Consider the following reactions: A -> B (1) B + M -> C (2) Assume M is present in great excess. The concentrations of B and C are zero at t =0. (a) Write out the rate equations for A, B and C (b) Assuming the pseudo-steady -state approximation for B, derive a set of equations for the time dependent variation in concentration of A, B and C
Consider the following reactions: A -> B (1) B + M -> C (2) Assume M is present in great excess. The concentrations of B and C are zero at t =0. (a) Write out the rate equations for A, B and C (b) Assuming the pseudo-steady -state approximation for B, derive a set of equations for the time dependent variation in concentration of A, B and C
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. Consider the following reactions:
A -> B (1)
B + M -> C (2)
Assume M is present in great excess. The concentrations of B and C are zero at t =0.
(a) Write out the rate equations for A, B and C
(b) Assuming the pseudo-steady -state approximation for B, derive a set of equations for
the time dependent variation in concentration of A, B and C
Expert Solution
Step 1
The rate equation derives the relationship between rate of forward reaction to the rate constant and concentration of reactants involved in it, where each concentration term is raised to the respective partial orders of reaction.
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