13.74 Methyl acetate, CH,COOCH3, reacts in basic solu-tion to give acetate ion, CH;COO , and methanol, CH,OH.CH,COOCH,(ag) + OH (ag) →CH;COO (ag) + CH;OH(aq)The overall order of the reaction was determined by start-ing with methyl acetate and hydroxide ion at the same con-centrations, so [CH,COOCH3] = [OH]= x. ThenRate = k[CH,COOCH;"[OH¯]" = kx"*n%3D%3DDetermine the overall order and the value of the rate con-stant by plotting the following data assuming first- andthen second-order kinetics.Time (min)[CH,COOCH;] (mollL)0.000.010003.000.007404.000.006835.000.0063410.000.0046320.000.0030430.000.00224

The rate law of the reaction is given as, => Rate = K xm+n where K = rate constant x =…

13.74 Methyl acetate, CH,COOCH, reacts in basic solu- tion to give acetate ion, CH,COO , and methanol, CH,OH. CH,COOCH,(ag) + OH (ag) → CH,COO (aq) + CH,OH(aq) The overall order of the reaction was determined by start- ing with methyl acetate and hydroxide ion at the same con- centrations, so [CH,COOCH;] = [OH ] = x. Then Rate = k[CH,COOCH,J"[OH )" = kx Determine the overall order and the value of the rate con- stant by plotting the following data assuming first- and then second-order kinetics. Time (min) [CH,COOCH,] (mollL) 0.00 0.01000 3.00 0.00740 4.00 0.00683 5.00 0.00634 10.00 0.00463 20.00 0.00304 30.00 0.00224

13.74 Methyl acetate, CH,COOCH, reacts in basic solu- tion to give acetate ion, CH,COO , and methanol, CH,OH. CH,COOCH,(ag) + OH (ag) → CH,COO (aq) + CH,OH(aq) The overall order of the reaction was determined by start- ing with methyl acetate and hydroxide ion at the same con- centrations, so [CH,COOCH;] = [OH ] = x. Then Rate = k[CH,COOCH,J"[OH )" = kx Determine the overall order and the value of the rate con- stant by plotting the following data assuming first- and then second-order kinetics. Time (min) [CH,COOCH,] (mollL) 0.00 0.01000 3.00 0.00740 4.00 0.00683 5.00 0.00634 10.00 0.00463 20.00 0.00304 30.00 0.00224

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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