Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter NW1, Problem 25CTQ
Interpretation Introduction

Interpretation: Whether the name of isopropyl and sec-butyl in 7-sec-butyl-6-isopropyl-2-methyldodecane is consistent with the last column Memorization Task NW1.2 or not should be given.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain. Names of branches that occur commonly as side chains are listed below:

  Custom eBook for Organic Chemistry, Chapter NW1, Problem 25CTQ

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(a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?
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First I wanted to see if you would mind checking my graphs behind me. (They haven't been coming out right)? Second, could you help me explain if the rate of reaction is proportional to iodide and persulfate of each graph. I highlighted my answer and understanding but I'm not sure if I'm on the right track. Thank you in advance.
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