Equilibrium What...Ch. 11 - Prob. 31RQCh. 11 - Changes of State and Dynamic Equilibrium
11.32 Why...Ch. 11 - Changes of State and Dynamic Equilibrium
11.33...Ch. 11 - Changes of State and Dynamic Equilibrium
11.34....Ch. 11 - Prob. 35RQCh. 11 - Prob. 36RQCh. 11 - Vapor Pressures of Liquids and Solids
11.37...Ch. 11 - Prob. 38RQCh. 11 - Vapor Pressures of Liquids and Solids 11.39 What...Ch. 11 - Vapor Pressures of Liquids and Solids Why does...Ch. 11 - Vapor Pressures of Liquids and Solids Why do we...Ch. 11 - Prob. 42RQCh. 11 - Boiling Points of Liquids Why does the boiling...Ch. 11 - Boiling Points of Liquids Mt. Kilimanjaro in...Ch. 11 - Boiling Points of Liquids
11.45. When liquid...Ch. 11 - Prob. 46RQCh. 11 - Boiling Points of Liquids Butane, C4H10, has a...Ch. 11 - Boiling Points of Liquids
11.48. Why does have a...Ch. 11 - Boiling Points of Liquids An HF bond is more polar...Ch. 11 - Energy and Changes of State The following is a...Ch. 11 - Energy and Changes of State
11.51 Why is larger...Ch. 11 - Energy and Changes of State Would the heat of...Ch. 11 - Energy and Changes of State Hurricanes can travel...Ch. 11 - Energy and Changes of State Ethanol (grain...Ch. 11 - Energy and Changes of State A burn caused by steam...Ch. 11 - Energy and Changes of State
11.56 Arrange the...Ch. 11 - Prob. 57RQCh. 11 - Phase Diagrams
11.58 Define critical temperature...Ch. 11 - Phase Diagrams What is a supercritical fluid? Why...Ch. 11 - Phase Diagrams
11.60 What phases of a substance...Ch. 11 - Prob. 61RQCh. 11 - Prob. 62RQCh. 11 - Phase Diagrams Sketch a generic phase diagram that...Ch. 11 - Phase Diagrams
11.64 What is the significance of...Ch. 11 - Prob. 65RQCh. 11 - Le Chtelier's Principle and Changes of State State...Ch. 11 - Le Châtelier's Principle and Changes of...Ch. 11 - Le Chtelier's Principle and Changes of State Use...Ch. 11 - Le Chtelier's Principle and Changes of State Use...Ch. 11 - Le Châtelier's Principle and Changes of...Ch. 11 - Determining Heats of Vaporization According to the...Ch. 11 - Determining Heats of Vaporization Why can't...Ch. 11 - Determining Heats of Vaporization Why can any...Ch. 11 - Prob. 74RQCh. 11 - Prob. 75RQCh. 11 - Prob. 76RQCh. 11 - Determining the Structure of Solids What...Ch. 11 - Determining the Structure of Solids
11.78 The...Ch. 11 - The figure below illustrates the way the atoms of...Ch. 11 - Make a sketch of a layer of sodium ions and...Ch. 11 - 11.81 How do the crystal structures of copper and...Ch. 11 - Determining the Structure of Solids
11.82 What...Ch. 11 - Determining the Structure of Solids Only 14...Ch. 11 - Determining the Structure of Solids Write the...Ch. 11 - Determining the Structure of Solids Why cant...Ch. 11 - Prob. 86RQCh. 11 - Crystal Types and Physical Properties
11.87 What...Ch. 11 - Prob. 88RQCh. 11 - Prob. 89RQCh. 11 - Prob. 90RQCh. 11 - Intermolecular Forces and Physical Properties What...Ch. 11 - Intermolecular Forces and Physical Properties What...Ch. 11 - Intermolecular Forces and Physical Properties...Ch. 11 - Prob. 94RQCh. 11 - 11.95 Consider the compounds (chloroform, an...Ch. 11 - 11.96 Carbon dioxide does not liquefy at...Ch. 11 - Prob. 97RQCh. 11 - Prob. 98RQCh. 11 - Prob. 99RQCh. 11 - Prob. 100RQCh. 11 - 11.101 The following are the vapor pressures of...Ch. 11 - 11.102 The boiling points of some common...Ch. 11 - 11.103 Using the information in Problem 11.101,...Ch. 11 - 11.104 Using the information in Problem 11.102,...Ch. 11 - 11.105 What intermolecular forces must the...Ch. 11 - 11.106 What intermolecular attractions will be...Ch. 11 - Energy and Changes of State The molar heat of...Ch. 11 - Energy and Changes of State The molar heat of...Ch. 11 - *11.109 Suppose 45.0 g of water at is added to...Ch. 11 - A cube of solid benzene (C6H6) at its melting...Ch. 11 - Prob. 111RQCh. 11 - Prob. 112RQCh. 11 - Prob. 113RQCh. 11 - Prob. 114RQCh. 11 - Prob. 115RQCh. 11 - Prob. 116RQCh. 11 - Determining Heats of Vaporization
*11.117 Mercury...Ch. 11 - Prob. 118RQCh. 11 - Prob. 119RQCh. 11 - *11.120 If the vapor pressure of ethylene glycol...Ch. 11 - Determining the Structure of Solids
11.121 How...Ch. 11 - 11.122 How many copper atoms are within the...Ch. 11 - The atomic radius of nickel is 1.24 . Nickel...Ch. 11 - 11.124 Silver forms face-centered cubic crystals....Ch. 11 - Potassium ions have a radius of 133 pm, and...Ch. 11 - 11.126 The unit cell edge in sodium chloride has a...Ch. 11 - Prob. 127RQCh. 11 - Prob. 128RQCh. 11 - *11.129 Cesium chloride forms a simple cubic...Ch. 11 - 11.130 Rubidium chloride has the rock salt...Ch. 11 - Prob. 131RQCh. 11 - Crystal Types and Physical Properties Elemental...Ch. 11 - Prob. 133RQCh. 11 - Prob. 134RQCh. 11 - Prob. 135RQCh. 11 - Crystal Types and Physical Properties
11.1 36...Ch. 11 - List all of the attractive forces that exist in...Ch. 11 - 11.138 Calculate the mass of water vapor present...Ch. 11 - 11.139 Should acetone molecules be attracted to...Ch. 11 - The following thermochemical equations apply to...Ch. 11 - Melting point is sometimes used as an indication...Ch. 11 - When warm, moist air sweeps in from the ocean and...Ch. 11 - *11.143 Gold crystallizes in a face-centered cubic...Ch. 11 - Gold crystallizes with a face-centered cubic unit...Ch. 11 - Identify the type of unit cell belonging to the...Ch. 11 - Calculate the amount of empty space (in pm3) in...Ch. 11 - Silver has an atomic radius of 144 pm. What would...Ch. 11 - Potassium chloride crystallizes with the rock salt...Ch. 11 - Prob. 149RQCh. 11 - There are 270 Calories in a Hersheys* Milk...Ch. 11 - Prob. 151RQCh. 11 - *11.152 Frecze-drying is a process used to...Ch. 11 - When reporting the vapor pressure for a substance...Ch. 11 - 11.154 Supercritical is used to decaffeinate...Ch. 11 - 11.155 Freshly precipitated crystals are usually...Ch. 11 - 11.156 What are three “everyday” applications of...Ch. 11 - Prob. 157RQCh. 11 - 11.158 Galileo's thermometer is a tube of liquid...Ch. 11 - Use the Clausius-Clapeyron equation to plot the...Ch. 11 - Prob. 160RQCh. 11 - Earlier in this chapter it was noted that the...
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- Lithium hydride (LiH) has the sodium chloride structure, and the length of the edge of the unit cell is 4.086 108 cm. Calculate the density of this solid.arrow_forwardDescribe the unit cell of lithium (see Figure).arrow_forwardThe unit cell of silicon carbide, SiC, is illustrated below. (a) In what type of unit cell are the (dark gray) C atoms arranged? (b) If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? A portion of the solid-state structure of silicon carbide.arrow_forward
- Phase diagrams for materials that have allotropes can be more complicated than those shown in the chapter. Use the phase diagram for carbon given here to answer the following questions. (a) How many triple points are present and what phases are in equilibrium for each? (b) Is there a single point where all four phases are in equilibrium? (c) Which is more stable at high pressures, diamond or graphite? (d) Which is the stable phase of carbon at room temperature and 1 atmosphere pressure?arrow_forwardAn amorphous solid can sometimes be converted to a crystalline solid by a process called annealing. Annealing consists of heating the substance to a temperature just below the melting point of the crystalline form and then cooling it slowly. Explain why this process helps produce a crystalline solid.arrow_forward(a) Determining an Atom Radius from Lattice Dimensions: Gold has a face-centered unit cell, and its density is 19.32 g/cm3. Calculate the radius of a gold atom. (b) The Structure of Solid Iron: Iron has a density of 7.8740 g/cm3, and the radius of an iron atom is 126 pm. Verify that solid iron has a body-centered cubic unit cell. (Be sure to note that the atoms in a body-centered cubic unit cell touch along the diagonal across the cell. They do not touch along the edges of the cell.) (Hint: The diagonal distance across the unit cell = edge 3.)arrow_forward
- Crystalline polonium has a primitive cubic unit cell, lithium has a body-centered cubic unit cell, and calcium has a face-centered cubic unit cell. How many Po atoms belong to one unit cell? How many Li atoms belong to one unit cell? How many Ca atoms belong to one unit cell? Draw each unit cell. Indicate on your drawing what fraction of each atom lies within the unit cell.arrow_forwardThe unit cell for nickel arsenide is shown below. What is the formula of this compound?arrow_forwardThe CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69). Given that the density of cesium chloride is 3.97 g/cm3, and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent Cs+ and Cl ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of Cs+ is 169 pm, and the ionic radius of Cl is 181 pm.arrow_forward
- Classify each substance in the table as either a metallic, ionic, molecular, or covalent network solid: Substance Appearance Melting Point Electrical Conductivity Solubility in Water X lustrous, malleable 1500 C high insoluble Y Soft, yellow 113 C None Insoluble Z Hard, white 800 C Only if melted/dissolved solublearrow_forwardConsider the three types of cubic units cells. (a) Assuming that the spherical atoms or ions in a primitive cubic unit cell just touch along the cubes edges, calculate the percentage of occupied space within the unit cell. (Recall that the volume of a sphere is (4/3)r3, where r is the radius of the sphere.) (b) Compare the percentage of occupied space in the primitive cell (pc) with the bcc and fcc unit cells. Based on this, will a metal in these three forms have the same or different densities? If different, in which is it most dense? In which is it least dense?arrow_forwardWhy is the C 60form of carbon called buckminsterfullerene?arrow_forward
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