Concept explainers
(a)
Interpretation: The curved arrows that show the movement of electrons in step [1] are to be added.
Concept introduction: In the representation of a
(b)
Interpretation: The curved arrows that helps in the identification of structure X in the given reaction are to be drawn and the conversion of structure X into phenol and HCl is to be shown in step [3].
Concept introduction: In the representation of a chemical reaction, the movement of electrons is shown by the curved arrows. This method shows the movement of electrons of electrons in resonance structures as well.
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Chapter 1 Solutions
ORGANIC CHEMISTRY
- Consider lisinopril, a drug used primarily in the treatment of high blood pressure, heart failure, and after heart attacks. (a) Complete the Lewis structure of lisinopril, showing all valence electrons. (b) Use the valence-shell electron-pair repulsion (VSEPR) model (Section 3.10) to predict all bond angles in lisinopril. (c) Which is the most polar bond in lisinopril? (d) Is lisinopril polar or nonpolar? (e) Is lisinopril expected to possess resonance (Section 3.9)? Explain why or why not. (f) Name the various functional groups in lisinopril. (g) What is the molecular formula of lisinopril? (h) What intermolecular forces are expected to exist between molecules of lisinopril in close proximity to one another (Section 5.7)?arrow_forward(a) Draw a line drawing for the Lewis diagram given below. Hint start converting the Lewis to a VSEPR diagram. H H H +4 H H (b) What is the line drawing for a chemical species with the condensed molecular formula -H CH3CHC(CH3)CH(CH3)2. Hint start by converting the condensed formula to a Lewis diagram....then you solve this just like Question 1(a)!. (c) Of course, concepts can be examined in reverse! Draw a VSEPR diagram THAT IS ALSO A BEST LEWIS DIAGRAM, for the chemical that has the following line drawing: H₂N IOarrow_forwardDraw the molecules in Problem 1.61 using line structuresarrow_forward
- 1.78 (a) Add curved arrows to show how the starting material A is converted to the product B. (b) Draw all reasonable resonance structures for B. (c) Draw the resonance hybrid for B. A Вarrow_forwardChemistry (a) Write three more resonance structures for each of compounds 1 and 2. (b) In each of compounds 1 and 2, determine which resonance structure contributes the most and explain your answer. (c) Are the 3/4 structures resonance structures or different compounds? Same question for 5/6 structures. Explain your answers.arrow_forwardUsing just a periodic table (not a table of electronegativities), decide which of these is likely to be the most polar bond. Explain your answer! (a) C-F (b) S-F (c) Si-F (d) O-Farrow_forward
- answer true or flase. don't need an explanation or solution (a) A covalent bond is formed between two atoms whose difference in electronegativity is less than 1.9. (b) If the difference in electronegativity between two atoms is zero (they have identical electronegativ- ities), then the two atoms will not form a covalent bond. (c) A covalent bond formed by sharing two electrons is called a double bond. (d) In the hydrogen molecule (H2), the shared pair of electrons completes the valence shell of each hydrogen. (e) In the molecule CH4 , each hydrogen has an electron configuration like that of helium and carbon has an electron configuration like that of neon. (f) In a polar covalent bond, the more electronegative atom has a partial negative charge (2) and the less electronegative atom has a partial positive charge (1). (g) These bonds are arranged in order of increasing polarity CiH , NiH , OiH. (h) These bonds are arranged in order of increasing polarity HiF , HiCl , HiBr. ( i) A…arrow_forwardanswer all sub partsarrow_forward3. The following are some molecules:H2, HF, CO2, H2O, Cl2, NH3, CH4, CHCl3 (a) Which of the above molecules do/does not contain polar bond? Explain your answer. (b) Which covalent bond has the highest bond polarity among the eight molecules? (c) (i) Which of the above molecules are non-polar molecules? (ii) Explain why these molecules are non-polar. 4. (d) Draw a diagram to illustrate the formation of hydrogen bonds in H2O.arrow_forward
- (a) Complete the Lewis structure for vinyl chloride by showing all unshared pairs of electrons. (b) Predict the H-C-H, H-C-C, and Cl-C-H bond angles in this molecule. (c) Does vinyl chloride have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forwardConsider the theoretical molecule KrCl3‾. (a) Draw a valid Lewis structure for KrCl3‾. Show all lone pairs and use lines for bonds. Label all non-zeroformal charges on individual atoms and show the overall charge, if it exists, using square brackets.(b) What would you expect to be the molecular geometry for this ion? Fully explain your thought process,including all details about how successive lone pairs should be positioned within this electron geometry.(c) Draw this ion in 3-D, using hashed and wedged bonds as appropriate. Do not worry about labeling the overall or formal charge.arrow_forwardWhat is the structural diagram of CH2ClF without lone pairs? Also what is its Electronegativity bond after you subtract the smaller from the greater value along with its bond type, total lone pairs of electrons and total bonding pairs of electrons? Lastly, is it polar or non polar (polar molecularity) ?arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning