6. The rate constant of the following second-order reaction of hydroxyl radical with 1,2- dichloroethane: OH(g) + CICH;CH,(g) → H20(g) + CIchCH;cl(g) was investigated experimentally and the following table was obtained TPC k/s a. What is the reaction order, why? b. Determine the Arrhenius parameters for this reactions c. Calculate the enthalpy, entropy, and free energy of activation at 298 K using Eyring equation for the transition complex (See page 338-343 Chapter 18 for part b and c 15.7 4.57 10.0 21.5 8.24 27.5 33.2 28.40 38.5 46.10 45.7 2.08 15.80 93.50

6. The rate constant of the following second-order reaction of hydroxyl radical with 1,2- dichloroethane: OH(g) + CICH;CH,(g) → H20(g) + CIchCH;cl(g) was investigated experimentally and the following table was obtained TPC k/s a. What is the reaction order, why? b. Determine the Arrhenius parameters for this reactions c. Calculate the enthalpy, entropy, and free energy of activation at 298 K using Eyring equation for the transition complex (See page 338-343 Chapter 18 for part b and c 15.7 4.57 10.0 21.5 8.24 27.5 33.2 28.40 38.5 46.10 45.7 2.08 15.80 93.50

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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