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The kinetics of the reaction: I⁻ + OCl⁻ ⇄ OI⁻ + Cl⁻ was studied in basic aqueous media by Chia and Connick [ J. Phys. Chem. 63:1518 (1959)]. The initial rate of I⁻ disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI⁻ or Cl⁻ ). 1-)What is the order of the reaction with respect to I⁻? 2-)What is the order of the reaction with respect to I⁻?.

The kinetics of the reaction: I⁻ + OCl⁻ ⇄ OI⁻ + Cl⁻ was studied in basic aqueous media by Chia and Connick [ J. Phys. Chem. 63:1518 (1959)]. The initial rate of I⁻ disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI⁻ or Cl⁻ ). 1-)What is the order of the reaction with respect to I⁻? 2-)What is the order of the reaction with respect to I⁻?.

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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The kinetics of the reaction: I⁻ + OCl⁻ ⇄ OI⁻ + Cl⁻ was studied in basic aqueous media by Chia and Connick [ J. Phys. Chem. 63:1518 (1959)]. The initial rate of I⁻ disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI⁻ or Cl⁻ ).

1-)What is the order of the reaction with respect to I⁻?

2-)What is the order of the reaction with respect to I⁻?. 

3-)What is the order of the reaction with respect to OH⁻?

4-)What is the order of total reaction?

5-)What is the value of the rate constant?

 
 
-d[I-] = k. [1-]*. [OCI-]*. [OH¯]° dt
Transcribed Image Text:-d[I-] = k. [1-]*. [OCI-]*. [OH¯]° dt
Initial Initial Initial Initial rate composition of I- (M) 2 × 10–3 composition composition of (moll-L-1s-1) of OCI- (M) OH- (M) 1.5 x 10-3 1.00 1.8 × 10-4 4 x 10-3 1.5 × 10-3 1.00 3.6 × 10-4 2 × 10-3 3 × 10-3 2.00 1.8 X 10-4 4 x 10-3 3 x 10-3 1.00 7.2 × 10¬4
Transcribed Image Text:Initial Initial Initial Initial rate composition of I- (M) 2 × 10–3 composition composition of (moll-L-1s-1) of OCI- (M) OH- (M) 1.5 x 10-3 1.00 1.8 × 10-4 4 x 10-3 1.5 × 10-3 1.00 3.6 × 10-4 2 × 10-3 3 × 10-3 2.00 1.8 X 10-4 4 x 10-3 3 x 10-3 1.00 7.2 × 10¬4
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