Bundle: Chemistry for Engineering Stude...3rd EditionLawrence S. Brown, Tom Holme Publisher: Cengage LearningISBN: 9781305367388
Bundle: Chemistry for Engineering Stude...
Solutions for Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Problem 1CO:
Describe the chemical composition of gasoline.Problem 4CO:
Calculate the amounts of reactants needed in a chemical reaction to produce a specified amount of...Problem 4.1PAE:
4.1 List at least two factors that make it difficult to describe the combustion of gasoline...Problem 4.2PAE:
4.2 What is an alkane?Problem 4.4PAE:
4.4 Automobile exhaust often contains traces of formaldehyde (CH2O), which is another possible...Problem 4.5PAE:
4.5 Methane, ethane, and propane are also hydrocarbons, but they are not major components of...Problem 4.6PAE:
4.6 Use the web to research prices of gasoline at the pump for consumers in your area during the...Problem 4.7PAE:
For the following reactions, write the ratios that can be established among molar amounts of the...Problem 4.8PAE:
4.8 In an experiment carried out at very low pressure, 13x1015 molecules of H2 are reacted with...Problem 4.9PAE:
4.9 Sulfur, S8, combines with oxygen at elevated temperatures to form sulfur dioxide. (a) Write a...Problem 4.10PAE:
4.10 How many moles of oxygen can be obtained by the decomposition of 7.5 mol of reactant in each of...Problem 4.11PAE:
4.11 MTBE, C5H12O, is one of the additives that replaced tetraethyl-lead in gasoline. (See Example...Problem 4.12PAE:
4.12 In petroleum refining, hydrocarbons are often manipulated by reacting them with H2(g). If...Problem 4.13PAE:
4.13 For the following reactions, determine the value of x. 4C+S84CS2 mol S8 yields x mol CS2...Problem 4.14PAE:
4.14 The combustion of liquid chloroethylene, C2H3Cl, yields carbon dioxide, steam, and hydrogen...Problem 4.15PAE:
4.15 What mass of the unknown compound is formed in the following reactions? (Assume that reactants...Problem 4.16PAE:
4.16 Many metals react with halogens to give metal halides. For example, iron reacts with chlorine...Problem 4.17PAE:
4.17 Phosgene is a highly toxic gas that has been used as a chemical weapon at times in the past. It...Problem 4.19PAE:
4.19 How many metric tons of carbon are required to react with 7.83 metric tons of Fe2O3 according...Problem 4.20PAE:
4.20 Assuming a charcoal briquette is composed entirely of carbon, what mass of oxygen is needed to...Problem 4.21PAE:
4.21 Ammonium nitrate, NH4NO3, will decompose explosively to form N2, O2, and H2O, a fact that has...Problem 4.22PAE:
If 3.4 mol Al and 6.2 mol Fe2O3 are mixed, what is the limiting reactant? 2Al+ Fe 2 O 3 A1 2 O 3...Problem 4.23PAE:
If 8.4 moles of disilane, Si2H6, is combined with 15.1 moles of O2, which is the limiting reactant?...Problem 4.24PAE:
4.22 Generally, an excess of O2 is needed for the reaction Sn+O2SnO2 . What is the minimum number of...Problem 4.25PAE:
4.23 In the reaction of arsenic with bromine, AsBr5 will form only when excess bromine is present....Problem 4.26PAE:
4.24 Ammonia gas can be prepared by the reaction CaO(s)+2NH4Cl(s)2NH3(g)+H2O(g)+CaCl2(s) If 112 g of...Problem 4.27PAE:
4.25 When octane is combusted with inadequate oxygen, carbon monoxide may form. If 100 g of octane...Problem 4.28PAE:
4.26 The equation for one of the reactions in the process of turning iron ore into the metal is...Problem 4.29PAE:
4.27 Copper reacts with sulfuric acid according to the following equation: 2H2SO4+CuCuSO4+2H2O+SO2...Problem 4.30PAE:
4.28 One of the steps in the manufacture of nitric acid is the oxidation of ammonia shown in this...Problem 4.31PAE:
4.29 When Al(OH)3 reacts with sulfuric acid, the following reaction occurs: 2Al(OH)3+3H2SO4Al2(...Problem 4.32PAE:
4.30 Copper reacts with nitric acid via the following equation: 3Cu(s)+8HNO3(aq)3Cu(...Problem 4.33PAE:
4.31 How much HNO3 can be formed in the following reaction if 3.6 kg of NO2 gas is bubbled through...Problem 4.34PAE:
4.32 Hydrogen and oxygen are reacted and the water formed is collected at 25°C, where it has a...Problem 4.35PAE:
4.33 Silicon carbide, an abrasive, is made by the reaction of silicon dioxide with graphite (solid...Problem 4.38PAE:
4.36 Sometimes students in chemistry labs determine percentage yields greater than 100%. Assuming...Problem 4.39PAE:
4.37 The theoretical yield and the actual yield for various reactions are given below. Determine the...Problem 4.40PAE:
4.38 A reaction that produced 4.8 mg of taxol, an anticancer drug, is reported to have a yield of...Problem 4.41PAE:
Methanol, CH3OH, is used in racing cars because it is a clean-burning fuel. It can be made by this...Problem 4.42PAE:
4.40 When iron and steam react at high temperatures, the following reaction takes place:...Problem 4.43PAE:
4.41 The percentage yield of the following reaction is consistently 87%. CH4(g)+4S(g)CS2(g)+2H2S(g)...Problem 4.44PAE:
4.42 Sulfur hexafluoride is a very stable gas useful ¡n electrical generators and switches. It is...Problem 4.45PAE:
4.43 Magnesium nitride forms in a side reaction when magnesium metal burns in air. This reaction may...Problem 4.46PAE:
4.44 Industrial production of hydrogen gas uses the reaction shown below. If 1.00 metric ton of...Problem 4.47PAE:
4.45 If 21 g of H2S is mixed with 38 g of O2 and 31 g of SO2 forms, what is the percentage yield?...Problem 4.48PAE:
4.46 A mixture of 10.0 g of NO and 14.0 g of NO2 result in the production of 8.52 g of N2O3. What is...Problem 4.49PAE:
4.47 Silicon carbide is, an abrasive used in the manufacture of grinding wheels. A company is...Problem 4.50PAE:
4.48 Elemental phosphorous is used in the semiconductor industry. It can be obtained from an ore...Problem 4.51PAE:
4.49 Small quantities of hydrogen gas can be prepared by the following reaction:...Problem 4.53PAE:
4.51 What is the role of an indicator in a titration?Problem 4.54PAE:
4.52 What volume of 0.812 M HCl, in milliliters, is required to titrate 1.45 g of NaOH to the...Problem 4.57PAE:
Hydrazine, N2H4, is a weak base and can react with an acid such as sulfuric acid:...Problem 4.61PAE:
4.59 Aluminum dissolves in HCI according to the equation written below, whereas copper does not...Problem 4.62PAE:
4.60 Why are fuel additives used?Problem 4.63PAE:
4.61 What is actually measured by the octane ratings of different grades of gasoline?Problem 4.66PAE:
4.64 Using the web, find information about the amount of lead in the environment during the past 50...Problem 4.67PAE:
4.65 Using the web, find out how lead “poisons” the catalyst in a catalytic converter.Problem 4.69PAE:
You have 0.954 g of an unknown acid, H2A, which reacts with NaOH according to the balanced equation...Problem 4.71PAE:
4.79 Phosphoric add (H3PO4) is important in the production of both fertilizers and detergents. It is...Problem 4.72PAE:
4.80 The reaction shown below is used to destroy Freon-12 (CF2Cl2), preventing its release into the...Problem 4.74PAE:
One way of determining blood alcohol levels is by performing a titration on a sample of blood. In...Problem 4.76PAE:
The pictures below show a molecular-scale view of a chemical reaction between the compounds AB2 and...Problem 4.77PAE:
The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce...Problem 4.78PAE:
4.84 Aluminum chloride (AlCl3) is used as a catalyst in the production of polyisobutylene, which is...Problem 4.79PAE:
4.85 In the cold vulcanization of rubber, disulfur dichloride (S2Cl2) is used as a source of sulfur...Problem 4.82PAE:
4.88 A quality control technician needs to determine the percentage of arsenic (As) in a particular...Problem 4.84PAE:
4.90 Iron metal can be refined (rom the mineral hematite (Fe2O3). One way of converting the mineral...Problem 4.87PAE:
4.93 A mixture of methane (CH4) and propane (C3H8) has a total mass of 29.84 g. When the mixture is...Problem 4.98PAE:
4.104 When 2.750 g of the oxide Pb3O4 is heated to a high temperature, it decomposes to produce...Problem 4.100PAE:
4.106 An ore sample with a mass of 670 kg contains 27.7% magnesium carbonate, MgCO3. If all of the...Problem 4.101PAE:
4.107 Existing stockpiles of the refrigerant Freon-12, CF2Cl2 must be destroyed under the terms of...Problem 4.102PAE:
4.108 Elemental analysis is sometimes carried out by combustion of the sample. For a hydrocarbon,...Problem 4.104PAE:
4.110 Write the balanced chemical equation lot the combustion of ethane, C2H6, and answer these...Browse All Chapters of This Textbook
Chapter 1 - Introduction To ChemistryChapter 2 - Atoms And MoleculesChapter 3 - Molecules, Moles, And Chemical EquationsChapter 4 - StoichiometryChapter 5 - GasesChapter 6 - The Periodic Table And Atomic StructureChapter 7 - Chemical Bonding And Molecular StructureChapter 8 - Molecules And MaterialsChapter 9 - Energy And ChemistryChapter 10 - Entropy And The Second Law Of Thermodynamics
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card homework problems. See examples below:
The increase in application of the aluminum is due to its properties such as strength,...Chapter 1, Problem 1.46PAEChapter 1, Problem 1.47PAEChapter 1, Problem 1.59PAEChapter 1, Problem 1.89PAEChapter 2, Problem 1CODue to isotopes of an element we cannot define atomic mass of the element. Each isotope is present...Place the ion in proper manner cation first then anion. Formation of cation from calcium atom:...Chapter 2, Problem 2.19PAE
In the periodic table, elements increase in metallic nature when approaching the “left” side of the...Chapter 3, Problem 1COChapter 3, Problem 3.16PAEChapter 3, Problem 3.34PAEChapter 3, Problem 3.35PAEChapter 3, Problem 3.43PAEChapter 3, Problem 3.64PAEChapter 3, Problem 3.65PAEChapter 3, Problem 3.66PAEMolarity is defined as the number of moles of solute in 1 L of solution. The final solution is 0.45...Chapter 3, Problem 3.98PAEChapter 4, Problem 1COChapter 4, Problem 4.7PAEChapter 4, Problem 4.10PAEChapter 4, Problem 4.14PAEChapter 4, Problem 4.15PAEChapter 4, Problem 4.26PAEChapter 4, Problem 4.31PAEChapter 4, Problem 4.49PAEChapter 4, Problem 4.72PAEGiven information: Total mass of Alloy = 7.264 g Total mass of H2(g) released out = 0.3284 g...Chapter 4, Problem 4.87PAEReactions given below take place to result the given products....The physical properties of gases are as follows: The gases have no fixed shape and volume. The...Chapter 5, Problem 5.33PAEChapter 5, Problem 5.43PAEChapter 5, Problem 5.47PAEChapter 5, Problem 5.65PAENo of moles of gas =mass of gas molar mass of CH4 =15.0 g16.0 g/m ( mass of CH4( given)=15.0 g)molar...The ideal gas equation is as follows: PV=nRT Or, PV=(mM) RT Or, M=mRT/PV =( 2.298 g)( 0.0821 atm...Chapter 5, Problem 5.89PAEThus, total number of moles = [0.40+0.50+0.30] mol = 1.20 mol = N1 As given total pressure = P = 740...Step 1: Write the chemical equation The SO2 and O2 react to produce SO3 according to the equation: 2...Chapter 5, Problem 5.103PAEChapter 6, Problem 1COChapter 6, Problem 16COPauli’s exclusion principle and Hund’s rule are useful in writing electronic configurations of atoms...Chapter 6, Problem 6.17PAEλ=( hCE)h=6.634×10−34JsC=3×108m/sE=6.0×10−19J Putting these values in above equation you get λ=(...Chapter 6, Problem 6.42PAEAtomic radius is the distance between center of nucleus and outermost electron shell. Atomic radius...Chapter 6, Problem 6.85PAEChapter 6, Problem 6.86PAEChapter 7, Problem 1COChapter 7, Problem 7.72PAEThe electronic configuration of I is [Kr]4d105s25p5. In the excited state, the configuration becomes...The electronic configuration of P is 3s23p33d0. In the excited state, the configuration becomes...The electronic configuration of Xeis 4d105s25p65d0. In the excited state, the configuration becomes...Chapter 7, Problem 7.76PAEIn the structure of diamond each carbon atom is linked to four other carbon atoms forming a three...1 metric ton of silicon = 106 gm of silicon. On conversion of 106 gm of silicon to moles of silicon,...1 metric ton of silicon = 106 gm of silicon. On conversion of 106 gm of silicon to moles of silicon,...Chapter 9, Problem 1COChapter 9, Problem 9.15PAEChapter 9, Problem 9.16PAEChapter 9, Problem 9.37PAEChapter 9, Problem 9.48PAEChapter 9, Problem 9.52PAEChapter 9, Problem 9.55PAEChapter 9, Problem 9.58PAEChapter 9, Problem 9.79PAEChapter 9, Problem 9.85PAEThe given reaction is: 3CO2(g)+Si3N4(s)→2SiO2(s)+2N2(g)+3C(s) Reaction enthalpy can be calculated...1 barrel of oil can produce 19.5 gallons = 73815.5 mL of gasoline We know, 1 gallon = 3785.41 mL...The causes to obstacles in the recovery and recycling of plastic solid waste in terms of economic,...Based on the thermodynamics third law, ’At absolute zero of temperature, the entropy of every...Chapter 10, Problem 10.47PAEChapter 10, Problem 10.69PAEThe change in Gibbs free energy of a reaction is calculated as follows: ΔG0 = sum of ΔG0 (product) -...Chapter 10, Problem 10.75PAEChapter 10, Problem 10.76PAEChapter 10, Problem 10.84PAEChapter 10, Problem 10.88PAEChapter 10, Problem 10.91PAEChapter 10, Problem 10.101PAEChapter 10, Problem 10.102PAEOzone also formed at ground level but the mechanism and kinetics are very different from that in...Chapter 11, Problem 11.6PAEChapter 11, Problem 11.20PAEChapter 11, Problem 11.24PAEChapter 11, Problem 11.30PAEChapter 11, Problem 11.33PAEChapter 11, Problem 11.35PAEChapter 11, Problem 11.36PAEChapter 11, Problem 11.49PAEGiven Information: The table containing the total pressures in the reaction vessel during the...Chapter 11, Problem 11.57PAEO(g)+N2(g)→NO(g)+ N(g) The rate of the equation for the reaction can be written as follows. R= −k...Chapter 11, Problem 11.70PAE(a) The molar ratio of the reactant molecules, products in balance equation is called stoichiometry....Chapter 12, Problem 1COUsing the formula K = [C]eqc[D]eqd[A]eqa[B]eqb we can calculate the values of equilibrium constants...Chapter 12, Problem 12.36PAEWhen the salt is dissolved in water, it forms the ions. When AgBr is dissolved in water, it...Let solubility of ZnCO3 is 3 then ZnCO 3 ( S ) Zn2+(aq)M C O 3 2− ( aq )M Initial concentration...AgCN(S)⇌Ag+(aq)+CN−(aq)KSP=[Ag+][CN−] Solubility of AgCN is 7.73×10−9M, it means that Concentration...Chapter 12, Problem 12.65PAEChapter 12, Problem 12.67PAECH3COOH(aq)+H2O(l)→CH3COO−(aq)+H3O+(aq) Rate of equilibrium expression...NH3(g)+H2O(l)→NH4+(aq)+OH−(aq) Apply the concept aA+bB⇌cC+dD Rate of equilibrium reaction...The given reaction is as follows:H2(g)+Cl2(g)⇌2HCl(g) First step is to calculate the value of...Here, sulfur dioxide, sodium chloride and water are formed when sodium hydrogen sulfite is reacted...For reaction S(s)+O2(g)⇌SO2(g) Enthalpy change (ΔH0)=ΔHf0[Product]−ΔHf0[Reactants]...There are different types of corrosion: Pitting corrosion: is the most destructive type of...Chapter 13, Problem 3COCell potential in standard condition: Measurement of standard electrode potential of Zn2+/Zn...Chapter 13, Problem 13.26PAEChapter 13, Problem 13.29PAEChapter 13, Problem 13.32PAEIn this reaction, Half-cell reaction at the anode Ga(s)→Ga3+(aq)+3e− Half-cell reaction at the...Chapter 13, Problem 13.39PAEChapter 13, Problem 13.43PAEChapter 13, Problem 13.49PAEChapter 13, Problem 13.104PAEUse the given data to calculate the following: 1st Step: Calculate the total amount of charge...Cosmic rays are divided into mainly three types: galactic cosmic rays, extragalactic cosmic rays and...Because this is an alpha decay, the helium nucleus is ejected with decrease in mass number by 4 and...Atomic numbers of thorium and radium are 90 and 88, respectively. Consider the transformation:...The 232Th radioactive series beginning with 232Th and ending with 208Pb. The sequence occurs as...Given information: The experimentally determined mass of 14C is 14.003242 u. Formula used: E =...Given information: Experimentally determined mass of 7Li is 7.016004 u. Formula used: E = (Δm)c2Δm =...Given information: Experimentally determined mass of 14N is 14.003074 u. Formula used: E = (Δm)c2...Formula used: E = (Δm)c2Δm = Mass defectc = Velocity of light Calculation: Let’s calculate the...92235U+01n→52137Te+4097Zr+201n Apply Einstein’s equation E=Δmc2 Δm= Mass of product − mass of...Write the balanced nuclear reaction. 92235U+01n→3890Sr+54143NP+301n Mass of reactant =mu+mn (putting...The total amount of electrical energy generated by all the nuclear reactors is...Calculating decay constant for A26l as follows: k=0.693t 1 2 k=0.6937.17× 105 yr=9.66×10−7 yr−1 Now,...
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