The overall gas phase reaction 3A --> B + 2C occurs via the following sequence of elementary steps 2A <--> I1 + B k1,k2 A + I1 --> 2I2 k2 I2 --> C k3 1. write an expression for the overall reaction rate, r, in terms of the rate step 3, r3 2. using the answer from 1, obtain an expression for the reaction rate, r, in terms of rate constants and concentrations of reactants and products, only use PSSH. 3. State the. specific inequality the must be satisfied for each of the following assumptions to hold, and use it to simplify the general rate expression from question 2. i) Step 1 is quasi-equilibrium ii) Step 1 is irreversible
The overall gas phase reaction 3A --> B + 2C occurs via the following sequence of elementary steps 2A <--> I1 + B k1,k2 A + I1 --> 2I2 k2 I2 --> C k3 1. write an expression for the overall reaction rate, r, in terms of the rate step 3, r3 2. using the answer from 1, obtain an expression for the reaction rate, r, in terms of rate constants and concentrations of reactants and products, only use PSSH. 3. State the. specific inequality the must be satisfied for each of the following assumptions to hold, and use it to simplify the general rate expression from question 2. i) Step 1 is quasi-equilibrium ii) Step 1 is irreversible
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The overall gas phase reaction
3A --> B + 2C
occurs via the following sequence of elementary steps
2A <--> I1 + B k1,k2
A + I1 --> 2I2 k2
I2 --> C k3
1. write an expression for the overall reaction rate, r, in terms of the rate step 3, r3
2. using the answer from 1, obtain an expression for the reaction rate, r, in terms of rate constants and concentrations of reactants and products, only use PSSH.
3. State the. specific inequality the must be satisfied for each of the following assumptions to hold, and use it to simplify the general rate expression from question 2.
i) Step 1 is quasi-equilibrium
ii) Step 1 is irreversible
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