For the reaction: 2Y + T - B + H, the mechanism below is proposed, in which M is a reactive intermediate, and its concentration is maintained at some low steady-state throughout the reaction. 1.2Y M + B 2. T+ M → X + H Note that only the reverse reaction of step one is significant Determine the rate law for this reaction. Select one: O A. -d[T]/dt = kµ[Y][T]/(k₁' [B]+ k₂[T]) B._-d[T]/dt = ka[Y]²/k1'[B] + k2[T] C. -d[T]/dt = ka[Y]²[T]/[B] OD. -d[T]/dt = ka[Y]²/(kb [B]/[T] + 1)

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 32P
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For the reaction: 2Y + T
B + H, the mechanism
below is proposed, in
which M is a reactive intermediate,
and its concentration is maintained at
some low steady-state throughout the
reaction.
1.2Y M + B
2. T+ M → X + H
Note that only the reverse reaction of
step one is significant
Determine the rate law for this
reaction.
Select one:
A. -d[T]/dt = k[Y][T]/(k₁' [B]+ k₂[T])
OB. -d[T]/dt = ka[Y]²/k1'[B] + k2[T]
C. -d[T]/dt = ka[Y]²[T]/[B]
OD. -d[T]/dt = ka[Y]²/(kb [B]/[T] + 1)
C
Transcribed Image Text:For the reaction: 2Y + T B + H, the mechanism below is proposed, in which M is a reactive intermediate, and its concentration is maintained at some low steady-state throughout the reaction. 1.2Y M + B 2. T+ M → X + H Note that only the reverse reaction of step one is significant Determine the rate law for this reaction. Select one: A. -d[T]/dt = k[Y][T]/(k₁' [B]+ k₂[T]) OB. -d[T]/dt = ka[Y]²/k1'[B] + k2[T] C. -d[T]/dt = ka[Y]²[T]/[B] OD. -d[T]/dt = ka[Y]²/(kb [B]/[T] + 1) C
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