A sample of Melbourne drinking water was injected into an ion chromatograph. The anions were separatedisocratically via ion-exchange using 4 mM NaOH as eluent and detected by conductivity after chemicalsuppression. The system void volume ( t) occurred at 1.25 minutes, while chloride and sulfate were eluted at3.12 and 6.62 minutes respectively. The eluent concentration was then increased to 10 mM The new retentiontime for chloride is:

Given: Void time = 1.25 min ts for chlorides = 3.12 min ts for sulfate = 6.62 min

Answered: A sample of Melbourne drinking water…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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The complete ionic composition of natural waters often is not known, aquatic chemists have developed equations to estimate ionic strength (/) from readily available information such as electrical conductivity (e.g., specific conductance (SC) in µS/cm) or total dissolved solids (TDS): /= 1.6 × 10-5 × SC (for 1 <0.06); / = 1.3 × 10-5 × SC (for 1 < 0.5) /= 2.5 x 10-5 × TDS; TDS ≈ b × SC (b= 0.55-0.70) Your field measurement of a stream sample gave a specific conductance of 100 µS/cm, and your analysis of the water gave concentrations of Na+, Ca²+, Cl-, and HCO3 of 9, 21, 6, and 45 mg/L, respectively. Are these measurements consistent?
Introductlon In Part (a) of this experiment you will prepare a primary standard. Potassium hydrogen phthalate (KHP) is a monoprotic acid with the formula KHC,H.O. In this experiment KHP is used as the primary standard. A standard solution is one whose solute concentration is accurately known. If a solute can be obtained in a very pure, stable, weighable form, a primary standard solution of it can be prepared directly. You will then use the standardized sodium hydroxide solution to determine the acetic acid content of a dilute unknown solution. Procedure (0) Preparation of a Primory Standard Potassium hydrogen phthalate (KHP) is a primary standard. Weigh accurately by difference, approximately 0.8 g of KHP in a clean, dry weighing bottle and transfer it into a 250 ml conical flask. Add 75 ml of distilled water. Swirl gently. Cover the flask and leave to dissolve, swirling periodicaly. Cautlon: KHP is not highly soluble and care must be taken to ensure it is all dissolved before you…
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3.) The following Beer's Law calibration plot was collected at 391.9 nm using the five mixtures listed above. The trendline equation was y = 4617.1x. A saturated solution of lead(II) chromate had an absorbance of 0.0025. Calculate its solubility, in molarity. Molar Solubility of PbCrO4: x 107 M ABSORBANCE VS CHROMATE CONCENTRATION AT 391.9 NM 1.40 1.20 y = 4617.1x R-0.9972 1.00 0.80 0.60 0.40 0.20 0.00 C 0.00005 0.0001 0.00015 0.0002 0.00025 0.0003 Chromate concentration (mol.L)
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If 30.0 mL of water that is 0.0500 M in Q is to be extracted with four 10.0-mL portions of an immiscible organic solvent, what is the minimum distribution coefficient that allows transfer of all but the following percentages of the solute to the organic layer: (a) 1.00 X10-24 (b) 1.00 X10-22
5) Retention factors for three solutes separated on a C8 nonpolar stationary phase at pH = 3 are given. Eluant was a 70:30 vol/vol mixture of 50 mM citrate buffer and methanol. a)Draw the dominant chemical structure of each of the substances at pH = 3. b)The retention factor for acetophenone is 4.21, for salicylic acid is 2.97, and for nicotine is zero. Explain the different retention factors.
You must separate three different compounds with reversed phase HPLC. Compound 1 is an acid (pKa = 4.3), compound 2 is neutral compounds and compound 3 is a base (pKa = 9.6). As eluent, use 30/70 (v / v)% methanol / pH 3.0 formic acid buffer. The retention time and the top width at the base of the top for the three components are presented below. You can assume the dead time to 1.2 minutes in your calculations.Compound Retention time [minutes] Peak width [seconds] 1 10.1 282 5.0 143 6.1 17a) Calculate the efficiency (number of theoretical bases) for component 1.b) Calculate the selectivity and resolution between components 1 and 2.c) When you increase the pH of your eluent to pH 6, how will the retention be affected (increase, decreaseor unchanged) for the different associations (1, 2 and 3) ?, justify your answer.d) How retention factors are generally affected by an increase in the proportion organicallymobile phase solvents for reversed phase HPLC separations ?, justify your…
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