Solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS)
Problem 1RQ:
Define the following: a. spontaneous process b. entropy c. positional probability d. system e....Problem 2RQ:
What is the second law of thermodynamics? For any process, there are four possible sign combinations...Problem 3RQ:
What determines Ssurr for a process? To calculate Ssurr at constant pressure and temperature, we use...Problem 4RQ:
The free energy change, G, for a process at constant temperature and pressure is related to Suniv...Problem 5RQ:
What is the third law of thermodynamics? What are standard entropy values, S, and how are these S...Problem 6RQ:
What is the standard free energy change, G, for a reaction? What is the standard free energy of...Problem 7RQ:
If you calculate a value for G for a reaction using the values of Gf in Appendix 4 and get a...Problem 8RQ:
Consider the equation G = G + RT ln(Q). What is the value of G for a reaction at equilibrium? What...Problem 9RQ:
Even if G is negative, the reaction may not occur. Explain the interplay between the thermodynamics...Problem 10RQ:
Discuss the relationship between wmax and the magnitude and sign of the free energy change for a...Problem 1ALQ:
For the process A(l) A(g), which direction is favored by changes in energy probability? Positional...Problem 3ALQ:
Gas A2 reacts with gas B2 to form gas AB at a constant temperature. The bond energy of AB is much...Problem 4ALQ:
What types of experiments can be carried out to determine whether a reaction is spontaneous? Does...Problem 5ALQ:
A friend tells you, Free energy G and pressure P are related by the equation G = G + RT ln(P). Also,...Problem 7ALQ:
Predict the sign of S for each of the following and explain. a. the evaporation of alcohol b. the...Problem 8ALQ:
Is Ssurr favorable or unfavorable for exothermic reactions? Endothermic reactions? Explain.Problem 9ALQ:
At 1 atm, liquid water is heated above 100C. For this process, which of the following choices (iiv)...Problem 11Q:
The synthesis of glucose directly from CO2 and H2O and the synthesis of proteins directly from amino...Problem 12Q:
When the environment is contaminated by a toxic or potentially toxic substance (for example, from a...Problem 14Q:
Human DNA contains almost twice as much information as is needed to code for all the substances...Problem 15Q:
A mixture of hydrogen gas and chlorine gas remains unreacted until it is exposed to ultraviolet...Problem 16Q:
Consider the following potential energy plots: a. Rank the reactions from fastest to slowest and...Problem 18Q:
Given the following illustration, what can be said about the sign of S for the process of solid NaCl...Problem 19Q:
The third law of thermodynamics states that the entropy of a perfect crystal at 0 K is zero. In...Problem 20Q:
The deciding factor on why HF is a weak acid and not a strong acid like the other hydrogen halides...Problem 21Q:
List three different ways to calculate the standard free energy change, G, for a reaction at 25C....Problem 22Q:
What information can be determined from G for a reaction? Does one get the same information from G,...Problem 23Q:
Monochloroethane (C2H5Cl) can be produced by the direct reaction of ethane gas (C2H6) with chlorine...Problem 24Q:
At 1500 K, the process I2(g)2I(g)10atm10atm is not spontaneous. However, the process...Problem 25E:
Which of the following processes are spontaneous? a. Salt dissolves in H2O. b. A clear solution...Problem 26E:
Which of the following processes are spontaneous? a. A house is built. b. A satellite is launched...Problem 27E:
Table 16-1 shows the possible arrangements of four molecules in a two-bulbed flask. What are the...Problem 28E:
Consider the following illustration of six molecules of gas in a two-bulbed flask. a. What is the...Problem 29E:
Consider the following energy levels, each capable of holding two particles: Draw all the possible...Problem 30E:
Redo Exercise 29 with two particles A and B, which can be distinguished from each other.Problem 31E:
Choose the substance with the larger positional probability in each case. a. 1 mole of H2 (at STP)...Problem 32E:
Which of the following involve an increase in the entropy of the system? a. melting of a solid b....Problem 34E:
Calculate Ssurr for the following reactions at 25C and 1 atm. a. C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(l)...Problem 35E:
Given the values of H and S, which of the following changes will be spontaneous at constant T and p?...Problem 36E:
At what temperatures will the following processes be spontaneous? a. H = 18 kJ and S = 60. J/K b. H...Problem 37E:
Ethanethiol (C2H5SH; also called ethyl mercaptan) is commonly added to natural gas to provide the...Problem 38E:
For mercury, the enthalpy of vaporization is 58.51 kJ/mol and the entropy of vaporization is 92.92...Problem 39E:
For ammonia (NH3), the enthalpy of fusion is 5.65 kJ/mol and the entropy of fusion is 28.9 J/K mol....Problem 40E:
The enthalpy of vaporization of ethanol is 38.7 kJ/mol at its boiling point (78C). Determine Ssys,...Problem 41E:
Predict the sign of S for each of the following changes. Assume all equations are balanced. a. b. c....Problem 42E:
Predict the sign of S for each of the following changes. a. K(s) + 12Br2(g) KBr(s) b. N2(g) +...Problem 43E:
For each of the following pairs of substances, which substance has the greater value of S? a....Problem 44E:
For each of the following pairs, which substance has the greater value of S? a. N2O (at 0 K) or He...Problem 45E:
Predict the sign of S and then calculate S for each of the following reactions. a. 2H2S (g) + SO2(g)...Problem 46E:
Predict the sign of S and then calculate S for each of the following reactions. a. H2(g) + 12O2(g) ...Problem 47E:
For the reaction C2H2(g)+4F2(g)2CF4(g)+H2(g) S is equal to 358 J/K. Use this value and data from...Problem 48E:
For the reaction CS2(g)+3O2(g)CO2(g)+2SO2(g) S is equal to 143 J/K. Use this value and data from...Problem 49E:
It is quite common for a solid to change from one structure to another at a temperature below its...Problem 50E:
Two crystalline forms of white phosphorus are known. Both forms contain P4 molecules, but the...Problem 51E:
Consider the reaction 2O(g)O2(g) a. Predict the signs of H and S. b. Would the reaction be more...Problem 53E:
From data in Appendix 4, calculate H, S, and G for each of the following reactions at 25C. a. CH4(g)...Problem 54E:
The major industrial use of hydrogen is in the production of ammonia by the Haber process:...Problem 55E:
For the reaction at 298 K, 2NO2(g)N2O4(g) the values of H and S are 58.03 kJ and 176.6 J/K,...Problem 56E:
At 100C and 1.00 atm, H = 40.6 kJ/mol for the vaporization of water. Estimate G for the vaporization...Problem 57E:
Given the following data: 2H2(g)+C(s)CH4(g)G=51kJ2H2(g)+O2(g)2H2O(l)G=474kJC(s)+O2(g)CO2G=394kJ...Problem 58E:
Given the following data:...Problem 59E:
For the reaction SF4(g)+F2(g)SF6(g) the value of G is 374 kJ. Use this value and data from Appendix...Problem 60E:
The value of G for the reaction 2C4H10(g)+13O2(g)8CO2(g)+10H2O(l) is 5490. kJ. Use this value and...Problem 61E:
Consider the reaction Fe2O3(s)+3H2(g)2Fe(s)+3H2O(g) a. Use Gf values in Appendix 4 to calculate G...Problem 62E:
Consider the reaction 2POCl3(g)2PCl3(g)+O2(g) a. Calculate G for this reaction. The Gfvalues for...Problem 63E:
Using data from Appendix 4, calculate H, S and G for the following reactions that produce acetic...Problem 65E:
Using data from Appendix 4, calculate G for the reaction NO(g)+O3(g)NO2(g)+O2(g) for these...Problem 66E:
Using data from Appendix 4, calculate G for the reaction 2H2S(g)+SO2(g)3Srhombic(s)+2H2O(g) for the...Problem 67E:
Consider the reaction 2NO2(g)N2O4(g) For each of the following mixtures of reactants and products at...Problem 68E:
Consider the following reaction: N2(g)+3H2(g)2NH3(g) Calculate G for this reaction under the...Problem 69E:
One of the reactions that destroys ozone in the upper atmosphere is NO(g)+O3(g)NO2(g)+O2(g) Using...Problem 70E:
Hydrogen sulfide can be removed from natural gas by the reaction 2H2S(g)+SO2(g)3S(s)+2H2O(g)...Problem 71E:
Consider the following reaction at 25.0C: 2NO2(g)N2O4(g) The values of H and S are 58.03 kJ/mol and...Problem 72E:
The standard free energies of formation and the standard enthalpies of formation at 298 K for...Problem 74E:
The Ostwald process for the commercial production of nitric acid involves three steps:...Problem 75E:
Cells use the hydrolysis of adenosine triphosphate, abbreviated as ATP, as a source of energy....Problem 76E:
One reaction that occurs in human metabolism is For this reaction G= 14 kJ at 25c. a. Calculate K...Problem 77E:
Consider the following reaction at 800. K: N2(g)+3F2(g)2NF3(g) An equilibrium mixture contains the...Problem 78E:
Consider the following reaction at 298 K: 2SO2(g)+O2(g)2SO3(g) An equilibrium mixture contains O2(g)...Problem 79E:
Consider the relationship In(K)=HRT+SR The equilibrium constant for some hypothetical process was...Problem 80E:
The equilibrium constant K for the reaction 2CI(g)CI2(g) was measured as a function of temperature...Problem 82AE:
Some water is placed in a coffee-cup calorimeter. When 1.0 g of an ionic solid is added, the...Problem 84AE:
Calculate the entropy change for the vaporization of liquid methane and liquid hexane using the...Problem 85AE:
As O2(l) is cooled at 1 atm, it freezes at 54.5 K to form solid I. At a lower temperature, solid I...Problem 87AE:
Using the following data, calculate the value of Ksp for Ba(NO3)2, one of the least soluble of the...Problem 88AE:
Many biochemical reactions that occur in cells require relatively high concentrations of potassium...Problem 89AE:
Carbon monoxide is toxic because it bonds much more strongly to the iron in hemoglobin (Hgb) than...Problem 90AE:
In the text, the equation G=G+RTIn(Q) was derived for gaseous reactions where the quantities in Q...Problem 92AE:
Use the equation in Exercise 79 to determine H and S for the autoionization of water:...Problem 94AE:
Consider the following diagram of free energy (G) versus fraction of A reacted in terms of moles for...Problem 96CWP:
For rubidium Hvapo=69.0KJ/mol at 686C, its boiling point. Calculate S, q, w, and E for the...Problem 97CWP:
Given the thermodynamic data below, calculate S and Ssurr for the following reaction at 25C and 1...Problem 98CWP:
Consider the reaction: H2S(g)+SO2(g)3S(g)+2H2O(l) for which H is 233 kJ and S is 424 J/K. a....Problem 99CWP:
The following reaction occurs in pure water: H2O(l)+H2O(l)H3O+(aq)+OH-(aq) which is often...Problem 101CWP:
Consider the reaction: PCl3(g)+Cl2(g)PCl5(g) At 25C, H = 92.50 kJ. Which of the following statements...Problem 102CWP:
The equilibrium constant for a certain reaction increases by a factor of 6.67 when the temperature...Problem 103CP:
Consider two perfectly insulated vessels. Vessel 1 initially contains an ice cube at 0C and water at...Problem 104CP:
Liquid water at 25C is introduced into an evacuated, insulated vessel. Identify the signs of the...Problem 105CP:
Using data from Appendix 4, calculate H, G, and K (at 298 K) for the production of ozone from...Problem 106CP:
Entropy can be calculated by a relationship proposed by Ludwig Boltzmann: S=kIn(W) where k = 1.38 ...Problem 107CP:
a. Using the free energy profile for a simple one-step reaction, show that at equilibrium K = kf/kr,...Problem 108CP:
Consider the reaction H2(g)+Br2(g)2HBr(g) where H = 103.8 kJ/mol. In a particular experiment, equal...Problem 109CP:
Consider the system A(g)B(g) at25C. a. Assuming that GAo=8996J/molandGBo=11,718J/mol, calculate the...Problem 110CP:
The equilibrium constant for a certain reaction decreases from 8.84 to 3.25 102 when the...Problem 111CP:
If wet silver carbonate is dried in a stream of hot air. the air must have a certain concentration...Problem 112CP:
Carbon tetrachloride (CCl4) and benzene (C6H6) form ideal solutions. Consider an equimolar solution...Problem 113CP:
Sodium chloride is added to water (at 25C) until it is saturated. Calculate the Cl concentration in...Problem 114CP:
You have a 1.00-L sample of hot water (90.0C) sitting open in a 25.0C room. Eventually the water...Problem 115CP:
Consider a weak acid, HX. If a 0.10-M solution of HX has a pH of 5.83 at 25C. what is G for the...Problem 116IP:
Some nonelectrolyte solute (molar mass = 142 g/mol) was dissolved in 150. mL of a solvent (density =...Problem 117IP:
For the equilibrium A(g)+2B(g)C(g) the initial concentrations are [A] = [B] = [C] = 0.100 atm. Once...Browse All Chapters of This Textbook
Chapter 1 - Chemical FoundationsChapter 2 - Atoms, Molecules, And IonsChapter 3 - StoichiometryChapter 4 - Types Of Chemical Reactions And Solution StoichiometryChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - Atomic Structure And PeriodicityChapter 8 - Bonding: General ConceptsChapter 9 - Covalent Bonding: OrbitalsChapter 10 - Liquids And Solids
Chapter 11 - Properties Of SolutionsChapter 12 - Chemical KineticsChapter 13 - Chemical EquilibriumChapter 14 - Acids And BasesChapter 15 - Acid-base EquilibriaChapter 16 - Solubility And Complex Ion EquilibriaChapter 17 - Spontaneity, Entropy, And Free EnergyChapter 18 - ElectrochemistryChapter 19 - The Nucleus: A Chemist's ViewChapter 20 - The Representative ElementsChapter 21 - Transition Metals And Coordination ChemistryChapter 22 - Organic And Biological Molecules
Sample Solutions for this Textbook
We offer sample solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS) homework problems. See examples below:
Chapter 1, Problem 1RQChapter 1, Problem 30EChapter 1, Problem 35EChapter 1, Problem 36EChapter 1, Problem 38EChapter 1, Problem 45EChapter 1, Problem 57EChapter 1, Problem 59EChapter 1, Problem 60E
Chapter 1, Problem 63EChapter 1, Problem 64EChapter 1, Problem 73EChapter 1, Problem 113CPChapter 2, Problem 1RQChapter 2, Problem 64EChapter 2, Problem 67EChapter 2, Problem 68EExplanation: Atomic number given is 13. From the periodic table we can identify that the element...Chapter 2, Problem 71EExplanation: To determine: The naming of CuI The name of CuI is copper(I) iodide. In naming of...Explanation: To determine: The naming of HC2H3O2 The naming of HC2H3O2 is acetic acid. Rules for...To determine: The formula of of sulfur difluoride The formula of sulfur difluoride is SF2 Sulfur...Explanation: To determine: The formula of sodium oxide. The formula of sodium oxide is Na2O The...Chapter 2, Problem 86EChapter 2, Problem 88EExplanation: To determine: The formula and the name of the binary compound formed from Ca and N. The...Explanation: To determine: The explanation for the term “counting by weighing”. The stated concept,...Chapter 3, Problem 59EChapter 3, Problem 60EChapter 3, Problem 61EExplanation: Given The mass of P4O6 is 1.00 g . The molar mass of P4O6 is 219.866 g/mol . Formula...Chapter 3, Problem 64EChapter 3, Problem 67EChapter 3, Problem 68EChapter 3, Problem 71EChapter 3, Problem 73EChapter 3, Problem 76EChapter 3, Problem 79EChapter 3, Problem 100EChapter 3, Problem 109EChapter 3, Problem 119EChapter 3, Problem 121EChapter 3, Problem 124EChapter 3, Problem 150AEChapter 3, Problem 152CWPChapter 3, Problem 180IPChapter 4, Problem 1RQChapter 4, Problem 7RQExplanation: NaBr(s)→Na(aq)++Braq- Figure 1 Let us consider the above molecular-level pictures of...Explanation: Record the given data Moles of Sodium phosphate= 0.200 moles Volume of the solution=...Chapter 4, Problem 66EChapter 4, Problem 79EChapter 4, Problem 82EChapter 4, Problem 93AEChapter 4, Problem 121CPChapter 4, Problem 122CPChapter 4, Problem 123CPExplanation Record the given data Mass of the sample mixture = 0.205 g Mass of the precipitate =...Explanation: Given: Record the given data Upstream at which the stream rate flows = 5.00×104 L/s...Chapter 4, Problem 144MPChapter 4, Problem 145MPA barometer consists of Mercury column that is tipped inverted and positioned in a dish containing...Chapter 5, Problem 41EExplanation: The relation between pressures measured in the manometers containing mercury and...Explanation According to ideal gas equation, PV=nRT By rearranging the above equation, PVnT=R Since...Chapter 5, Problem 88EExplanation: To find: the mole fractions of CH4 and O2 in the given mixture if the partial pressure...Explanation To find: the number of moles of dimethyl hydrazine from its given mass. The number of...Explanation To determine: The partial pressure of carbon monoxide Partial pressure of carbon...Explanation To determine: The mixing ratio of benzene Mixing ratio of benzene = 9.47 × 10-3ppmv For...Explanation: The mass percent from the given data is, 26.1% Carbon13.1% Hydrogen61.0% Nitrogen Mass...Chapter 5, Problem 135AEExplanation To find: the empirical formula of the compound Convert the mass percent to gram 58.51%...Chapter 5, Problem 139AEChapter 5, Problem 152CPChapter 5, Problem 153CPExplanation To determine: Mass of hot air when the average molar mass of air 29.0g/mol Mass of hot...Chapter 5, Problem 162IPChapter 6, Problem 1RQChapter 6, Problem 20QChapter 6, Problem 34EChapter 6, Problem 50EChapter 6, Problem 52EChapter 6, Problem 79EChapter 6, Problem 80EExplanation: The balanced equation is: a) N2(g)→N2(l) In (a) the volume of products is decreases...Chapter 6, Problem 108AEChapter 6, Problem 115AEChapter 6, Problem 130CPChapter 6, Problem 131CPChapter 6, Problem 134IPChapter 6, Problem 135IPChapter 6, Problem 137MPChapter 7, Problem 1RQChapter 7, Problem 24QChapter 7, Problem 43EChapter 7, Problem 57EChapter 7, Problem 58EChapter 7, Problem 61EChapter 7, Problem 62EChapter 7, Problem 63EChapter 7, Problem 74EChapter 7, Problem 79EChapter 7, Problem 81EChapter 7, Problem 82EChapter 7, Problem 86EChapter 7, Problem 87EChapter 7, Problem 94EChapter 7, Problem 95EChapter 7, Problem 97EChapter 7, Problem 142AEChapter 7, Problem 171CPChapter 8, Problem 1RQExplanation: Refer to figure 3-4. The electro negativity of carbon (C) , nitrogen (N) , and oxygen...Explanation: Refer to figure 3-4 The electro negativity of Sodium (Na) Potassium (K) and Rubidium...Chapter 8, Problem 46EChapter 8, Problem 47EChapter 8, Problem 49EExplanation: In a periodic table the size of ions depends on the nuclear attraction on the valence...Chapter 8, Problem 54EChapter 8, Problem 62EChapter 8, Problem 81EChapter 8, Problem 84EChapter 8, Problem 89EChapter 8, Problem 101EChapter 8, Problem 102EChapter 8, Problem 129AEChapter 8, Problem 154CPChapter 8, Problem 155CPChapter 9, Problem 1RQChapter 9, Problem 23EChapter 9, Problem 24EChapter 9, Problem 26EChapter 9, Problem 29EChapter 9, Problem 30EChapter 9, Problem 39EChapter 9, Problem 52EChapter 9, Problem 53EChapter 9, Problem 63AEChapter 9, Problem 89CPChapter 10, Problem 1RQChapter 10, Problem 41EExplanation: CCl4 , CBr4, CF4 Identify the compound which has highest boiling point and justify it....Chapter 10, Problem 53EChapter 10, Problem 55EChapter 10, Problem 56EChapter 10, Problem 57EChapter 10, Problem 58EChapter 10, Problem 59EChapter 10, Problem 60EChapter 10, Problem 62EChapter 10, Problem 80EChapter 10, Problem 88EChapter 10, Problem 131CPChapter 10, Problem 146CPChapter 10, Problem 148IPExplanation: To explain molarity Molarity can be defined as moles of solute to litres of solution....Chapter 11, Problem 16SRChapter 11, Problem 31EExplanation: Record the given data Gram equivalent of HCl = 0.25 Molarity of HCl = 0.25 M To...Explanation: KrF2 8+2(7)=22e- KrF2 is dissolves in CCl4 . KrF2 is non-polar molecule that makes it...Chapter 11, Problem 55EChapter 11, Problem 79EExplanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: To find the Acetone and water polarity CH3COCH3 and H2O The electrostatic possible...Explanation: Record the given data, Freezing point of an aqueous solution =- 2.79°C To calculate...Mass of Sodium = 285-315 mg Mass of Potassium = 14.1-17.3 mg Mass of Calcium = 4.9-6.0 mg Mass of...Chapter 11, Problem 109AEChapter 11, Problem 120CPChapter 11, Problem 132IPChapter 12, Problem 1RQChapter 12, Problem 30EChapter 12, Problem 33EChapter 12, Problem 35EChapter 12, Problem 36EChapter 12, Problem 58EChapter 12, Problem 84AEChapter 12, Problem 86AEChapter 12, Problem 87AEChapter 12, Problem 91AEChapter 12, Problem 93AEChapter 12, Problem 105CPChapter 12, Problem 112CPChapter 13, Problem 1RQChapter 13, Problem 5ALQChapter 13, Problem 23EChapter 13, Problem 39EChapter 13, Problem 42EChapter 13, Problem 54EChapter 13, Problem 56EChapter 13, Problem 57EChapter 13, Problem 72AEChapter 13, Problem 73AEChapter 13, Problem 78AEChapter 13, Problem 104CPChapter 13, Problem 106CPChapter 14, Problem 1RQChapter 14, Problem 49EChapter 14, Problem 50EChapter 14, Problem 51EChapter 14, Problem 52EChapter 14, Problem 63EChapter 14, Problem 64EChapter 14, Problem 68EChapter 14, Problem 73EChapter 14, Problem 74EExplanation: To determine: The pH, [H+] and [OH−] of (C2H5)3N . The equilibrium constant expression...Chapter 14, Problem 101EChapter 14, Problem 107EChapter 14, Problem 108EChapter 14, Problem 109EChapter 14, Problem 119EChapter 14, Problem 120EChapter 14, Problem 123EChapter 14, Problem 126EChapter 14, Problem 151AEChapter 15, Problem 1RQChapter 15, Problem 7RQChapter 15, Problem 43EChapter 15, Problem 57EChapter 15, Problem 58EChapter 15, Problem 59EChapter 15, Problem 60EChapter 15, Problem 61EChapter 15, Problem 62EChapter 15, Problem 63EChapter 15, Problem 64EChapter 15, Problem 65EExplanation The value of pH of solution when 0.0 mL NaOH has been added is. 1.0_ . Given: The...Chapter 15, Problem 107CWPChapter 16, Problem 1RQExplanation To determine: The solubility product of CaC2O4 . The concentration of Ca2+ is 4.8×10−5...Chapter 16, Problem 22EChapter 16, Problem 27EChapter 16, Problem 28EChapter 16, Problem 35EChapter 16, Problem 36EChapter 16, Problem 37EChapter 16, Problem 40EChapter 16, Problem 53EChapter 16, Problem 70EChapter 16, Problem 102CPChapter 17, Problem 1RQChapter 17, Problem 53EChapter 17, Problem 54EChapter 17, Problem 63EChapter 17, Problem 64EChapter 17, Problem 68EChapter 17, Problem 70EChapter 17, Problem 72EChapter 17, Problem 74EChapter 17, Problem 78EChapter 17, Problem 86AEChapter 17, Problem 90AEChapter 17, Problem 119MPChapter 18, Problem 1RQChapter 18, Problem 16RORRExplanation: Given: I- (aq) + ClO- (aq) →I3− (aq) + Cl-(aq) To write the equations for two...Explanation: Given: Cu (s) + NO3- (aq) →Cu2+ (aq) + NO(g) To write the equations for two...Chapter 18, Problem 47EChapter 18, Problem 75EChapter 18, Problem 76EChapter 18, Problem 85EChapter 18, Problem 86EChapter 18, Problem 95EChapter 18, Problem 115AEChapter 18, Problem 117AEExplanation: Given The given reaction is, Fe(s)+HCl(aq)→HFeCl4(aq)+H2(g) . In this equation, the...Chapter 18, Problem 144CPExplanation The half cell reactions are, Anode: Hg→Hg2++2e− Eanodeο=0.242 V Cathode: 2Ag++2e−→2Ag...Chapter 18, Problem 153CPChapter 18, Problem 159MPExplanation (a) To define: The term thermodynamic stability. The thermodynamic stability is related...Explanation: Alpha particle is emitted. The parent nuclide is 232Th and the nuclide after the...Explanation The most stable isotope is 81Kr and the hottest one is 73Kr The nuclides having longer...Explanation Given The atomic mass of 232Pu is 3.85285×10−22 g . The mass of a neutron is...Explanation The atomic mass of 11H=1.0078 amu The mass of a neutron is 1.0087 amu . Mass of...Explanation Given The value of half life of 87Rb is 4.5×109 years . The decay constant is calculated...Explanation The decay constant is calculated by the formula given below. λ=0.693t1/2 Where t1/2 is...Explanation: The zirconium metal is capable of reducing water to form hydrogen gas at standard...Explanation The number of α and β particles produced are 4_ and 2_ . The mass number of 92238U is...Explanation The nuclear reaction for the synthesis of cobalt- 60 is, 2658Fe+201n→ 2760Co+ −10e . The...Chapter 20, Problem 1RQExplanation The valence electron configuration for halogens is ns2np5 . The common halogen elements...Explanation The value of ΔH° for the given reaction is 180 kJ_ . The stated reaction is,...Explanation: The compound XeO4 and IO4− ion are isoelectronic. The molecule xenon tetroxide (XeO4)...Explanation: The Lewis structure, molecular structure, bond angle and hybridization of central atom...Explanation Given Dimension of room is 10.0 m×10.0 m×10.0 m . Temperature is 25 °C . Pressure is...Explanation: Hydrogen gas is produced by reacting graphite with water. C(s)+H2O(g)→CO(g)+H2(g) The...Explanation: The number of moles of hydrogen gas is 0.249 mol_. Given Mass of alkaline earth metal...Explanation: Mass of radon (Ra) is 25 g_ . Given Mass of pitch-blende is 1.75×108 g . The conversion...Explanation Given Temperature is 900 K . Pressure of In(CH3)3 is 2.00 atm . Volume of In(CH3)3 is...Chapter 20, Problem 108IPChapter 20, Problem 109IPChapter 21, Problem 1RQExplanation: (I) To determine: The geometry and associated bond angles when a metal ion has a...Explanation: Atomic number of Nickel is 28 . Accordingly the electronic configuration is –...Explanation: Atomic number of Nickel is 22 . Accordingly the electronic configuration is –...EXPLANATION (a) To write: The electron configuration of metal ion in (NH4)2[Fe(H2O)2Cl4] . The...Explanation The complex ion is [Ru(NH3)5Cl]2+. This ion contains positive charge. Oxidation state of...Explanation The complex compound is [Co(NH3)6]Cl2 . Oxidation state of Chlorine ion (Cl−) is −1 ....Explanation The complex compound is [Cr(H2O)5Br]Br2 . Oxidation state of Bromine ion (Br−) is −1 ....Explanation The value of ΔH° for the given reaction is −11 kJ_ . For the reaction,...Explanation The reaction that takes place is, 3Fe2O3(s)+CO(g)→2Fe3O4(s)+CO2(g) Refer to Appendix 4....Explanation The given equations are, Co+3+e−→Co+2 Eο=1.82 V (1) Co2++3en→Co(en)32+ K=1.5×1012 (2)...Chapter 21, Problem 99IPChapter 22, Problem 1RQChapter 22, Problem 5RQExplanation: The type of isomerism that could be exhibited by C6H12 and an example that illustrates...Chapter 22, Problem 16EChapter 22, Problem 45EExplanation To determine: The monomer of the given polymer. The monomer is vinyl fluoride. It is an...Explanation The correct name of the compound is 2,3,5,6−Tetramethyl−octane whose structure is shown...Explanation The structure of the given compound 2,3,7,8−tetrachloro−dibenzo−p−dioxin is shown in...Chapter 22, Problem 130AEChapter 22, Problem 136AEExplanation The equilibrium constant for the given reaction is 6.88×10−13_ . The equilibrium...Chapter 22, Problem 148CPExplanation The structure of C5H12 is shown in Figure 1. The structure of C5H12 is, Figure 1 The...Explanation The structure of the polymer of ABS plastic is shown in figure 1. The reaction of Abs...Explanation Given Electronic configuration of M+2 is [Ar]3d10. So, atomic number of M is 30. In...Explanation The empirical formula of the given helicene is C5H3 . Helicene is an aromatic compound...The correct responses are urea and Ammonium cyanate. The first organic compound that is synthesized...Explanation Aldohexose is a six carbon aldehyde sugar with an aldehyde group on one end.
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9th Edition
ISBN: 9781285692333
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13th Edition
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9th Edition
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9th Edition
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10th Edition
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10th Edition
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10th Edition
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11th Edition
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CHEMISTRY-OWLV2 W/STUD.SOLN.MAN.EBOOK
10th Edition
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Chemistry Iae 7ed
7th Edition
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7th Edition
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7th Edition
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7th Edition
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5th Edition
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5th Edition
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4th Edition
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11th Edition
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8th Edition
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8th Edition
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8th Edition
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International Student Edition - Chemistry (chemistry)
8th Edition
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The magic animal.
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8th Edition
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Fast Track To A 5 Preparing For The Ap Chemistry Examination
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8th Edition
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8th Edition
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6th Edition
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Chemistry
6th Edition
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