Interpretation: The molality, mass percent, normality and mole fraction of Citric acid has to be calculated.
Concept Introduction:
Mass percent can be defined as ratio of calculated mass to the total mass of the compound whole multiplied by
Molality of a solution also called as molal concentration can be defined as the mass of solute in grams to the mass of the solvent in kilograms. It can be given by the equation,
Mole fraction of a compound can be defined as the number of moles of a substance to the total number of moles present in them. The mole fraction can be calculated by,
Normality can be defined as number of gram equivalent to the volume of the solution. It can be given by formula,
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Chapter 11 Solutions
Chemistry
- Water at 25 C has a density of 0.997 g/cm3. Calculate the molality and molarity of pure water at this temperature.arrow_forwardThe freezing point of a 0.11 m solution of HNO2 is -0.20C. (a) What is i for the solution? (b) Is the solution made (i) of HNO2 molecules only? (ii) of H+ and NO2- only? (iii) of more HNO2 molecules than H+ ions? (iv) primarily of H+ and NO2- ions with some HNO2 molecules?arrow_forwardA 0.109 mol/kg aqueous solution of formic acid, HCOOH, freezes at −0.210 °C. Calculate the percent dissociation of formic acid.arrow_forward
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forwardThe freezing point of 0.109 m aqueous formic acid is 0.210C. Formic acid, HCHO2, is partially dissociated according to the equation HCHO2(aq)H+(aq)+CHO2(aq) Calculate the percentage of HCHO2 molecules that are dissociated, assuming the equation for the freezing-point depression holds for the total concentration of molecules and ions in the solution.arrow_forwardConcentrated hydrochloric acid contains 1.00 mol HCl dissolved in 3.31 mol H2O. What is the mole fraction of HCl in concentrated hydrochloric acid? What is the molal concentration of HCl?arrow_forward
- What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? a. 250 g (0.25 kg) b. 500 g (0.500 kg) c. 1000 g (1.000 kg) d. 2000 g (2.000 kg)arrow_forwardFor each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Oxygen gas in water with P = 1 atm and T = 10C Oxygen gas in water with P = 1 atm and T = 20C b. Nitrogen gas in water with P = 2 atm and T = 50C Nitrogen gas in water with P = 1 atm and T = 70C c. Table salt in water with P = 1 atm and T = 40C Table salt in water with P = 1 atm and T = 70C d. Table sugar in water with P = 3 atm and T = 30C Table sugar in water with P = 1 atm and T = 80Carrow_forwardFor each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Ammonia gas in water with P = 1 atm and T = 50C Ammonia gas in water with P = 1 atm and T = 90C b. Carbon dioxide gas in water with P = 2 atm and T = 50C Carbon dioxide gas in water with P = 1 atm and T = 50C c. Table salt in water with P = 1 atm and T = 60C Table salt in water with P = 1 atm and T = 50C d. Table sugar in water with P = 2 atm and T = 40C Table sugar in water with P = 1 atm and T = 70Carrow_forward
- Consider three test tubes. Tube A has pure water. Tube B has an aqueous 1.0 m solution of ethanol, C2H5OH. Tube C has an aqueous 1.0 m solution of NaCl. Which of the following statements are true? (Assume that for these solutions 1.0m=1.0M.) (a) The vapor pressure of the solvent over tube A is greater than the solvent pressure over tube B. (b) The freezing point of the solution in tube B is higher than the freezing point of the solution in tube A. (c) The freezing point of the solution in tube B is higher than the freezing point of the solution in tube C. (d) The boiling point of the solution in tube B is higher than the boiling point of the solution in tube C. (e) The osmotic pressure of the solution in tube B is greater than the osmotic pressure of the solution in tube C.arrow_forwardFructose, C6H12O6, is a sugar occurring in honey and fruits. The sweetest sugar, it is nearly twice as sweet as sucrose (cane or beet sugar). How much water should be added to 1.75 g of fructose to give a 0.125 m solution?arrow_forwardWill red blood cells swell, remain the same size, or shrink when placed in each of the solutions in Problem 8-101? Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? a. 0.92%(m/v) glucose solution b. 0.92%(m/v) NaCl solution c. 2.3%(m/v) glucose solution d. 5.0%(m/v) NaCl solutionarrow_forward
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