O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Br,(g) → NOB1,(g) NOBr, (g) + N0(g) →2 NOB1(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced On chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = the reverse of the two elementary reactions in the mechanism. olo

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O KINETICS AND EQUILIBRIUM
Writing the rate law implied by a simple mechanism
Suppose the reaction between nitric oxide and bromine proceeds by the
following mechanism:
step
elementary reaction
rate constant
1
NO(g) + Br,(g) → NOB1,(g)
k1
2 NOB1,(g) + NO(g) →2 NOBr(g)
Suppose also k,»k,. That is, the first step is much faster than the second.
Write the balanced
equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
rate = k
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k1, k2,
and (if necessary) the rate
constants k-1 and k-2 for
k =
the reverse of the two
elementary reactions in
the mechanism.
olo
Transcribed Image Text:O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Br,(g) → NOB1,(g) k1 2 NOB1,(g) + NO(g) →2 NOBr(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k-1 and k-2 for k = the reverse of the two elementary reactions in the mechanism. olo
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