Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 10, Problem 10.53PAE
Interpretation Introduction
Interpretation:
In order to rank entropy, the values must be standardized.
Concept introduction:
- For a forward process, the entropy of the universe must increase
- Negative entropy for given systems must be accompanied by an increase in the entropy of the universe, typically, the surrounding entropy
- The entropy change for a system is given by final minus initial states of entropy.
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Indicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are false
(f) SO:
Best Lewis Structure
3
e group geometry:_
shape/molecular geometry:,
(g) CF2CF2
Best Lewis Structure
polarity:
e group arrangement:_
shape/molecular geometry:
(h) (NH4)2SO4
Best Lewis Structure
polarity:
e group arrangement:
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
Sketch (with angles):
1.
Problem Set 3b
Chem 141
For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing
bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the
molecule is polar or non-polar (iv)
(a) SeF4
Best Lewis Structure
e group arrangement:_
shape/molecular geometry:
polarity:
(b) AsOBr3
Best Lewis Structure
e group arrangement:_
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
Chapter 10 Solutions
Chemistry for Engineering Students
Ch. 10 - Prob. 1COCh. 10 - . explain the concept of entropy in your own...Ch. 10 - Prob. 3COCh. 10 - . state the second law of thermodynamics in words...Ch. 10 - Prob. 5COCh. 10 - Prob. 6COCh. 10 - Prob. 7COCh. 10 - Prob. 8COCh. 10 - Prob. 9COCh. 10 - Prob. 10CO
Ch. 10 - Prob. 10.1PAECh. 10 - Prob. 10.2PAECh. 10 - Prob. 10.3PAECh. 10 - Prob. 10.4PAECh. 10 - Prob. 10.5PAECh. 10 - Use the web to learn how many pounds of plastics...Ch. 10 - On the basis of your experience, predict which of...Ch. 10 - In the thermodynamic definition of a spontaneous...Ch. 10 - 1f the combustion of butane is spontaneous, how...Ch. 10 - Identify each of the processes listed as...Ch. 10 - Identify each of the processes listed as...Ch. 10 - Athletic trainers use instant ice packs that can...Ch. 10 - Are any of the following exothermic processes not...Ch. 10 - Enthalpy changes often help predict whether or not...Ch. 10 - When a fossil fuel burns, is that fossil fuel the...Ch. 10 - Murphy's law is a whimsical rule that says that...Ch. 10 - Prob. 10.17PAECh. 10 - Prob. 10.18PAECh. 10 - Prob. 10.19PAECh. 10 - Some games include dice with more than six sides....Ch. 10 - How does probability relate to spontaneity?Ch. 10 - Prob. 10.22PAECh. 10 - For each pair of items, tell which has the higher...Ch. 10 - Prob. 10.24PAECh. 10 - Prob. 10.25PAECh. 10 - For each process, tell whether the entropy change...Ch. 10 - Without doing a calculation, predict whether the...Ch. 10 - For the following chemical reactions, predict the...Ch. 10 - Prob. 10.29PAECh. 10 - Prob. 10.30PAECh. 10 - Prob. 10.31PAECh. 10 - Prob. 10.32PAECh. 10 - According to Lambert, leaves lying in the yard and...Ch. 10 - Prob. 10.34PAECh. 10 - What happens to the entropy of the universe during...Ch. 10 - Prob. 10.36PAECh. 10 - One statement of the second law of thermodynamics...Ch. 10 - Prob. 10.38PAECh. 10 - How does the second law of thermodynamics explain...Ch. 10 - Prob. 10.40PAECh. 10 - Prob. 10.41PAECh. 10 - Which reaction occurs with the greater increase in...Ch. 10 - Which reaction occurs with the greater increase in...Ch. 10 - Methanol is burned as fuel in some race cars. This...Ch. 10 - Limestone is predominantly CaCO3, which can...Ch. 10 - Suppose that you find out that a system has an...Ch. 10 - Use tabulated thermodynamic data to calculate the...Ch. 10 - Prob. 10.48PAECh. 10 - Calculate S for the dissolution of magnesium...Ch. 10 - Calculate the standard entropy change for the...Ch. 10 - Through photosynthesis, plants build molecules of...Ch. 10 - Find websites describing two different attempts to...Ch. 10 - Prob. 10.53PAECh. 10 - Prob. 10.54PAECh. 10 - A beaker of water at 400 C(on the left in the...Ch. 10 - Describe why it is easier to use Gto determine the...Ch. 10 - Under what conditions does G allow us to predict...Ch. 10 - There is another free energy state function, the...Ch. 10 - 10.45 Calculate G at 45°C for reactions for which...Ch. 10 - 10.46 Discuss the effect of temperature change on...Ch. 10 - The reaction CO2(g)+H2(g)CO(g)+H2O(g) is not...Ch. 10 - Prob. 10.62PAECh. 10 - Prob. 10.63PAECh. 10 - For the reaction NO(g)+NO2(g)N2O3(g) , use...Ch. 10 - 10.51 The combustion of acetylene was used in...Ch. 10 - Natural gas (methane) is being used in...Ch. 10 - Silicon forms a series of compounds analogous to...Ch. 10 - Explain why Gf of O2 (g) is zero.Ch. 10 - Using tabulated thermodynamic data, calculate G...Ch. 10 - Using tabulated thermodynamic data, calculate G...Ch. 10 - Calculate G for the dissolution of both sodium...Ch. 10 - Phosphorus exists in multiple solid phases,...Ch. 10 - 10.59 The normal melting point of benzene, C6H6,...Ch. 10 - Prob. 10.74PAECh. 10 - Estimate the temperature range over which each of...Ch. 10 - Recall that incomplete combustion of fossil fuels...Ch. 10 - During polymerization, the system usually becomes...Ch. 10 - Prob. 10.78PAECh. 10 - Prob. 10.79PAECh. 10 - The recycling of polymers represents only one...Ch. 10 - Diethyl ether is a liquid at normal temperature...Ch. 10 - Calculate the entropy change, S , for the...Ch. 10 - Gallium metal has a melting point of 29.8°C. Use...Ch. 10 - Methane can be produced from CO and H2.The process...Ch. 10 - 10.85 Iodine is not very soluble in water, but it...Ch. 10 - The enthalpy of vaporization for water is 40.65 kJ...Ch. 10 - Determine whether each of the following statements...Ch. 10 - Nickel metal reacts with carbon monoxide to form...Ch. 10 - Polyethylene has a heat capacity of 2,3027 J g-1...Ch. 10 - A key component in many chemical engineering...Ch. 10 - The reaction shown below is involved in the...Ch. 10 - Using only the data given below, determine G for...Ch. 10 - The graph below shows G as a function of...Ch. 10 - Prob. 10.94PAECh. 10 - Prob. 10.95PAECh. 10 - Prob. 10.96PAECh. 10 - Prob. 10.97PAECh. 10 - Prob. 10.98PAECh. 10 - Thermodynamics provides a way to interpret...Ch. 10 - Prob. 10.100PAECh. 10 - 10.101 Fluorine reacts with liquid water to form...Ch. 10 - 10.102 Ammonia can react with oxygen gas to form...Ch. 10 - Prob. 10.103PAECh. 10 - 10.104 (a) When a chemical bond forms, what...
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