Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter NW1, Problem 18CTQ
Interpretation Introduction

Interpretation: The prefix that stands for cyclic chain should be given.

Concept introduction: The convention followed for IUPAC nomenclature of cyclic alkanes is as follows:

  • If even a single ring is found in a molecule, this ring is regarded as the parent chain.
  • Alkyl groups attached to rings are assigned the smallest priority and number and it is followed in a cyclic manner toward the closest group.
  • If two alkyl; group happens to be the same the smallest priority number is assigned alphabetically.

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(a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?
Show the curved arrow mechanism and both products for the reaction between methyl iodide and propoxide. 1st attempt NV H 10: H H 1 Add the missing curved arrow notation. H + See Periodic Table
First I wanted to see if you would mind checking my graphs behind me. (They haven't been coming out right)? Second, could you help me explain if the rate of reaction is proportional to iodide and persulfate of each graph. I highlighted my answer and understanding but I'm not sure if I'm on the right track. Thank you in advance.
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