Suppose a pair of chemical compounds A and B can react in two different ways: A+B C Reaction 1 gives product C. A+BD Reaction 2 gives product D. The following facts are known about the two reactions: . Both reactions are exothermic, but the heat of reaction of Reaction #1 is larger. • If a reaction vessel is charged ("filled") with A and B, then at first D is produced faster than C. Use these facts to sketch a qualitative reaction energy diagram for both reactions. Note: because these sketches are only qualitative, the energies don't have to be exact. They only have to have the right relationship to each other. For example, if one energy is less than another, that fact should be clear in your sketch. energy A+B Reaction 1. energy A+B Reaction 2 olo Ar E DEATH OF A BACHELOR

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Chapter1: Chemical Foundations
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Relating activation energy to reaction rate
Suppose a pair of chemical compounds A and B can react in two different ways:
A+B C Reaction 1 gives product C.
Reaction 2 gives product D.
A+B= → D
The following facts are known about the two reactions:
Both reactions are exothermic, but the heat of reaction of Reaction #1 is larger.
• If a reaction vessel is charged ("filled") with A and B, then at first. is produced faster than C.
Use these facts to sketch a qualitative reaction energy diagram for both reactions.
Note: because these sketches are only qualitative, the energies don't have to be exact. They only have to have the right relationship to each other. For
example, if one energy is less than another, that fact should be clear in your sketch.
energy
A + B
Reaction 1
reaction coordinate
C
energy
A + B
Reaction 2
reaction coordinate
55
D
?
olo
18
Ar
Al·
DEATH OF A BACHELOR
Transcribed Image Text:Relating activation energy to reaction rate Suppose a pair of chemical compounds A and B can react in two different ways: A+B C Reaction 1 gives product C. Reaction 2 gives product D. A+B= → D The following facts are known about the two reactions: Both reactions are exothermic, but the heat of reaction of Reaction #1 is larger. • If a reaction vessel is charged ("filled") with A and B, then at first. is produced faster than C. Use these facts to sketch a qualitative reaction energy diagram for both reactions. Note: because these sketches are only qualitative, the energies don't have to be exact. They only have to have the right relationship to each other. For example, if one energy is less than another, that fact should be clear in your sketch. energy A + B Reaction 1 reaction coordinate C energy A + B Reaction 2 reaction coordinate 55 D ? olo 18 Ar Al· DEATH OF A BACHELOR
Writing the rate law implied by a simple mechanism with an initial slow...
Suppose the formation of nitryl fluoride proceeds by the following mechanism:
step
elementary reaction
1 NO₂ (g) +F₂ (g) → NO₂F (g)+F(g)
2
F (g) + NO₂ (g) → NO₂F (g)
Write the balanced chemical
equation for the overall
chemical reaction.
Suppose also k₁ « k₂. That is, the first step is much slower than the second.
<<
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
rate
rate constant
= k 0
k₁
k₂
×
Ś
?
olo
18
Ar
AE
DEATH OF A BACHELOR
Transcribed Image Text:Writing the rate law implied by a simple mechanism with an initial slow... Suppose the formation of nitryl fluoride proceeds by the following mechanism: step elementary reaction 1 NO₂ (g) +F₂ (g) → NO₂F (g)+F(g) 2 F (g) + NO₂ (g) → NO₂F (g) Write the balanced chemical equation for the overall chemical reaction. Suppose also k₁ « k₂. That is, the first step is much slower than the second. << Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate rate constant = k 0 k₁ k₂ × Ś ? olo 18 Ar AE DEATH OF A BACHELOR
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