kinetics of the reaction OCI OI+CI studied in basic aqueous media by Chia and Connick (J. Phys. Chem. 63:1518 9). The initial rate of I disappearance is given below for mixtures of various I compositions, at 25°C (None of the solutions initially contained OI or Cl Initial concentration of OCI (mol/L) 1.5 x 103 Initial concentration of OH (mol/L) 1.00 1.00 2.00 1.5 x 10 ¹ 3x10-3 3 x 10 ¹ 1.00 Initial oncentration of I (mol/L) 2 x 10 ¹ 4x10 ¹ 2 x 10¹ 4 x 10-¹ rate law can be expressed in the form kI OCI POH. dt Initial rate (mol L 's ¹) 1.8 x 10 3.6 x 10 1.8 x 10 7.2 x 10 Part A Find the value of a. Express your answer as an integer. a= ΠΙΑΣΦ Submit Request Answer Part B A OIE Find the value of b. Express your answer as an integer. IVE ΑΣΦ 4 → C P ? 2

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Part D
Calculate the value of k, including its units.
Express your answer to one significant figure and include the appropriate units.
k=
μA
Value
13
Units
?
Transcribed Image Text:Part D Calculate the value of k, including its units. Express your answer to one significant figure and include the appropriate units. k= μA Value 13 Units ?
The kinetics of the reaction
I + OCI OI + Cl
was studied in basic aqueous media by Chia and Connick [J. Phys. Chem. 63:1518
(1959)]. The initial rate of I disappearance is given below for mixtures of various
initial compositions, at 25°C (None of the solutions initially contained OI or Cl):
Initial
concentration of
OCI (mol/L)
1.5 x 10-³
Initial
concentration of
OH (mol/L)
1.5 x 10-³
3x10-¹
3 x 10-³
Initial
concentration of
I- (mol/L)
2 x 10-²
4x10 ²
-3
2 x 10
4 x 10-²
The rate law can be expressed in the form
d[1]
dt
k[I][OCI | [OH-]º.
1.00
1.00
2.00
1.00
Initial rate
(mol L=¹s ¹)
1.8 x 104
3.6 x 10 4
1.8 x 10-4
7.2 x 104
▼
▼
Part A
Find the value of a.
Express your answer as an integer.
a=
Submit
Part B
|| ΑΣΦ
b=
Find the value of b.
Express your answer as an integer.
Part C
Request Answer
Submit
IVD ΑΣΦ
Request Answer
A
ΠΑΠΑΣΦ
VAX
→
Find the value of C.
Express your answer as an integer.
5 A
E
E
?
?
?
Transcribed Image Text:The kinetics of the reaction I + OCI OI + Cl was studied in basic aqueous media by Chia and Connick [J. Phys. Chem. 63:1518 (1959)]. The initial rate of I disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI or Cl): Initial concentration of OCI (mol/L) 1.5 x 10-³ Initial concentration of OH (mol/L) 1.5 x 10-³ 3x10-¹ 3 x 10-³ Initial concentration of I- (mol/L) 2 x 10-² 4x10 ² -3 2 x 10 4 x 10-² The rate law can be expressed in the form d[1] dt k[I][OCI | [OH-]º. 1.00 1.00 2.00 1.00 Initial rate (mol L=¹s ¹) 1.8 x 104 3.6 x 10 4 1.8 x 10-4 7.2 x 104 ▼ ▼ Part A Find the value of a. Express your answer as an integer. a= Submit Part B || ΑΣΦ b= Find the value of b. Express your answer as an integer. Part C Request Answer Submit IVD ΑΣΦ Request Answer A ΠΑΠΑΣΦ VAX → Find the value of C. Express your answer as an integer. 5 A E E ? ? ?
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