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2. At 325°C, NO,(g) reacts with CO(g) to yield NO(g) and CO,(g). The reaction is: NO,(g) + CO(g) I NO(g) + CO,(g) It is observed that the reaction rate does not depend upon the concentration of CO, and t\so the reaction rate law does not involve [CO]. The rate does depend upon [NO,], however, and the following data is obtained. Determine the rate law and the value of the rate constant. Rate ( M sec ") 1. 1 X 10 -² NO,] 0.15 4.5 X 102 0.3 1.8 X 10- 4.0 X 1013 0.6 0.9

2. At 325°C, NO,(g) reacts with CO(g) to yield NO(g) and CO,(g). The reaction is: NO,(g) + CO(g) I NO(g) + CO,(g) It is observed that the reaction rate does not depend upon the concentration of CO, and t\so the reaction rate law does not involve [CO]. The rate does depend upon [NO,], however, and the following data is obtained. Determine the rate law and the value of the rate constant. Rate ( M sec ") 1. 1 X 10 -² NO,] 0.15 4.5 X 102 0.3 1.8 X 10- 4.0 X 1013 0.6 0.9

Chemistry for Engineering Students
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.35PAE: 11.35 For the reaction 2 NO(g) + 2 H?(g) — N,(g) + 2 H,O(g) at 1100°C, the following data have been...
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2. At 325°C, N0,(g) reacts with CO(g) to yield NO(g) and CO,(g). The reaction is: NO,(g) + CO(g) I NO(g) + CO,(g) It is observed that the reaction rate does not depend upon the concentration of CO, and t\so the reaction rate law does not involve [CO]. The rate does depend upon [NO,], however, and the following data is obtained. Determine the rate law and the value of the rate constant. Rate ( M sec ') NO,] 1. 1 X 10 -2 0.15 4.5 X 10-2 0.3 1.8 X 10- 4.0 X 10-13 0.6 0.9
Transcribed Image Text:2. At 325°C, N0,(g) reacts with CO(g) to yield NO(g) and CO,(g). The reaction is: NO,(g) + CO(g) I NO(g) + CO,(g) It is observed that the reaction rate does not depend upon the concentration of CO, and t\so the reaction rate law does not involve [CO]. The rate does depend upon [NO,], however, and the following data is obtained. Determine the rate law and the value of the rate constant. Rate ( M sec ') NO,] 1. 1 X 10 -2 0.15 4.5 X 10-2 0.3 1.8 X 10- 4.0 X 10-13 0.6 0.9
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