The terms lattice and unit cell are to be defined for a cell. Concept Introduction: Solids are the substances which have strong forces of attraction between their molecules. The atoms are tightly bound and cannot be compressed by pressure. These can be of two types: Amorphous and crystalline solids. Amorphous solids are formed when the molecules of atom are tightly coupled together such that they are fixed in their position. These do not have any fixed shape. Such solids are glass, polymers and gels. On the other hand, crystalline solids are defined as the type of solids in which the atoms or molecules occupy specific positions. These are rigid and compact in nature. These possess long range order and definite melting points. For example: sodium chloride, diamond etc..
The terms lattice and unit cell are to be defined for a cell. Concept Introduction: Solids are the substances which have strong forces of attraction between their molecules. The atoms are tightly bound and cannot be compressed by pressure. These can be of two types: Amorphous and crystalline solids. Amorphous solids are formed when the molecules of atom are tightly coupled together such that they are fixed in their position. These do not have any fixed shape. Such solids are glass, polymers and gels. On the other hand, crystalline solids are defined as the type of solids in which the atoms or molecules occupy specific positions. These are rigid and compact in nature. These possess long range order and definite melting points. For example: sodium chloride, diamond etc..
Solution Summary: The author explains that lattice and unit cell are to be defined for a cell.
Definition Definition Large and very high-molecular-weight substances that consist of hundreds to thousands of repeating units. Polymers are also known as macromolecules. Number-average-molecular weight is the measuring system for the polymers.
Chapter 11, Problem 76RQ
Interpretation Introduction
Interpretation:
The terms lattice and unit cell are to be defined for a cell.
Concept Introduction:
Solids are the substances which have strong forces of attraction between their molecules. The atoms are tightly bound and cannot be compressed by pressure. These can be of two types: Amorphous and crystalline solids.
Amorphous solids are formed when the molecules of atom are tightly coupled together such that they are fixed in their position. These do not have any fixed shape. Such solids are glass, polymers and gels.
On the other hand, crystalline solids are defined as the type of solids in which the atoms or molecules occupy specific positions. These are rigid and compact in nature. These possess long range order and definite melting points. For example: sodium chloride, diamond etc..
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
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