The reaction A=B is first order with respect to A. We experimentally determined the values of the rate constant, k, at various temperatures, plotted the product Tlnk against temperature T, and obtained the straight line in the figure below:

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Chapter1: Chemical Foundations
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EX5
The reaction A=B is first order with respect to A. We experimentally determined the
values of the rate constant, k, at various temperatures, plotted the product Tlnk against
temperature T, and obtained the straight line in the figure below:
Tink/K
1500
1000
500
0
-500
-1000
-1500
-2000
-2500
340 360 380 400 420 440 460 480 500 520
T/K
Using the method of least squares we found that the equation of this line is:
y = 22.11x10224. Explain why this reaction obeys the Arrhenius equation and
calculate the values of the Arrhenius parameters.
Supt. You will start from the relation Ink
=
InA
EA
RT
Transcribed Image Text:EX5 The reaction A=B is first order with respect to A. We experimentally determined the values of the rate constant, k, at various temperatures, plotted the product Tlnk against temperature T, and obtained the straight line in the figure below: Tink/K 1500 1000 500 0 -500 -1000 -1500 -2000 -2500 340 360 380 400 420 440 460 480 500 520 T/K Using the method of least squares we found that the equation of this line is: y = 22.11x10224. Explain why this reaction obeys the Arrhenius equation and calculate the values of the Arrhenius parameters. Supt. You will start from the relation Ink = InA EA RT
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