1. (a) A study was made of the effect of hydroxide ion, OH-, concentration on the rate for the following reaction: (aq) + OCH(aq) 10-(aq) + Cl(aq) Experimental data: [OCI-] [OH-] Rate M/sec 0.0013 0.012 0.1 0.0026 0.012 0.1 9.4 X 10-3 18.7 X 10-3 0.0013 0.006 0.1 0.0013 0.018 0.1 0.0013 0.012 0.05 0.0013 0.012 0.2 0.0013 0.018 0.2 4.7 X 10-3 14.0 X 10-3 18.7 x 10-3 4.7 X 10-3 7.0 X 10-3 Determine the rate law and the value of the rate constant, k.

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  1. (a) A study was made of the effect of hydroxide ion, OH–, concentration on the rate for the following reaction:

I(aq) + OCl(aq) ----------------> IO(aq) + Cl(aq)

Experimental data:

[I]

[OCl–]

[OH–]

Rate M/sec

0.0013

0.012

0.1

9.4 x 10-3

0.0026

0.012

0.1

18.7 x 10-3

0.0013

0.006

0.1

4.7 x 10-3

0.0013

0.018

0.1

14.0 x 10-3

0.0013

0.012

0.05

18.7 x 10-3

0.0013

0.012

0.2

4.7 x 10-3

0.0013

0.018

0.2

7.0 x 10-3

1. (a) A study was made of the effect of hydroxide ion, OH-, concentration on the rate
for the following reaction:
(aq) + OCH(aq)
10-(aq) + Cl(aq)
Experimental data:
[OCI-]
[OH-]
Rate M/sec
0.0013
0.012
0.1
0.0026
0.012
0.1
9.4 X 10-3
18.7 X 10-3
0.0013
0.006
0.1
0.0013
0.018
0.1
0.0013
0.012
0.05
0.0013
0.012
0.2
0.0013
0.018
0.2
4.7 X 10-3
14.0 X 10-3
18.7 x 10-3
4.7 X 10-3
7.0 X 10-3
Determine the rate law and the value of the rate constant, k.
Transcribed Image Text:1. (a) A study was made of the effect of hydroxide ion, OH-, concentration on the rate for the following reaction: (aq) + OCH(aq) 10-(aq) + Cl(aq) Experimental data: [OCI-] [OH-] Rate M/sec 0.0013 0.012 0.1 0.0026 0.012 0.1 9.4 X 10-3 18.7 X 10-3 0.0013 0.006 0.1 0.0013 0.018 0.1 0.0013 0.012 0.05 0.0013 0.012 0.2 0.0013 0.018 0.2 4.7 X 10-3 14.0 X 10-3 18.7 x 10-3 4.7 X 10-3 7.0 X 10-3 Determine the rate law and the value of the rate constant, k.
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