4. Consider the reaction: 2 A + B → products The tentative rate law is: rate k [A]* [B]" 2 experiments were performed. For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked. This is an isolation experiment which simplifies the determination of the rate law. For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M Use integrated rate equations to determine The order wrt [A]. а. Exp.1 Exp. 2 Time [A] (M) [A] (M) O min 1.000 x 10 1.000 x 10 0.951 x 10 0.975 x 10 Compare the rates of rx for Exp. 1 & 2 to determine the order of rx wrt [B]. b. 1 min 5 min 0.779 x 10* 0.883 x 10* 10 min 0.607 x 10 0.779 x 10* 20 min 0.368 x 10 0.607 x 10
4. Consider the reaction: 2 A + B → products The tentative rate law is: rate k [A]* [B]" 2 experiments were performed. For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked. This is an isolation experiment which simplifies the determination of the rate law. For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M Use integrated rate equations to determine The order wrt [A]. а. Exp.1 Exp. 2 Time [A] (M) [A] (M) O min 1.000 x 10 1.000 x 10 0.951 x 10 0.975 x 10 Compare the rates of rx for Exp. 1 & 2 to determine the order of rx wrt [B]. b. 1 min 5 min 0.779 x 10* 0.883 x 10* 10 min 0.607 x 10 0.779 x 10* 20 min 0.368 x 10 0.607 x 10
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![4. Consider the reaction: 2 A + B → products
The tentative rate law is: rate = k [A]* [B]
2 experiments were performed.
For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked.
This is an isolation experiment which simplifies the determination of the rate law.
Use integrated rate equations to determine
The order wrt [A].
For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M
%3D
%3D
a.
Exp.1
Exp. 2
Time
[A] (M)
[A] (M)
O min
1.000 x 10°
1.000 x 10°
0.951 x 10
0.975 x 10
Compare the rates of rx for Exp. 1 & 2 to
determine the order of rx wrt [B].
b.
1 min
5 min
0.779 x 10
0.883 x 10°
10 min
0.607 x 10°
0.779 x 10
20 min
0.368 x 10
0.607 x 10°](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb6ab40b9-7bd3-4bb2-b274-ffa816f68e79%2F4bb4f0f6-6975-4671-b1ee-c0d56fe43bf0%2Fwlw5q_processed.jpeg&w=3840&q=75)
Transcribed Image Text:4. Consider the reaction: 2 A + B → products
The tentative rate law is: rate = k [A]* [B]
2 experiments were performed.
For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked.
This is an isolation experiment which simplifies the determination of the rate law.
Use integrated rate equations to determine
The order wrt [A].
For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M
%3D
%3D
a.
Exp.1
Exp. 2
Time
[A] (M)
[A] (M)
O min
1.000 x 10°
1.000 x 10°
0.951 x 10
0.975 x 10
Compare the rates of rx for Exp. 1 & 2 to
determine the order of rx wrt [B].
b.
1 min
5 min
0.779 x 10
0.883 x 10°
10 min
0.607 x 10°
0.779 x 10
20 min
0.368 x 10
0.607 x 10°
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