ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 1, Problem 1.57P
Predict all bond angles in each compound.
a.
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Predict all bond angles in each compound.
a. CH3Cl
b. NH2OH
c. CH2=NCH3
d. HC≡CCH2OH
1. Complete the following table.
Molecular Formula
Atom
a
b
C
C₂H4O
2. Use the Lewis structure below to complete the following table.
d
H
b
Lewis Structure
H
a
H
H-C-C
C-H
H-C-O:
H
Electron Geometry
Line-Angle Structure
H H
:O: H
C
||||--
H
H
C
CC H
d
Hybridization
to
3. Identify the functional groups in the Lewis structure from question #2.
Approx. Bond Angle
8. For each molecular fomula, detem ine the electron pair geom etry (EPG), make a 3-dimensional
representation, and determ ine the molecular geometry. Determine whether the molecule is polar or non-
polar. All of these have central atoms surounded by term inal atom s/one pairs only.
Formula
A. CHF3
Lewis structure
EPG
3-D drawing
Mol Geom.
Polar molecule?
B. SF2
Chapter 1 Solutions
ORGANIC CHEMISTRY
Ch. 1 - While the most common isotope of nitrogen has a...Ch. 1 - Label each bond in the following compounds as...Ch. 1 - How many covalent bonds are predicted for each...Ch. 1 - Draw a valid Lewis structure for each species. a....Ch. 1 - Draw an acceptable Lewis structure for each...Ch. 1 - Prob. 1.6PCh. 1 - Draw a Lewis structure for each ion. a. CH3Ob....Ch. 1 - Prob. 1.8PCh. 1 - Draw Lewis structures for each molecular formula....Ch. 1 - Classify each pair of compounds as isomers or...
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Draw a second resonance structure for each species...Ch. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Using the principles of VSEPR theory, you can...Ch. 1 - Convert each condensed formula to a Lewis...Ch. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Convert each skeletal structure to a complete...Ch. 1 - What is the molecular formula of quinine, the...Ch. 1 - Draw in all hydrogens and lone pairs on the...Ch. 1 - Prob. 1.26PCh. 1 - What orbitals are used to form each of the CC, and...Ch. 1 - What orbitals are used to form each bond in the...Ch. 1 - Determine the hybridization around the highlighted...Ch. 1 - The unmistakable odor of a freshly cut cucumber is...Ch. 1 - Prob. 1.31PCh. 1 - Rank the following atoms in order of increasing...Ch. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - Provide the following information about...Ch. 1 - Use the ball-and-stick model to answer each...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Assign formal charges to each carbon atom in the...Ch. 1 - Assign formal charges to each and atom in the...Ch. 1 - Prob. 1.41PCh. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 1.46PCh. 1 - Prob. 1.47PCh. 1 - Prob. 1.48PCh. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Prob. 1.52PCh. 1 - Consider compounds A-D, which contain both a...Ch. 1 - Prob. 1.54PCh. 1 - Prob. 1.55PCh. 1 - 1.56 Consider the compounds and ions with curved...Ch. 1 - 1.57 Predict all bond angles in each...Ch. 1 - 1.58 Predict the geometry around each highlighted...Ch. 1 - Prob. 1.59PCh. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - 1.61 Convert each molecule into a skeletal...Ch. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Predict the hybridization and geometry around each...Ch. 1 - Prob. 1.65PCh. 1 - Ketene, , is an unusual organic molecule that has...Ch. 1 - Rank the following bonds in order of increasing...Ch. 1 - Prob. 1.68PCh. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Prob. 1.71PCh. 1 - Anacin is an over-the-counter pain reliever that...Ch. 1 - Answer the following questions about acetonitrile...Ch. 1 - Prob. 1.74PCh. 1 - 1.75 The principles of this chapter can be...Ch. 1 -
a. What is the hybridization of each N atom in...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - Prob. 1.82PCh. 1 - Prob. 1.83PCh. 1 - Prob. 1.84PCh. 1 - Prob. 1.85P
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- In addition to CO, CO2, and C3O2, there is another molecular oxide of carbon, pentacarbon dioxide, C5O2, a yellow solid. (a) What is the approximate C-to-C-to-O bond angle in pentacarbon dioxide? (b) What is the approximate C-to-C-to-C bond angle in this compound?arrow_forwardWhich of these molecules and ions contain polar bonds? Which of these molecules and ions have dipole moments? (a) H3O (b) PCl4 (c) SnCl3 (d) BrCl4 (e) ICI3 (f) XeF4 (g) SF2arrow_forwardWhat is the approximate ClCCl bond angle in phosgene, COCl2? (Carbon is the central atom in this compound.) (a) 90 (b) 109.5 (c) 120 (d) 180arrow_forward
- Consider the following compounds: CO2, SO2, KrF2, SO3, NF3, IF3, CF4, SF4, XeF4, PF5, TF5, and SCl6. These 12 compounds are all examples of different molecular structures. Draw the Lewis structures for each and predict the molecular structures. Predict the bond angles and the polarity of each. (A polar molecule has a net dipole moment, while a nonpolar molecule does not.) See Exercises 25 and 26 for the molecular structures based on the trigonal bipyramid and the octahedral geometries.arrow_forwarda Carbonyl fluoride, COF2, is an extremely poisonous gas used in organofluorine synthesis. Give the valence bond description of the carbonyl fluoride molecule. (Both fluorine atoms are attached to the carbon atom.) b Nitrogen, N2, makes up about 80% of the earths atmosphere. Give the valence bond description of this molecule.arrow_forwardWhich compound contains at least one pi bond?A. C O 2B. CHC l 3C. As I 3D. Be F 2arrow_forward
- Using BEST Lewis structures and the VSEPR model, match each molecular formula with the molecular geometry that describes it.arrow_forwardConsider NH3 and PH3. Electronegativities: P = 2.1, H = 2.1, N=3.0. Which statement is false? O A. The P-H bonds are more polar than the N-H bonds. OB. The bond dipoles in NH3 are directed toward the nitrogen atom. For PH3 there is no bond dipole moment. OC. Both are sp hybridized at the central atom. に O D. There are no false statements. All of these statements are corect. OE. Both molecules are polar.arrow_forwarda. Predict the molecular structure and bond angles for ICI5. Approximate bond angles are sufficient. Molecular Structure %3D Bond Angles = b. Predict the molecular structure and bond angles for SeO2. Approximate bond angles are sufficient. Molecular Structure %3D Bond Angles = %3Darrow_forward
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