The reaction A=B is first order with respect to A. We experimentally determined the values of the rate constant, k, at various temperatures, plotted the product Tlnk against temperature T, and obtained the straight line in the figure below:
The reaction A=B is first order with respect to A. We experimentally determined the values of the rate constant, k, at various temperatures, plotted the product Tlnk against temperature T, and obtained the straight line in the figure below:
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![EX5
The reaction A=B is first order with respect to A. We experimentally determined the
values of the rate constant, k, at various temperatures, plotted the product Tlnk against
temperature T, and obtained the straight line in the figure below:
Tink/K
1500
1000
500
0
-500
-1000
-1500
-2000
-2500
340 360 380 400 420 440 460 480 500 520
T/K
Using the method of least squares we found that the equation of this line is:
y = 22.11x10224. Explain why this reaction obeys the Arrhenius equation and
calculate the values of the Arrhenius parameters.
Supt. You will start from the relation Ink
=
InA
EA
RT](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb4d74cef-f64d-4ed0-a004-41e9fb8cce2f%2F24851442-964e-4971-b7c5-7c23cd17b11a%2Fvzqvjni_processed.jpeg&w=3840&q=75)
Transcribed Image Text:EX5
The reaction A=B is first order with respect to A. We experimentally determined the
values of the rate constant, k, at various temperatures, plotted the product Tlnk against
temperature T, and obtained the straight line in the figure below:
Tink/K
1500
1000
500
0
-500
-1000
-1500
-2000
-2500
340 360 380 400 420 440 460 480 500 520
T/K
Using the method of least squares we found that the equation of this line is:
y = 22.11x10224. Explain why this reaction obeys the Arrhenius equation and
calculate the values of the Arrhenius parameters.
Supt. You will start from the relation Ink
=
InA
EA
RT
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