A student opens a stack of new playing cards and shuffles them. In the light of the quoted paragraph, have the cards increased in entropy? Explain your answer in terms of thermodynamics . Explain the agent (the shuffler) undergoes an increase in entropy. Concept introduction: Entropy is an amount of the inaccessible energy in a closed thermodynamic system which is also generally considered to be a measure of the disorder of the system, which is a property of the state of the system, and that changes precisely with any reversible change in heat in the system and inversely with the temperature of the system; broadly: the level of disorder or instability in a system.

Question

" is The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: :Ö: HO + Bicarbonate is crucial for the control of body pH (for example, blood pH: 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO₂ 2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.

Answer 1

Question

Chapter 10, Problem 10.30PAE

Interpretation Introduction

Interpretation:

A student opens a stack of new playing cards and shuffles them. In the light of the quoted paragraph, have the cards increased in entropy? Explain your answer in terms of thermodynamics. Explain the agent (the shuffler) undergoes an increase in entropy.

Concept introduction:

Entropy is an amount of the inaccessible energy in a closed thermodynamic system which is also generally considered to be a measure of the disorder of the system, which is a property of the state of the system, and that changes precisely with any reversible change in heat in the system and inversely with the temperature of the system; broadly: the level of disorder or instability in a system.

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" is The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: :Ö: HO + Bicarbonate is crucial for the control of body pH (for example, blood pH: 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO₂ 2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.

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