II.2- Saponification of ethyl ethanoate, a second-order kinetic? Data: R = 8.314 J mol- K-1 The kinetic study of the saponification reaction of ethyl ethanoate by caustic soda (sodium hydroxide NaOH): CH3COOCH2CH3 + OH → CH3CO2 + CH3CH2OH was achieved at 298 K for initial concentrations a in ester and hydroxide that are identical. Experimental results, for different values of a, are reported in the following table: a (mol L-') 0.1 7.5 x 10-2 5 x 10-2 4 x 10-2 t1/2 (s) 6.66 x105 8.89 x105 1.33 x106 1.66 x106 For the initial concentration a = 5 x 10-2 mol L-', calculate the value of the time that is necessary for the concentration in ethanol CH3CH2OH to reach 5 x 10-3 mol L-'.

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II.2- Saponification of ethyl ethanoate, a second-order kinetic?
Data: R = 8.314 J mol-' K-'
The kinetic study of the saponification reaction of ethyl ethanoate by caustic soda (sodium hydroxide
NaOH):
CH3COOCH2CH3 + OH → CH;CO2¯ + CH3CH2OH
was achieved at 298 K for initial concentrations a in ester and hydroxide that are identical.
Experimental results, for different values of a, are reported in the following table:
a (mol L-')
0.1
7.5 × 10-2
5 x 10-2
4 x 10-2
t1/2 (s)
6.66 ×10$
8.89 ×10$
1.33 ×106
1.66 ×106
For the initial concentration a = 5 × 10-² mol L-', calculate the value of the time that is
necessary for the concentration in ethanol CH;CH2OH to reach 5 × 103 mol L-'.
Transcribed Image Text:II.2- Saponification of ethyl ethanoate, a second-order kinetic? Data: R = 8.314 J mol-' K-' The kinetic study of the saponification reaction of ethyl ethanoate by caustic soda (sodium hydroxide NaOH): CH3COOCH2CH3 + OH → CH;CO2¯ + CH3CH2OH was achieved at 298 K for initial concentrations a in ester and hydroxide that are identical. Experimental results, for different values of a, are reported in the following table: a (mol L-') 0.1 7.5 × 10-2 5 x 10-2 4 x 10-2 t1/2 (s) 6.66 ×10$ 8.89 ×10$ 1.33 ×106 1.66 ×106 For the initial concentration a = 5 × 10-² mol L-', calculate the value of the time that is necessary for the concentration in ethanol CH;CH2OH to reach 5 × 103 mol L-'.
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